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Title: Stabilization of battery electrodes using polymer coatings

An electrochemical device (e.g., a battery (cell)) including: an aqueous electrolyte and one or two electrodes (e.g., an anode and/or a cathode), one or both of which is a Prussian Blue analogue material of the general chemical formula A.sub.xP[R(CN).sub.6-jL.sub.j].sub.z.nH.sub.2O, where: A is a cation; P is a metal cation; R is a transition metal cation; L is a ligand that may be substituted in the place of a CN.sup.- ligand; 0.ltoreq.x.ltoreq.2; 0.ltoreq.z.ltoreq.1; and 0.ltoreq.n.ltoreq.5, the electrode including a polymer coating to reduce capacity loss.
Inventors:
;
Issue Date:
OSTI Identifier:
1414934
Assignee:
Natron Energy, Inc. (Santa Clara, CA) ARPA-E
Patent Number(s):
9,853,318
Application Number:
13/892,982
Contract Number:
AR000300
Resource Relation:
Patent File Date: 2013 May 13
Research Org:
Natron Energy, Inc., Santa Clara, CA (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Other works cited in this record:

Nonaqueous secondary battery
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patent, February 1999

Nonflammable non-aqueous electrolyte and non-aqueous electrolyte cells comprising the same
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Polymer composition for encapsulation of electrode particles
patent, January 2008

Rechargeable lithium-ion cell with triphenylamine redox shuttle
patent, September 2009

Materials for battery electrolytes and methods for use
patent, November 2012

Stabilization of battery electrodes using prussian blue analogue coatings
patent, September 2015

Stabilization of battery electrodes
patent, September 2015

Cosolvent electrolytes for electrochemical devices
patent, March 2016

LI/AIR NON-AQUEOUS BATTERIES
patent-application, May 2007

High Rate, Long Cycle Life Battery Electrode Materials With An Open Framework Structure
patent-application, December 2012

High Rate, Long Cycle Life Electrochemical Energy Storage Devices
patent-application, February 2013

Novel Separators For Electrochemical Systems
patent-application, August 2013

Alkali and Alkaline-Earth Ion Batteries with Hexacyanometallate Cathode and Non-Metal Anode
patent-application, October 2013

Fabrication of a Cyanide-Bridged Coordination Polymer Electrode for Enhanced Electrochemical Ion Storage Ability
journal, April 2012
  • Asakura, Daisuke; Okubo, Masashi; Mizuno, Yoshifumi
  • The Journal of Physical Chemistry C, Vol. 116, Issue 15, p. 8364-8369
  • DOI: 10.1021/jp2118949

Formation of copper(II), zinc(II), silver(I) and lead(II) ferrocyanides
journal, November 1970

The crystal structure of Prussian Blue: Fe4[Fe(CN)6]3.xH2O
journal, November 1977
  • Buser, H. J.; Schwarzenbach, D.; Petter, W.
  • Inorganic Chemistry, Vol. 16, Issue 11, p. 2704-2710
  • DOI: 10.1021/ic50177a008

Photogalvanic behaviour of K3Mn(CN)6 in CN aqueous solutions
journal, February 1990

Core-Multishell Magnetic Coordination Nanoparticles: Toward Multifunctionality on the Nanoscale
journal, November 2008
  • Catala, Laure; Brinzei, Daniela; Prado, Yoann
  • Angewandte Chemie, Vol. 121, Issue 1, p. 189-193
  • DOI: 10.1002/ange.200804238

Über Hexacyanomanganate(I) und Hexacyanorhenat(I)
journal, December 1958
  • Clauss, D.; Lissner, A.
  • Zeitschrift für anorganische und allgemeine Chemie, Vol. 297, Issue 5-6, p. 300-310
  • DOI: 10.1002/zaac.19582970505

The Effect of Insertion Species on Nanostructured Open Framework Hexacyanoferrate Battery Electrodes
journal, January 2012
  • Wessells, Colin D.; Peddada, Sandeep V.; McDowell, Matthew T.
  • Journal of The Electrochemical Society, Vol. 159, Issue 2, p. A98-A103
  • DOI: 10.1149/2.060202jes

Electrochemical Analysis of Conductive Polymer-Coated LiFePO4 Nanocrystalline Cathodes with Controlled Morphology
journal, July 2011
  • Dinh, Hung-Cuong; Mho, Sun-il; Yeo, In-Hyeong
  • Electroanalysis, Vol. 23, Issue 9, p. 2079-2086
  • DOI: 10.1002/elan.201100222

Fabrication of all-solid-state thin-film secondary cells using hexacyanometallate-based electrode materials
journal, May 2004

Hexacyanoferrate layers as electrodes for secondary cells
journal, May 1987
  • Grabner, E. W.; Kalwellis-Mohn, S.
  • Journal of Applied Electrochemistry, Vol. 17, Issue 3, p. 653-656
  • DOI: 10.1007/BF01084142

Cyanide complexes of the early transition metals (groups IVa-VIIa)
journal, November 1975

Anomalous Non-Prussian Blue Structures and Magnetic Ordering of K2MnII[MnII(CN)6] and Rb2MnII[MnII(CN)6]
journal, February 2010
  • Her, Jae-Hyuk; Stephens, Peter W.; Kareis, Christopher M.
  • Inorganic Chemistry, Vol. 49, Issue 4, p. 1524-1534
  • DOI: 10.1021/ic901903f

Sulfone-Based Electrolyte Solutions for Rechargeable Magnesium Batteries Using 2,5-Dimethoxy-1,4-benzoquinone Positive Electrode
journal, January 2014
  • Senoh, H.; Sakaebe, H.; Sano, H.
  • Journal of the Electrochemical Society, Vol. 161, Issue 9, p. A1315-A1320
  • DOI: 10.1149/2.0531409jes

Prussian Blue Containing Nafion Composite Film as Rechargeable Battery
journal, January 1987
  • Honda, Kenji; Hayashi, Hideko
  • Journal of The Electrochemical Society, Vol. 134, Issue 6, p. 1330-1334
  • DOI: 10.1149/1.2100668

One-step synthesis and self-organization of polypyrrole ultrathin films inlayed with Prussian blue nanoparticles induced by a drop of toluene solution on water surface
journal, January 2012

Electrochemistry of polynuclear transition metal cyanides: Prussian blue and its analogues
journal, June 1986
  • Itaya, Kingo; Uchida, Isamu; Neff, Vernon D.
  • Accounts of Chemical Research, Vol. 19, Issue 6, p. 162-168
  • DOI: 10.1021/ar00126a001

Charge–discharge characteristics of a solid-state Prussian blue secondary cell
journal, April 2000

Performance characteristics of zinc hexacyanoferrate/Prussian blue and copper hexacyanoferrate/Prussian blue solid state secondary cells
journal, December 2000

Highly Sensitive Molecularly Imprinted Electrochemical Sensor Based on the Double Amplification by an Inorganic Prussian Blue Catalytic Polymer and the Enzymatic Effect of Glucose Oxidase
journal, January 2012
  • Li, Jianping; Li, Yuping; Zhang, Yun
  • Analytical Chemistry, Vol. 84, Issue 4, p. 1888-1893
  • DOI: 10.1021/ac2026817

A secondary cell based on thin layers of zeolite-like nickel hexacyanometallates
journal, August 1989

Electrochemical behavior of iron-hexacyanoruthenate(II) thin films in aqueous electrolytes: potential analytical and catalytic applications
journal, June 2001

Fast disproportionation of hexacyanomanganate(III) in acidic solution. Formation of hexacyanomanganate(IV) and kinetics of its decomposition
journal, December 1986
  • López-Cueto, Guillermo; Ubide, Carlos
  • Canadian Journal of Chemistry, Vol. 64, Issue 12, p. 2301-2304
  • DOI: 10.1139/v86-377

Some Performance Characteristics of a Prussian Blue Battery
journal, January 1985
  • Neff, Vernon D.
  • Journal of The Electrochemical Society, Vol. 132, Issue 6, p. 1382-1384
  • DOI: 10.1149/1.2114121

A high-rate and long cycle life aqueous electrolyte battery for grid-scale energy storage
journal, January 2012
  • Pasta, Mauro; Wessells, Colin D.; Huggins, Robert A.
  • Nature Communications, Vol. 3, Issue 1, Article No. 1149
  • DOI: 10.1038/ncomms2139

The Color and Electronic Configurations of Prussian Blue
journal, May 1962

In Situ Investigation of the Electrochemical Reduction of Carbonate Electrolyte Solutions at Graphite Electrodes
journal, January 1998
  • Imhof, Roman; Novák, Petr
  • Journal of The Electrochemical Society, Vol. 145, Issue 4, p. 1081-1087
  • DOI: 10.1149/1.1838420

The Formal Potentials of Solid Metal Hexacyanometalates
journal, January 1996
  • Scholz, Fritz; Dostal, Aleš
  • Angewandte Chemie International Edition in English, Vol. 34, Issue 23-24, p. 2685-2687
  • DOI: 10.1002/anie.199526851

Beiträge zur Komplexchemie des Technetiums. II. Darstellung und Eigenschaften von Kalium-cyanotechnetat(I)
journal, December 1962
  • Schwochau, K.; Herr, W.
  • Zeitschrift für anorganische und allgemeine Chemie, Vol. 319, Issue 3-4, p. 148-158
  • DOI: 10.1002/zaac.19623190305

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976

The thermodynamics of the insertion electrochemistry of solid metal hexacyanometallates
journal, March 2002
  • Bárcena Soto, Maximiliano; Scholz, Fritz
  • Journal of Electroanalytical Chemistry, Vol. 521, Issue 1-2, p. 183-189
  • DOI: 10.1016/S0022-0728(02)00710-6

Solubilities of some chloride and perchlorate salts in sulfolane
journal, February 1972
  • Starkovich, J. A.; Janghorbani, M.
  • Journal of Inorganic and Nuclear Chemistry, Vol. 34, Issue 2, p. 789-791
  • DOI: 10.1016/0022-1902(72)80471-8

Electrochemical studies of the factors influencing the cycle stability of Prussian Blue films
journal, April 1992
  • Stilwell, D. E.; Park, K. H.; Miles, M. H.
  • Journal of Applied Electrochemistry, Vol. 22, Issue 4, p. 325-331
  • DOI: 10.1007/BF01092684

Copper hexacyanoferrate battery electrodes with long cycle life and high power
journal, November 2011
  • Wessells, Colin D.; Huggins, Robert A.; Cui, Yi
  • Nature Communications, Vol. 2, Article No. 550
  • DOI: 10.1038/ncomms1563

Nickel Hexacyanoferrate Nanoparticle Electrodes For Aqueous Sodium and Potassium Ion Batteries
journal, December 2011
  • Wessells, Colin D.; Peddada, Sandeep V.; Huggins, Robert A.
  • Nano Letters, Vol. 11, Issue 12, p. 5421-5425
  • DOI: 10.1021/nl203193q

Tunable Reaction Potentials in Open Framework Nanoparticle Battery Electrodes for Grid-Scale Energy Storage
journal, January 2012
  • Wessells, Colin D.; McDowell, Matthew T.; Peddada, Sandeep V.
  • ACS Nano, Vol. 6, Issue 2, p. 1688-1694
  • DOI: 10.1021/nn204666v

A simple and an efficient strategy to synthesize multi-component nanocomposites for biosensor applications
journal, January 2012

Electrochemical properties and lithium ion solvation behavior of sulfone–ester mixed electrolytes for high-voltage rechargeable lithium cells
journal, May 2008

High Affinity of Thallium Ions to Copper Hexacyanoferrate Films
journal, January 2001
  • Zadronecki, Marcin; Linek, Iwona A.; Stroka, Jadwiga
  • Journal of The Electrochemical Society, Vol. 148, Issue 8, p. E348-E355
  • DOI: 10.1149/1.1381074

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