Methods for using atomic layer deposition to produce a film for solid state electrolytes and protective electrode coatings for lithium batteries

Elam, Jeffrey W.; Meng, Xiangbo

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Title: Methods for using atomic layer deposition to produce a film for solid state electrolytes and protective electrode coatings for lithium batteries

Abstract

A method for using atomic layer deposition to produce a film configured for use in an anode, cathode, or solid state electrolyte of a lithium-ion battery or a lithium-sulfur battery. The method includes repeating a cycle for a predetermined number of times in an inert atmosphere. The cycle includes exposing a substrate to a first precursor, purging the substrate with inert gas, exposing the substrate to a second precursor, and purging the substrate with inert gas. The film is a metal sulfide.

Inventors:: Elam, Jeffrey W.; Meng, Xiangbo

Issue Date:: 2018-03-13

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1425947

Patent Number(s):: 9917295

Application Number:: 14/711,504

Assignee:: UChicago Argonne, LLC (Chicago, IL)

Patent Classifications (CPCs):: H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

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H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/052 - Li-accumulators
H01M10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes
H01M10/0562 - Solid materials
H01M10/058 - Construction or manufacture
H01M2220/20 - Batteries in motive systems, e.g. vehicle, ship, plane
H01M2300/0068 - inorganic
H01M4/0426 - {Sputtering}
H01M4/136 - Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M4/1397 - of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M4/5815 - {Sulfides}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
Y02P70/50 - Manufacturing or production processes characterised by the final manufactured product

Show less

DOE Contract Number:: AC02-06CH11357

Resource Type:: Patent

Resource Relation:: Patent File Date: 2015 May 13

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE

Citation Formats


                    Elam, Jeffrey W., and Meng, Xiangbo. Methods for using atomic layer deposition to produce a film for solid state electrolytes and protective electrode coatings for lithium batteries.  United States: N. p., 2018. 
        Web.

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                    Elam, Jeffrey W., & Meng, Xiangbo. Methods for using atomic layer deposition to produce a film for solid state electrolytes and protective electrode coatings for lithium batteries.  United States.

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                    Elam, Jeffrey W., and Meng, Xiangbo. Tue .  
        "Methods for using atomic layer deposition to produce a film for solid state electrolytes and protective electrode coatings for lithium batteries".  United States.  https://www.osti.gov/servlets/purl/1425947.

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@article{osti_1425947,

  title        = {Methods for using atomic layer deposition to produce a film for solid state electrolytes and protective electrode coatings for lithium batteries},

  author       = {Elam, Jeffrey W. and Meng, Xiangbo},

  abstractNote = {A method for using atomic layer deposition to produce a film configured for use in an anode, cathode, or solid state electrolyte of a lithium-ion battery or a lithium-sulfur battery. The method includes repeating a cycle for a predetermined number of times in an inert atmosphere. The cycle includes exposing a substrate to a first precursor, purging the substrate with inert gas, exposing the substrate to a second precursor, and purging the substrate with inert gas. The film is a metal sulfide.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2018},

  month        = {3}

}

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Works referenced in this record:

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patent, May 2015

Martinson, Alex B.; Elam, Jeffrey W.; Pellin, Michael J.
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Integrated Electrochemical and Solar Cell
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Gallium sulfide thin film grown on GaAs(1 0 0) by microwave glow discharge
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Japanese Journal of Applied Physics, Vol. 44, Issue 7A, p. 4780-4783
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Similar Records

Title: Methods for using atomic layer deposition to produce a film for solid state electrolytes and protective electrode coatings for lithium batteries

Abstract

Citation Formats

Atomic layer deposition of metal sulfide thin films using non-halogenated precursors patent, May 2015

Nanotechnological processing of catalytic surfaces patent-application, June 2006

Integrated Electrochemical and Solar Cell patent-application, March 2009

Sulfur-Containing Thin Films patent-application, June 2015

Atomic Layer Deposition of Lead Sulfide Quantum Dots on Nanowire Surfaces journal, March 2011

Design of an atomic layer deposition reactor for hydrogen sulfide compatibility journal, April 2010

(Invited) Atomic Layer Deposition of Multicomponent Metal Sulfides Applied to Thin Film Photovoltaics journal, August 2013

Atomic Layer Deposition of Metal Sulfide Materials journal, January 2015

Gallium sulfide thin film grown on GaAs(1 0 0) by microwave glow discharge journal, March 1997

Deposition of Thin Films of Gallium Sulfide from a Novel Single-Source Precursor, Ga(S2CNMeHex)3, by Low-Pressure Metal−Organic Chemical Vapor Deposition journal, December 1999

Growth, Optical and Structural Characterization of Layered GaS Films Prepared by Reactive RF Sputtering Method journal, July 2005

Influence of the synthesis conditions on gallium sulfide thin films prepared by modulated flux deposition journal, March 2009

Gallium (III) sulfide as an active material in lithium secondary batteries journal, July 2011

Chemical Vapor Deposition of Gallium Sulfide Thin Films journal, September 2000

Nanoporous Li2S and MWCNT-linked Li2S powder cathodes for lithium-sulfur and lithium-ion battery chemistries journal, January 2014

High-Capacity Micrometer-Sized Li2 S Particles as Cathode Materials for Advanced Rechargeable Lithium-Ion Batteries journal, September 2012

In situ synthesis of lithium sulfide–carbon composites as cathode materials for rechargeable lithium batteries journal, January 2013

Controlled Nucleation and Growth Process of Li2S2/Li2S in Lithium-Sulfur Batteries journal, January 2013

Atomic layer deposition of metal sulfide thin films using non-halogenated precursors
patent, May 2015

Nanotechnological processing of catalytic surfaces
patent-application, June 2006

Integrated Electrochemical and Solar Cell
patent-application, March 2009

Sulfur-Containing Thin Films
patent-application, June 2015

Atomic Layer Deposition of Lead Sulfide Quantum Dots on Nanowire Surfaces
journal, March 2011

Design of an atomic layer deposition reactor for hydrogen sulfide compatibility
journal, April 2010

(Invited) Atomic Layer Deposition of Multicomponent Metal Sulfides Applied to Thin Film Photovoltaics
journal, August 2013

Atomic Layer Deposition of Metal Sulfide Materials
journal, January 2015

Gallium sulfide thin film grown on GaAs(1 0 0) by microwave glow discharge
journal, March 1997

Deposition of Thin Films of Gallium Sulfide from a Novel Single-Source Precursor, Ga(S₂CNMeHex)₃, by Low-Pressure Metal−Organic Chemical Vapor Deposition
journal, December 1999

Growth, Optical and Structural Characterization of Layered GaS Films Prepared by Reactive RF Sputtering Method
journal, July 2005

Influence of the synthesis conditions on gallium sulfide thin films prepared by modulated flux deposition
journal, March 2009

Gallium (III) sulfide as an active material in lithium secondary batteries
journal, July 2011

Chemical Vapor Deposition of Gallium Sulfide Thin Films
journal, September 2000

Nanoporous Li₂S and MWCNT-linked Li₂S powder cathodes for lithium-sulfur and lithium-ion battery chemistries
journal, January 2014

High-Capacity Micrometer-Sized Li₂ S Particles as Cathode Materials for Advanced Rechargeable Lithium-Ion Batteries
journal, September 2012

In situ synthesis of lithium sulfide–carbon composites as cathode materials for rechargeable lithium batteries
journal, January 2013

Controlled Nucleation and Growth Process of Li₂S₂/Li₂S in Lithium-Sulfur Batteries
journal, January 2013