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Title: Process to separate alkali metal salts from alkali metal reacted hydrocarbons

A process to facilitate gravimetric separation of alkali metal salts, such as alkali metal sulfides and polysulfides, from alkali metal reacted hydrocarbons. The disclosed process is part of a method of upgrading a hydrocarbon feedstock by removing heteroatoms and/or one or more heavy metals from the hydrocarbon feedstock composition. This method reacts the oil feedstock with an alkali metal and an upgradant hydrocarbon. The alkali metal reacts with a portion of the heteroatoms and/or one or more heavy metals to form an inorganic phase containing alkali metal salts and reduced heavy metals, and an upgraded hydrocarbon feedstock. The inorganic phase may be gravimetrically separated from the upgraded hydrocarbon feedstock after mixing at a temperature between about 350.degree. C. to 400.degree. C. for a time period between about 15 minutes and 2 hours.
Inventors:
; ; ;
Issue Date:
OSTI Identifier:
1366745
Assignee:
FIELD UPGRADING LIMITED NETL
Patent Number(s):
9,688,920
Application Number:
14/253,286
Contract Number:
FE0000408
Resource Relation:
Patent File Date: 2014 Apr 15
Research Org:
FIELD UPGRADING LIMITED, Calgary, CA (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

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Electrolytic Process and Cell
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Process of Producing Lubricating Oil
patent, September 1936

Method of Decreasing Metal Corrosion
patent, July 1941

Treatment of Hydrocarbon Stocks with Sodium
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Nuclear Alkylation of Certain Aromatic Hydrocarbons with Alkali Metals as Catalysts
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Desulfurization Process
patent, January 1965

Process for upgrading a hydrocarbon fraction
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Combined disulfurization and conversion with alkali metals
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Upgrading hydrocarbonaceous oils with an aqueous liquid
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Process for selective removal of CCR, arsenic and conjugated diolefins from shale oil
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Hydrotreating of carbonaceous materials
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Process for the alkylation of aromatics
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Methods for adding value to heavy oil utilizing a soluble metal catalyst
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Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides
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