Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides

Gordon, John Howard

Title: Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides

Abstract

Alkali metals and sulfur may be recovered from alkali monosulfide and polysulfides in an electrolytic process that utilizes an electrolytic cell having an alkali ion conductive membrane. An anolyte includes an alkali monosulfide, an alkali polysulfide, or a mixture thereof and a solvent that dissolves elemental sulfur. A catholyte includes molten alkali metal. Applying an electric current oxidizes sulfide and polysulfide in the anolyte compartment, causes alkali metal ions to pass through the alkali ion conductive membrane to the catholyte compartment, and reduces the alkali metal ions in the catholyte compartment. Liquid sulfur separates from the anolyte and may be recovered. The electrolytic cell is operated at a temperature where the formed alkali metal and sulfur are molten.

Inventors:: Gordon, John Howard

Issue Date:: 2018-10-02

Research Org.:: Field Upgrading Limited, Calgary, CA

Sponsoring Org.:: USDOE

OSTI Identifier:: 1490855

Patent Number(s):: 10087538

Application Number:: 15/279,926

Assignee:: FIELD UPGRADING LIMITED (Calgary, CA)

Patent Classifications (CPCs):: C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS

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C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS
C10G2300/202 - Heteroatoms content, i.e. S, N, O, P
C10G32/02 - by electric or magnetic means

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B17/34 - Polysulfides of sodium or potassium

C - CHEMISTRY C25 - ELECTROLYTIC OR ELECTROPHORETIC PROCESSES C25C - PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS
C25C3/02 - of alkali or alkaline earth metals
C25C7/06 - Operating or servicing
C25C1/02 - of light metals

C - CHEMISTRY C25 - ELECTROLYTIC OR ELECTROPHORETIC PROCESSES C25B - ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS
C25B1/00 - Electrolytic production of inorganic compounds or non-metals

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B17/22 - Alkali metal sulfides or polysulfides

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DOE Contract Number:: FE0000408

Resource Type:: Patent

Resource Relation:: Patent File Date: 2016 Sep 29

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Gordon, John Howard. Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides.  United States: N. p., 2018. 
        Web.

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                    Gordon, John Howard. Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides.  United States.

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                    Gordon, John Howard. Tue .  
        "Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides".  United States.  https://www.osti.gov/servlets/purl/1490855.

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@article{osti_1490855,

  title        = {Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides},

  author       = {Gordon, John Howard},

  abstractNote = {Alkali metals and sulfur may be recovered from alkali monosulfide and polysulfides in an electrolytic process that utilizes an electrolytic cell having an alkali ion conductive membrane. An anolyte includes an alkali monosulfide, an alkali polysulfide, or a mixture thereof and a solvent that dissolves elemental sulfur. A catholyte includes molten alkali metal. Applying an electric current oxidizes sulfide and polysulfide in the anolyte compartment, causes alkali metal ions to pass through the alkali ion conductive membrane to the catholyte compartment, and reduces the alkali metal ions in the catholyte compartment. Liquid sulfur separates from the anolyte and may be recovered. The electrolytic cell is operated at a temperature where the formed alkali metal and sulfur are molten.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2018},

  month        = {10}

}

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Similar Records

Title: Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides

Abstract

Citation Formats

Dentrite-Free Electrochemical Deposition of Li–Na Alloys from an Ionic Liquid Electrolyte journal, January 2006

Effects of M3+ Ions on the Conductivity of Glasses and Glass-Ceramics in the System Li2O-M2O3-GeO2-P2O5 (M = Al, Ga, Y, Dy, Gd, and La) journal, April 2000

Cation Electrochemical Stability in Chloroaluminate Ionic Liquids journal, October 2005

Lithium ion conducting Li4−2xGe1−xSxO4 solid electrolytes journal, August 1993

Electrochemical Investigation of Quaternary Ammonium/Aluminum Chloride Ionic Liquids journal, January 2004

Polymer composite electrolytes containing ionically active mesoporous SiO2 particles journal, September 2007

Conduction paths in sintered ionic conductive material Na1+xYxZr2−x(PO4)3 journal, October 1981

Crystal structures and crystal chemistry in the system Na1+xZr2SixP3−xO12 journal, February 1976

Ionic-liquid materials for the electrochemical challenges of the future journal, July 2009

Ionic conductivity of NASICON-type conductors Na1.5M0.5Zr1.5(PO4)3 (M:Al3+, Ga3+, Cr3+, Sc3+, Fe3+, In3+, Yb3+, Y3+) journal, December 1992

Selective sodium removal from aqueous waste streams with NaSicon ceramics journal, May 1999

Li+ and Na+ transfer through interfaces between inorganic solid electrolytes and polymer or liquid electrolytes journal, August 2005

Fast Li+ ion conducting glass-ceramics in the system Li2O–Al2O3–GeO2–P2O5 journal, December 1997

Electrical conductivity and Ti4+ ion substitution range in NASICON system journal, July 1995

New solid electrolytes and mixed conductors: Li3 + xCr1 − xMxO4: M = Ge, Ti journal, March 1995

The Role of Additives in the Electroreduction of Sodium Ions in Chloroaluminate-Based Ionic Liquids journal, January 2005

The comparative structure, properties, and ionic conductivity of LiI+Li2S+GeS2 glasses doped with Ga2S3 and La2S3 journal, March 2008

Crystal chemistry of the Na1+xZr2−xLx(PO4)3 (L = Cr, In, Yb) solid solutions journal, March 1981

Novel Li+ Ion Conductors and Mixed Conductors, Li[sub 3+x]Si[sub x]Cr[sub 1−x]O[sub 4] and a Simple Method for Estimating Li[sup +]/e[sup −] Transport Numbers journal, January 1995

Preparation and characterization of lithium-ion-conductive Li1.3Al0.3Ti1.7(PO4)3 thin films by the solution deposition journal, February 2003

Desulphurization of gasoline by metallic sodium journal, July 1976

High temperature naphthenic acid corrosion of steel in high TAN refining media journal, September 2008

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Li-air batteries: A classic example of limitations owing to solubilities journal, January 2007

LiTi2(PO4)3 with NASICON-type structure as lithium-storage materials journal, October 2003

Superionic Conductivity in a Lithium Aluminum Germanium Phosphate Glass–Ceramic journal, January 2008

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Fast Na+-ion transport in skeleton structures journal, February 1976

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Dentrite-Free Electrochemical Deposition of Li–Na Alloys from an Ionic Liquid Electrolyte
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Effects of M3+ Ions on the Conductivity of Glasses and Glass-Ceramics in the System Li2O-M2O3-GeO2-P2O5 (M = Al, Ga, Y, Dy, Gd, and La)
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Cation Electrochemical Stability in Chloroaluminate Ionic Liquids
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Electrochemical Investigation of Quaternary Ammonium/Aluminum Chloride Ionic Liquids
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Polymer composite electrolytes containing ionically active mesoporous SiO₂ particles
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Crystal structures and crystal chemistry in the system Na1+xZr2SixP3−xO12
journal, February 1976

Ionic-liquid materials for the electrochemical challenges of the future
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Ionic conductivity of NASICON-type conductors Na1.5M0.5Zr1.5(PO4)3 (M:Al3+, Ga3+, Cr3+, Sc3+, Fe3+, In3+, Yb3+, Y3+)
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Selective sodium removal from aqueous waste streams with NaSicon ceramics
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Li+ and Na+ transfer through interfaces between inorganic solid electrolytes and polymer or liquid electrolytes
journal, August 2005

Fast Li+ ion conducting glass-ceramics in the system Li2O–Al2O3–GeO2–P2O5
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Electrical conductivity and Ti4+ ion substitution range in NASICON system
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New solid electrolytes and mixed conductors: Li3 + xCr1 − xMxO4: M = Ge, Ti
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The Role of Additives in the Electroreduction of Sodium Ions in Chloroaluminate-Based Ionic Liquids
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Li-air batteries: A classic example of limitations owing to solubilities
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Superionic Conductivity in a Lithium Aluminum Germanium Phosphate Glass–Ceramic
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The preparation and characterization of dense, highly conductive Na₅GdSi₄O₁₂ nasicon (NGS)
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Fast Na+-ion transport in skeleton structures
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Compositional dependence of the electrochemical and structural parameters in the Nasicon system (Na1+xSixZr2P3−xO12)
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High Voltage Lithium Polymer Cells Using a PAN-Based Composite Electrolyte
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Chemistry and properties of solids with the [NZP] skeleton
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The Electrolysis of Sodium Sulphide Solutions
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Li_1.3Al_0.3Ti_1.7(PO₄)₃ filler effect on (PEO)LiClO₄ solid polymer electrolyte
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Characterization of the Lithium/Oxygen Organic Electrolyte Battery
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Ionic conductivity of NASICON-type Na1+xMxZr2−xP3O12 (M: Yb, Er, Dy)
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