Electrolytes comprising metal amide and metal chlorides for multivalent battery

Liao, Chen; Zhang, Zhengcheng; Burrell, Anthony; Vaughey, John T.

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Title: Electrolytes comprising metal amide and metal chlorides for multivalent battery

Abstract

An electrolyte includes compounds of formula M.sup.1X.sub.n and M.sup.2Z.sub.m; and a solvent wherein M.sup.1 is Mg, Ca, Sr, Ba, Sc, Ti, Al, or Zn; M.sup.2 is Mg, Ca, Sr, Ba, Sc, Ti, Al, or Zn; X is a group forming a covalent bond with M.sup.1; Z is a halogen or pseudo-halogen; n is 1, 2, 3, 4, 5, or 6; and m is 1, 2, 3, 4, 5, or 6.

Inventors:: Liao, Chen; Zhang, Zhengcheng; Burrell, Anthony; Vaughey, John T.

Issue Date:: Tue Mar 21 00:00:00 EDT 2017

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1347538

Patent Number(s):: 9601801

Application Number:: 14/335,604

Assignee:: UCHICAGO ARGONNE, LLC

Patent Classifications (CPCs):: H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

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H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/054 - Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
H01M10/0568 - characterised by the solutes
H01M2300/0025 - Organic electrolyte
H01M4/485 - of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M4/5815 - {Sulfides}
H01M4/5825 - {Oxygenated metallic slats or polyanionic structures, e.g. borates, phosphates, silicates, olivines}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

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DOE Contract Number:: AC02-06CH11357

Resource Type:: Patent

Resource Relation:: Patent File Date: 2014 Jul 18

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 25 ENERGY STORAGE; 36 MATERIALS SCIENCE

Citation Formats


                    Liao, Chen, Zhang, Zhengcheng, Burrell, Anthony, and Vaughey, John T. Electrolytes comprising metal amide and metal chlorides for multivalent battery.  United States: N. p., 2017. 
        Web.

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                    Liao, Chen, Zhang, Zhengcheng, Burrell, Anthony, & Vaughey, John T. Electrolytes comprising metal amide and metal chlorides for multivalent battery.  United States.

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                    Liao, Chen, Zhang, Zhengcheng, Burrell, Anthony, and Vaughey, John T. Tue .  
        "Electrolytes comprising metal amide and metal chlorides for multivalent battery".  United States.  https://www.osti.gov/servlets/purl/1347538.

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@article{osti_1347538,

  title        = {Electrolytes comprising metal amide and metal chlorides for multivalent battery},

  author       = {Liao, Chen and Zhang, Zhengcheng and Burrell, Anthony and Vaughey, John T.},

  abstractNote = {An electrolyte includes compounds of formula M.sup.1X.sub.n and M.sup.2Z.sub.m; and a solvent wherein M.sup.1 is Mg, Ca, Sr, Ba, Sc, Ti, Al, or Zn; M.sup.2 is Mg, Ca, Sr, Ba, Sc, Ti, Al, or Zn; X is a group forming a covalent bond with M.sup.1; Z is a halogen or pseudo-halogen; n is 1, 2, 3, 4, 5, or 6; and m is 1, 2, 3, 4, 5, or 6.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Tue Mar 21 00:00:00 EDT 2017},

  month        = {Tue Mar 21 00:00:00 EDT 2017}

}

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Works referenced in this record:

Catalytic composition and a process for oligomerizing ethylene, in particular to 1-hexene
patent, December 2004

Commereuc, Dominique; Drochon, Sebastien; Saussine, Lucien
US Patent Document 6,828,269
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Electrochemical device with a magnesium anode and a stable, safe electrolyte compatible with sulfur
patent-application, May 2012

Muldoon, John; Kim, Hee Soo; Matsui, Masaki
US Patent Application 12/913253; 20120107698
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120107698

High Voltage Rechargeable Magnesium Batteries Having A Non-Aqueous Electrolyte
patent-application, September 2013

Doe, Robert Ellis; Lane, George Hamilton
US Patent Application 13/803321; 20130252112
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20130252112

Prototype systems for rechargeable magnesium batteries
journal, October 2000

Aurbach, D.; Lu, Z.; Schechter, A.
Nature, Vol. 407, Issue 6805, p. 724-727
https://doi.org/10.1038/35037553

Nonaqueous Electrochemistry of Magnesium
journal, January 1990

Gregory, Thomas D.; Hoffman, Ronald J.; Winterton, Richard C.
Journal of The Electrochemical Society, Vol. 137, Issue 3, p. 775-780
https://doi.org/10.1149/1.2086553

Molten salt synthesis (MSS) of Cu₂Mo₆S₈—New way for large-scale production of Chevrel phases
journal, June 2006

Lancry, E.; Levi, E.; Mitelman, A.
Journal of Solid State Chemistry, Vol. 179, Issue 6, p. 1879-1882
https://doi.org/10.1016/j.jssc.2006.02.032

Plating of magnesium from organic solvents
journal, February 1996

Lossius, Lorentz Petter; Emmenegger, Franzpeter
Electrochimica Acta, Vol. 41, Issue 3, p. 445-447
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On the electrochemical behavior of magnesium electrodes in polar aprotic electrolyte solutions
journal, May 1999

Lu, Z.; Schechter, A.; Moshkovich, M.
Journal of Electroanalytical Chemistry, Vol. 466, Issue 2, p. 203-217
https://doi.org/10.1016/S0022-0728(99)00146-1

Electrolyte Solutions with a Wide Electrochemical Window for Rechargeable Magnesium Batteries
journal, January 2008

Mizrahi, Oren; Amir, Nir; Pollak, Elad
Journal of The Electrochemical Society, Vol. 155, Issue 2, p. A103-A109
https://doi.org/10.1149/1.2806175

Corrosion of magnesium electrolytes: chlorides – the culprit
journal, December 2012

Muldoon, John; Bucur, Claudiu B.; Oliver, Allen G.
Energy Environ. Sci., Vol. 6, Issue 2, p. 482-487
https://doi.org/10.1039/C2EE23686A

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Similar Records

Title: Electrolytes comprising metal amide and metal chlorides for multivalent battery

Abstract

Citation Formats

Catalytic composition and a process for oligomerizing ethylene, in particular to 1-hexene patent, December 2004

Electrochemical device with a magnesium anode and a stable, safe electrolyte compatible with sulfur patent-application, May 2012

High Voltage Rechargeable Magnesium Batteries Having A Non-Aqueous Electrolyte patent-application, September 2013

Prototype systems for rechargeable magnesium batteries journal, October 2000

Nonaqueous Electrochemistry of Magnesium journal, January 1990

Molten salt synthesis (MSS) of Cu2Mo6S8—New way for large-scale production of Chevrel phases journal, June 2006

Plating of magnesium from organic solvents journal, February 1996

On the electrochemical behavior of magnesium electrodes in polar aprotic electrolyte solutions journal, May 1999

Electrolyte Solutions with a Wide Electrochemical Window for Rechargeable Magnesium Batteries journal, January 2008

Corrosion of magnesium electrolytes: chlorides – the culprit journal, December 2012

Catalytic composition and a process for oligomerizing ethylene, in particular to 1-hexene
patent, December 2004

Electrochemical device with a magnesium anode and a stable, safe electrolyte compatible with sulfur
patent-application, May 2012

High Voltage Rechargeable Magnesium Batteries Having A Non-Aqueous Electrolyte
patent-application, September 2013

Prototype systems for rechargeable magnesium batteries
journal, October 2000

Nonaqueous Electrochemistry of Magnesium
journal, January 1990

Molten salt synthesis (MSS) of Cu₂Mo₆S₈—New way for large-scale production of Chevrel phases
journal, June 2006

Plating of magnesium from organic solvents
journal, February 1996

On the electrochemical behavior of magnesium electrodes in polar aprotic electrolyte solutions
journal, May 1999

Electrolyte Solutions with a Wide Electrochemical Window for Rechargeable Magnesium Batteries
journal, January 2008

Corrosion of magnesium electrolytes: chlorides – the culprit
journal, December 2012