Electrolyte for high efficiency cycling of sodium metal and rechargeable sodium-based batteries comprising the electrolyte
Abstract
Embodiments of a non-aqueous electrolyte for a rechargeable sodium (Na)-based battery comprise a sodium salt and a nonaqueous solvent, the electrolyte having a sodium salt concentration .gtoreq.2.5 M or a solvent-sodium salt mole ratio .ltoreq.4:1. Na-based rechargeable batteries including the electrolyte exhibit both high cycling stability and high coulombic efficiency (CE). Some embodiments of the disclosed batteries attain a CE.gtoreq.80% within 10-30 charge-discharge cycles and maintain a CE.gtoreq.80% for at least 100 charge-discharge cycles. In certain embodiments, the battery is an anode-free battery in the as-assembled initial state.
- Inventors:
- Issue Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1493293
- Patent Number(s):
- 10170795
- Application Number:
- 14/869,647
- Assignee:
- Battelle Memorial Institute (Richland, WA)
- Patent Classifications (CPCs):
-
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- DOE Contract Number:
- AC05-76RL01830
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2015 Sep 29
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Zhang, Ji-Guang, Cao, Ruiguo, Henderson, Wesley A., Mishra, Kuber, and Xu, Wu. Electrolyte for high efficiency cycling of sodium metal and rechargeable sodium-based batteries comprising the electrolyte. United States: N. p., 2019.
Web.
Zhang, Ji-Guang, Cao, Ruiguo, Henderson, Wesley A., Mishra, Kuber, & Xu, Wu. Electrolyte for high efficiency cycling of sodium metal and rechargeable sodium-based batteries comprising the electrolyte. United States.
Zhang, Ji-Guang, Cao, Ruiguo, Henderson, Wesley A., Mishra, Kuber, and Xu, Wu. Tue .
"Electrolyte for high efficiency cycling of sodium metal and rechargeable sodium-based batteries comprising the electrolyte". United States. https://www.osti.gov/servlets/purl/1493293.
@article{osti_1493293,
title = {Electrolyte for high efficiency cycling of sodium metal and rechargeable sodium-based batteries comprising the electrolyte},
author = {Zhang, Ji-Guang and Cao, Ruiguo and Henderson, Wesley A. and Mishra, Kuber and Xu, Wu},
abstractNote = {Embodiments of a non-aqueous electrolyte for a rechargeable sodium (Na)-based battery comprise a sodium salt and a nonaqueous solvent, the electrolyte having a sodium salt concentration .gtoreq.2.5 M or a solvent-sodium salt mole ratio .ltoreq.4:1. Na-based rechargeable batteries including the electrolyte exhibit both high cycling stability and high coulombic efficiency (CE). Some embodiments of the disclosed batteries attain a CE.gtoreq.80% within 10-30 charge-discharge cycles and maintain a CE.gtoreq.80% for at least 100 charge-discharge cycles. In certain embodiments, the battery is an anode-free battery in the as-assembled initial state.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}
Works referenced in this record:
Symmetrical Impedance Study on Inactivation Induced Degradation of Lithium Electrodes for Batteries Beyond Lithium-Ion
journal, January 2014
- Woo, Jung-Je; Maroni, Victor A.; Liu, Gao
- Journal of The Electrochemical Society, Vol. 161, Issue 5
Cathode Materials for Lithium Battery Having Higher Performance
patent-application, January 2008
- Paulson, Jens M.; Park, Hong-Kyu; Shin, Sun Sik
- US Patent Application 11/688358; 20080026292
Multi-layered, chemically bonded lithium-ion and lithium/air batteries
patent, May 2014
- Narula, Chaitanya K.; Nanda, Jagjit; Bischoff, Brian L.
- US Patent Document 8,722,256
“Lithium-Free” Thin-Film Battery with In Situ Plated Li Anode
journal, January 2000
- Neudecker, B. J.; Dudney, N. J.; Bates, J. B.
- Journal of The Electrochemical Society, Vol. 147, Issue 2
Sodium Secondary Battery
patent-application, February 2013
- Kageura, Jun-ichi; Kuze, Satoru
- US Patent Application 13/588238; 20130052525
Buried anode lithium thin film battery and process for forming the same
patent, October 2004
- Lee, Se-Hee; Tracy, C. Edwin; Liu, Ping
- US Patent Document 6,805,999
Morphological Transitions on Lithium Metal Anodes
journal, January 2009
- López, Carmen M.; Vaughey, John T.; Dees, Dennis W.
- Journal of The Electrochemical Society, Vol. 156, Issue 9
Secondary Battery
patent-application, September 2016
- Kim, Young Sik; Kim, Jae Kwang; Jung, Mooyoung
- US Patent Application 15/162753; 20160268661
Solid-State Sodium-Based Secondary Cell Having a Sodium Ion Conductive Ceramic Separator
patent-application, May 2011
- Boxley, Chett; Coors, W. Grover; Watkins, John Joseph
- US Patent Application 12/940864; 20110104526
Lithium metal anodes for rechargeable batteries
journal, January 2014
- Xu, Wu; Wang, Jiulin; Ding, Fei
- Energy Environ. Sci., Vol. 7, Issue 2
Molten Salt Composition and Use Thereof
patent-application, August 2009
- Hagiwara, Rika; Matsumoto, Kazuhiko; Tamaki, Kenichiro
- US Patent Application 11/886781; 20090212743
Optimization of the lithium-ion cell electrolyte composition through the use of the LiTDI salt
journal, January 2014
- Niedzicki, L.; Karpierz, E.; Bitner, A.
- Electrochimica Acta, Vol. 117
Effects of High and Low Salt Concentration in Electrolytes at Lithium–Metal Anode Surfaces
journal, December 2016
- Camacho-Forero, Luis E.; Smith, Taylor W.; Balbuena, Perla B.
- The Journal of Physical Chemistry C, Vol. 121, Issue 1
The Application of Atomic Force Microscopy for the Study of Li Deposition Processes
journal, January 1996
- Aurbach, Doron
- Journal of The Electrochemical Society, Vol. 143, Issue 11
Active Substance for Electrode for a Sodium Ion Battery
patent-application, October 2015
- Senguttuvan, Premkumar; Palacin, Rose Maria; Tarascon, Jean-Marie
- US Patent Application 14/129,756; 2015/0295236 Al
A Highly Reversible Lithium Metal Anode
journal, January 2014
- Park, Min Sik; Ma, Sang Bok; Lee, Dong Joon
- Scientific Reports, Vol. 4, Issue 1
Microscopic observations of the formation, growth and shrinkage of lithium moss during electrodeposition and dissolution
journal, August 2014
- Steiger, Jens; Kramer, Dominik; Mönig, Reiner
- Electrochimica Acta, Vol. 136
Aliovalent Protective Layers for Active Metal Anodes
patent-application, December 2004
- Jonghe, Lutgard C. De; Nimon, Yevgeniy S.; Visco, Steven J.
- US Patent Application 10/861336; 20040253510
Rechargeable Seawater Battery and Its Electrochemical Mechanism
journal, November 2014
- Kim, Jae-Kwang; Lee, Eungje; Kim, Hyojin
- ChemElectroChem, Vol. 2, Issue 3
Secondary battery with electrolytic solution including a methylene cyclic carbonate, battery pack, electric vehicle, energy storage system, electric power tool, and electronic unit including the same
patent, January 2017
- Ihara, Masayuki; Kubota, Tadahiko
- US Patent Document 9,543,613
History, Evolution, and Future Status of Energy Storage
journal, May 2012
- Whittingham, M. S.
- Proceedings of the IEEE, Vol. 100, Issue Special Centennial Issue
Fabrication and characterization of amorphous lithium electrolyte thin films and rechargeable thin-film batteries
journal, March 1993
- Bates, J. B.; Dudney, N. J.; Gruzalski, G. R.
- Journal of Power Sources, Vol. 43, Issue 1-3, p. 103-110
High Energy Density Non-Aqueous Electrochemical Cell with Extended Operating Temperature Window
patent-application, December 2016
- Janakiraman, Umamaheswari; Ndzebet, Ernest; Destephen, Mario
- US Patent Application 14/054454; 20160359158
Thin film buried anode battery
patent, December 2009
- Lee, Se-Hee; Tracy, C. Edwin; Liu, Ping
- US Patent Document 7,632,602
High Voltage Lithium Ion Batteries Having Fluorinated Electrolytes and Lithium-Based Additives
patent-application, February 2015
- Zhang, Zhengcheng; Hu, Libo; Amine, Khalil
- US Patent Application 13/969134; 20150050561
Thin-film rechargeable lithium batteries
journal, March 1995
- Bates, J. B.; Dudney, N. J.; Lubben, D. C.
- Journal of Power Sources, Vol. 54, Issue 1, p. 58-62