Procedures for the synthesis of ethylenediamine bisborane and ammonia borane

Ramachandran, Padi Veeraraghavan; Gagare, Pravin D.; Mistry, Hitesh; Biswas, Bidyut

Procedures for the synthesis of ethylenediamine bisborane and ammonia borane

Patent · Mon Jan 02 23:00:00 EST 2017

OSTI ID:1338064

Ramachandran, Padi Veeraraghavan; Gagare, Pravin D.; Mistry, Hitesh; Biswas, Bidyut

A method for synthesizing ammonia borane includes (a) preparing a reaction mixture in one or more solvents, the reaction mixture containing sodium borohydride, at least one ammonium salt, and ammonia; and (b) incubating the reaction mixture at temperatures between about 0.degree. C. to about room temperature in an ambient air environment under conditions sufficient to form ammonia borane. Methods for synthesizing ethylenediamine bisborane, and methods for dehydrogenation of ethylenediamine bisborane are also described.

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Research Organization:: PURDUE RESEARCH FOUNDATION, West Lafayette, IN (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: FG36-06GO86050

Assignee:: PURDUE RESEARCH FOUNDATION (West Lafayette, IN)

Patent Number(s):: 9,534,002

Application Number:: 13/809,316

OSTI ID:: 1338064

Country of Publication:: United States

Language:: English

References (14)

Synthesis of ammonia borane for hydrogen storage applications Heldebrant, David J.; Karkamkar, Abhi; Linehan, John C. Energy & Environmental Science, Vol. 1, Issue 1, p. 156-160 https://doi.org/10.1039/B808865A	journal	January 2008
Efficient Regeneration of Partially Spent Ammonia Borane Fuel Davis, Benjamin L.; Dixon, David A.; Garner, Edward B. Angewandte Chemie International Edition, Vol. 48, Issue 37, p. 6812-6816 https://doi.org/10.1002/anie.200900680	journal	September 2009
Iridium-Catalyzed Dehydrogenation of Substituted Amine Boranes: Kinetics, Thermodynamics, and Implications for Hydrogen Storage Dietrich, Brandon L.; Goldberg, Karen I.; Heinekey, D. Michael Inorganic Chemistry, Vol. 47, Issue 19, p. 8583-8585 https://doi.org/10.1021/ic801161g	journal	October 2008
B–N compounds for chemical hydrogenstorage Hamilton, Charles W.; Baker, R. Tom; Staubitz, Anne Chem. Soc. Rev., Vol. 38, Issue 1, p. 279-293 https://doi.org/10.1039/B800312M	journal	January 2009
Ammonia Borane Hydrogen Release in Ionic Liquids Himmelberger, Daniel W.; Alden, Laif R.; Bluhm, Martin E. Inorganic Chemistry, Vol. 48, Issue 20, p. 9883-9889 https://doi.org/10.1021/ic901560h	journal	October 2009
Will We Soon Be Fueling our Automobiles with Ammonia–Borane? Marder, Todd B. Angewandte Chemie International Edition, Vol. 46, Issue 43, p. 8116-8118 https://doi.org/10.1002/anie.200703150	journal	November 2007
Diaminomethane dihydrochloride, a novel reagent for the synthesis of primary amides of amino acids and peptides from active esters Galaverna, Gianni; Corradini, Roberto; Dossena, Arnaldo International Journal of Peptide and Protein Research, Vol. 42, Issue 1, p. 53-57 https://doi.org/10.1111/j.1399-3011.1993.tb00349.x	journal	July 1993
A Soft Hydrogen Storage Material: Poly(Methyl Acrylate)-Confined Ammonia Borane with Controllable Dehydrogenation Zhao, Jianzhi; Shi, Jifu; Zhang, Xiaowei Advanced Materials, Vol. 22, Issue 3, p. 394-397 https://doi.org/10.1002/adma.200902174	journal	January 2010
Ammonia–borane: the hydrogen source par excellence? Stephens, Frances H.; Pons, Vincent; Tom Baker, R. Dalton Trans., Issue 25, p. 2613-2626 https://doi.org/10.1039/B703053C	journal	January 2007
Ethane 1,2-Diamineborane Kelly, Henry C.; Edwards, John O. Journal of the American Chemical Society, Vol. 82, Issue 18, p. 4842-4846 https://doi.org/10.1021/ja01503a023	journal	September 1960
Ammonia Borane and Related Compounds as Hydrogen Source Materials Mertens, Florian; Wolf, Gert; Baitalow, Felix Handbook of Hydrogen Storage New Materials for Future Energy Storage https://doi.org/10.1002/9783527629800.ch8	book	March 2010
Ammonia Borane as a Hydrogen Carrier: Dehydrogenation and Regeneration Smythe, Nathan C.; Gordon, John C. European Journal of Inorganic Chemistry, Vol. 2010, Issue 4, p. 509-521 https://doi.org/10.1002/ejic.200900932	journal	February 2010
Preparation of Ammonia Borane in High Yield and Purity, Methanolysis, and Regeneration Ramachandran, P. Veeraraghavan; Gagare, Pravin D. Inorganic Chemistry, Vol. 46, Issue 19, p. 7810-7817 https://doi.org/10.1021/ic700772a	journal	September 2007
Amine− and Phosphine−Borane Adducts: New Interest in Old Molecules Staubitz, Anne; Robertson, Alasdair P. M.; Sloan, Matthew E. Chemical Reviews, Vol. 110, Issue 7, p. 4023-4078 https://doi.org/10.1021/cr100105a	journal	July 2010

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Procedures for the synthesis of ethylenediamine bisborane and ammonia borane

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