Composite oxygen transport membrane

Lu, Zigui; Plonczak, Pawel J.; Lane, Jonathan A.

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A - human necessities
A01 - agriculture
A21 - baking
A22 - butchering
A23 - foods or foodstuffs
A24 - tobacco
A41 - wearing apparel
A42 - headwear
A43 - footwear
A44 - haberdashery
A45 - hand or travelling articles
A46 - brushware
A47 - furniture
A61 - medical or veterinary science
A62 - life-saving
A63 - sports
A99 - subject matter not otherwise provided for in this section
B - performing operations
B01 - physical or chemical processes or apparatus in general
B02 - crushing, pulverising, or disintegrating
B03 - separation of solid materials using liquids or using pneumatic tables or jigs
B04 - centrifugal apparatus or machines for carrying-out physical or chemical processes
B05 - spraying or atomising in general
B06 - generating or transmitting mechanical vibrations in general
B07 - separating solids from solids
B08 - cleaning
B09 - disposal of solid waste
B21 - mechanical metal-working without essentially removing material
B22 - casting
B23 - machine tools
B24 - grinding
B25 - hand tools
B26 - hand cutting tools
B27 - working or preserving wood or similar material
B28 - working cement, clay, or stone
B29 - working of plastics
B30 - presses
B31 - making articles of paper, cardboard or material worked in a manner analogous to paper
B32 - layered products
B33 - additive manufacturing technology
B41 - printing
B42 - bookbinding
B43 - writing or drawing implements
B44 - decorative arts
B60 - vehicles in general
B61 - railways
B62 - land vehicles for travelling otherwise than on rails
B63 - ships or other waterborne vessels
B64 - aircraft
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B66 - hoisting
B67 - opening, closing {or cleaning} bottles, jars or similar containers
B68 - saddlery
B81 - microstructural technology
B82 - nanotechnology
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C01 - inorganic chemistry
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C03 - glass
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C12 - biochemistry
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C22 - metallurgy
C23 - coating metallic material
C25 - electrolytic or electrophoretic processes
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D - textiles
D01 - natural or man-made threads or fibres
D02 - yarns
D03 - weaving
D04 - braiding
D05 - sewing
D06 - treatment of textiles or the like
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D10 - indexing scheme associated with sublasses of section d, relating to textiles
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E01 - construction of roads, railways, or bridges
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F01 - machines or engines in general
F02 - combustion engines
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F17 - storing or distributing gases or liquids
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F22 - steam generation
F23 - combustion apparatus
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F28 - heat exchange in general
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F42 - ammunition
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G - physics
G01 - measuring
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G16 - information and communication technology [ict] specially adapted for specific application fields
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H01 - basic electric elements
H02 - generation
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Y02 - technologies or applications for mitigation or adaptation against climate change
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Title: Composite oxygen transport membrane

Abstract

A method is described of producing a composite oxygen ion membrane and a composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln.sub.1-xA.sub.x).sub.wCr.sub.1-yB.sub.yO.sub.3-.delta. and a doped zirconia. Preferred materials are (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.7Fe.sub.0.3O.sub.3-.delta. for the porous fuel oxidation layer, (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.5Fe.sub.0.5O.sub.3-.delta. for the dense separation layer, and (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.3Fe.sub.0.7O.sub.3-.delta. for the porous surface exchange layer. Firing the said fuel activation and separation layers in nitrogen atmosphere unexpectedly allows the separation layer to sinter into a fully densified mass.

Inventors:: Lu, Zigui; Plonczak, Pawel J.; Lane, Jonathan A.

Issue Date:: Tue Nov 08 00:00:00 EST 2016

Research Org.:: PRAXAIR TECHNOLOGY, INC. Danbury, CT (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1331385

Patent Number(s):: 9486735

Application Number:: 14/856,038

Assignee:: PRAXAIR TECHNOLOGY, INC. (Danbury, CT)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

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B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B01D2255/204 - Alkaline earth metals
B01D2255/2063 - Lanthanum
B01D2255/20738 - Iron
B01D2255/20784 - Chromium
B01D2255/40 - Mixed oxides
B01D2255/402 - Perovskites
B01D2255/407 - Zr-Ce mixed oxides
B01D2255/902 - Multilayered catalyst
B01D2256/12 - Oxygen
B01D2257/104 - Oxygen
B01D2258/06 - Polluted air
B01D2325/023 - Dense layer within the membrane
B01D53/228 - {characterised by specific membranes}
B01D67/0041 - {by agglomeration of particles in the dry state, e.g. sintering}
B01D69/02 - characterised by their properties
B01D69/12 - Composite membranes
B01D71/024 - {Oxides}
B01D71/028 - {Molecular sieves, e.g. zeolites, silicalite

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J19/2475 - {Membrane reactors}
B01J2219/24 - Stationary reactors without moving elements inside

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B13/0255 - {characterised by the type of membrane}

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B2111/00612 - {as one or more layers of a layered structure}
C04B2111/00801 - {Membranes
C04B2111/0081 - {as catalysts or catalyst carriers}
C04B2235/3208 - Calcium oxide or oxide-forming salts thereof, e.g. lime
C04B2235/3217 - Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
C04B2235/3222 - Aluminates other than alumino-silicates, e.g. spinel
C04B2235/3224 - Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
C04B2235/3225 - Yttrium oxide or oxide-forming salts thereof
C04B2235/3227 - Lanthanum oxide or oxide-forming salts thereof
C04B2235/3229 - Cerium oxides or oxide-forming salts thereof
C04B2235/3232 - Titanium oxides or titanates, e.g. rutile or anatase
C04B2235/3234 - Titanates, not containing zirconia
C04B2235/3243 - Chromates or chromites, e.g. aluminum chromate, lanthanum strontium chromite
C04B2235/3246 - Stabilised zirconias, e.g. YSZ or cerium stabilised zirconia
C04B2235/3262 - Manganese oxides, manganates, rhenium oxides or oxide-forming salts thereof, e.g. MnO
C04B2235/3268 - Manganates, manganites, rhenates or rhenites, e.g. lithium manganite, barium manganate, rhenium oxide
C04B2235/3272 - Iron oxides or oxide forming salts thereof, e.g. hematite, magnetite
C04B2235/3274 - Ferrites
C04B2235/3275 - Cobalt oxides, cobaltates or cobaltites or oxide forming salts thereof, e.g. bismuth cobaltate, zinc cobaltite
C04B2235/5445 - submicron sized, i.e. from 0,1 to 1 micron
C04B2235/768 - Perovskite structure ABO3
C04B2235/80 - Phases present in the sintered or melt-cast ceramic products other than the main phase
C04B35/01 - based on oxide ceramics
C04B35/016 - {based on manganites}
C04B35/2633 - {containing barium, strontium or calcium}
C04B35/42 - based on chromites
C04B35/44 - based on aluminates
C04B35/462 - based on titanates
C04B35/48 - based on zirconium or hafnium oxides, zirconates, {zircon} or hafnates
C04B35/488 - Composites
C04B38/0074 - {expressed as porosity percentage}
C04B38/02 - by adding chemical blowing agents

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T428/1314 - Contains fabric, fiber particle, or filament made of glass, ceramic, or sintered, fused, fired, or calcined metal oxide, or metal carbide or other inorganic compound [e.g., fiber glass, mineral fiber, sand, etc.]
Y10T428/24997 - Of metal-containing material
Y10T428/24999 - Inorganic

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DOE Contract Number:: FC26-07NT43088

Resource Type:: Patent

Resource Relation:: Patent File Date: 2015 Sep 16

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE

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                    Lu, Zigui, Plonczak, Pawel J., and Lane, Jonathan A. Composite oxygen transport membrane.  United States: N. p., 2016. 
        Web.

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                    Lu, Zigui, Plonczak, Pawel J., & Lane, Jonathan A. Composite oxygen transport membrane.  United States.

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                    Lu, Zigui, Plonczak, Pawel J., and Lane, Jonathan A. Tue .  
        "Composite oxygen transport membrane".  United States.  https://www.osti.gov/servlets/purl/1331385.

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@article{osti_1331385,

  title        = {Composite oxygen transport membrane},

  author       = {Lu, Zigui and Plonczak, Pawel J. and Lane, Jonathan A.},

  abstractNote = {A method is described of producing a composite oxygen ion membrane and a composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln.sub.1-xA.sub.x).sub.wCr.sub.1-yB.sub.yO.sub.3-.delta. and a doped zirconia. Preferred materials are (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.7Fe.sub.0.3O.sub.3-.delta. for the porous fuel oxidation layer, (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.5Fe.sub.0.5O.sub.3-.delta. for the dense separation layer, and (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.3Fe.sub.0.7O.sub.3-.delta. for the porous surface exchange layer. Firing the said fuel activation and separation layers in nitrogen atmosphere unexpectedly allows the separation layer to sinter into a fully densified mass.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Tue Nov 08 00:00:00 EST 2016},

  month        = {Tue Nov 08 00:00:00 EST 2016}

}

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Works referenced in this record:

Development of interconnect materials for solid oxide fuel cells
journal, May 2003

Zhu, W. Z.; Deevi, S. C.
Materials Science and Engineering: A, Vol. 348, Issue 1-2, p. 227-243
https://doi.org/10.1016/S0921-5093(02)00736-0

Development of oxygen transport membranes for coal-based power generation
journal, January 2011

Rosen, Lee; Degenstein, Nick; Shah, Minish
Energy Procedia, Vol. 4, p. 750-755
https://doi.org/10.1016/j.egypro.2011.01.115

Efficient Reduction of CO₂ in a Solid Oxide Electrolyzer
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Bidrawn, F.; Kim, G.; Corre, G.
Electrochemical and Solid-State Letters, Vol. 11, Issue 9, p. B167-B170
https://doi.org/10.1149/1.2943664

Electrolysis of carbon dioxide in Solid Oxide Electrolysis Cells
journal, August 2009

Ebbesen, Sune Dalgaard; Mogensen, Mogens
Journal of Power Sources, Vol. 193, Issue 1, p. 349-358
https://doi.org/10.1016/j.jpowsour.2009.02.093

Freeze-Casting of Porous Ceramics: A Review of Current Achievements and Issues
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Deville, S.
Advanced Engineering Materials, Vol. 10, Issue 3, p. 155-169
https://doi.org/10.1002/adem.200700270

Ion transport membrane technology for oxygen separation and syngas production
journal, October 2000

Dyer, Paul N.; Richards, Robin E.; Russek, Steven L.
Solid State Ionics, Vol. 134, Issue 1-2, p. 21-33
https://doi.org/10.1016/S0167-2738(00)00710-4

Methods for the catalytic activation of metallic structured substrates
journal, January 2014

Montebelli, Andrea; Visconti, Carlo Giorgio; Groppi, Gianpiero
Catalysis Science & Technology, Vol. 4, Issue 9, p. 2846-2870
https://doi.org/10.1039/C4CY00179F

Thermomechanical, transport and anodic properties of perovskite-type (La_0.75Sr_0.25)_0.95Cr_1−xFe_xO_3−δ
journal, May 2012

Lü, M. F.; Tsipis, E. V.; Waerenborgh, J. C.
Journal of Power Sources, Vol. 206, p. 59-69
https://doi.org/10.1016/j.jpowsour.2012.01.100

Tubular zirconia–yttria electrolyte membrane technology for oxygen separation
journal, December 2002

Ciacchi, F. T.; Badwal, S. P. S.; Zelizko, V.
Solid State Ionics, Vol. 152-153, p. 763-768
https://doi.org/10.1016/S0167-2738(02)00323-5

Stoichiometric lanthanum chromite based ceramic interconnects with low sintering temperature
journal, March 2006

Zhong, Z.
Solid State Ionics, Vol. 177, Issue 7-8, p. 757-764
https://doi.org/10.1016/j.ssi.2006.01.023

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Similar Records

Title: Composite oxygen transport membrane

Abstract

Citation Formats

Development of interconnect materials for solid oxide fuel cells journal, May 2003

Development of oxygen transport membranes for coal-based power generation journal, January 2011

Efficient Reduction of CO2 in a Solid Oxide Electrolyzer journal, January 2008

Electrolysis of carbon dioxide in Solid Oxide Electrolysis Cells journal, August 2009

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Methods for the catalytic activation of metallic structured substrates journal, January 2014

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Development of interconnect materials for solid oxide fuel cells
journal, May 2003

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journal, March 2008

Ion transport membrane technology for oxygen separation and syngas production
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