Composite oxygen transport membrane

Lu, Zigui; Plonczak, Pawel J.; Lane, Jonathan A.

Title: Composite oxygen transport membrane

Abstract

A method is described of producing a composite oxygen ion membrane and a composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln.sub.1-xA.sub.x).sub.wCr.sub.1-yB.sub.yO.sub.3-.delta. and a doped zirconia. Preferred materials are (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.7Fe.sub.0.3O.sub.3-.delta. for the porous fuel oxidation layer, (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.5Fe.sub.0.5O.sub.3-.delta. for the dense separation layer, and (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.3Fe.sub.0.7O.sub.3-.delta. for the porous surface exchange layer. Firing the said fuel activation and separation layers in nitrogen atmosphere unexpectedly allows the separation layer to sinter into a fully densified mass.

Inventors:: Lu, Zigui; Plonczak, Pawel J.; Lane, Jonathan A.

Issue Date:: 2016-11-08

Research Org.:: PRAXAIR TECHNOLOGY, INC. Danbury, CT (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1331385

Patent Number(s):: 9486735

Application Number:: 14/856,038

Assignee:: PRAXAIR TECHNOLOGY, INC. (Danbury, CT)

Patent Classifications (CPCs):: C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

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C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B38/02 - by adding chemical blowing agents
C04B2111/00801 - {Membranes
C04B35/44 - based on aluminates

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T428/24997 - Of metal-containing material

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B2235/80 - Phases present in the sintered or melt-cast ceramic products other than the main phase
C04B35/2633 - {containing barium, strontium or calcium}

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J19/2475 - {Membrane reactors}

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B35/462 - based on titanates
C04B2235/3217 - Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B01D2255/20784 - Chromium
B01D69/02 - characterised by their properties

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B2235/3275 - Cobalt oxides, cobaltates or cobaltites or oxide forming salts thereof, e.g. bismuth cobaltate, zinc cobaltite

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T428/1314 - Contains fabric, fiber particle, or filament made of glass, ceramic, or sintered, fused, fired, or calcined metal oxide, or metal carbide or other inorganic compound [e.g., fiber glass, mineral fiber, sand, etc.]

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B2235/5445 - submicron sized, i.e. from 0,1 to 1 micron
C04B2235/3234 - Titanates, not containing zirconia
C04B2235/3222 - Aluminates other than alumino-silicates, e.g. spinel
C04B2111/0081 - {as catalysts or catalyst carriers}

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B01D71/028 - {Molecular sieves, e.g. zeolites, silicalite

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B2235/3268 - Manganates, manganites, rhenates or rhenites, e.g. lithium manganite, barium manganate, rhenium oxide
C04B2235/3229 - Cerium oxides or oxide-forming salts thereof

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B01D2255/902 - Multilayered catalyst

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B2235/3232 - Titanium oxides or titanates, e.g. rutile or anatase
C04B35/488 - Composites
C04B2235/3224 - Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B13/0255 - {characterised by the type of membrane}

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B01D2255/40 - Mixed oxides

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B35/48 - based on zirconium or hafnium oxides, zirconates, {zircon} or hafnates

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B01D2255/407 - Zr-Ce mixed oxides

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B35/01 - based on oxide ceramics

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J2219/24 - Stationary reactors without moving elements inside

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B01D2258/06 - Polluted air

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B2235/3246 - Stabilised zirconias, e.g. YSZ or cerium stabilised zirconia

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B01D2325/023 - Dense layer within the membrane

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B35/016 - {based on manganites}

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B01D69/12 - Composite membranes

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B2235/3272 - Iron oxides or oxide forming salts thereof, e.g. hematite, magnetite
C04B2235/3227 - Lanthanum oxide or oxide-forming salts thereof

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B01D2255/20738 - Iron

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B35/42 - based on chromites
C04B2111/00612 - {as one or more layers of a layered structure}

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B01D2255/204 - Alkaline earth metals
B01D2256/12 - Oxygen
B01D2255/2063 - Lanthanum

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B2235/3274 - Ferrites
C04B2235/3208 - Calcium oxide or oxide-forming salts thereof, e.g. lime

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B01D71/024 - {Oxides}

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B2235/3225 - Yttrium oxide or oxide-forming salts thereof

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B01D2255/402 - Perovskites
B01D53/228 - {characterised by specific membranes}

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B2235/3262 - Manganese oxides, manganates, rhenium oxides or oxide-forming salts thereof, e.g. MnO
C04B2235/768 - Perovskite structure ABO3

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B01D67/0041 - {by agglomeration of particles in the dry state, e.g. sintering}
B01D2257/104 - Oxygen

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B38/0074 - {expressed as porosity percentage}
C04B2235/3243 - Chromates or chromites, e.g. aluminum chromate, lanthanum strontium chromite

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T428/24999 - Inorganic

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DOE Contract Number:: FC26-07NT43088

Resource Type:: Patent

Resource Relation:: Patent File Date: 2015 Sep 16

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE

Citation Formats


                    Lu, Zigui, Plonczak, Pawel J., and Lane, Jonathan A. Composite oxygen transport membrane.  United States: N. p., 2016. 
        Web.

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                    Lu, Zigui, Plonczak, Pawel J., & Lane, Jonathan A. Composite oxygen transport membrane.  United States.

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                    Lu, Zigui, Plonczak, Pawel J., and Lane, Jonathan A. Tue .  
        "Composite oxygen transport membrane".  United States.  https://www.osti.gov/servlets/purl/1331385.

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@article{osti_1331385,

  title        = {Composite oxygen transport membrane},

  author       = {Lu, Zigui and Plonczak, Pawel J. and Lane, Jonathan A.},

  abstractNote = {A method is described of producing a composite oxygen ion membrane and a composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln.sub.1-xA.sub.x).sub.wCr.sub.1-yB.sub.yO.sub.3-.delta. and a doped zirconia. Preferred materials are (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.7Fe.sub.0.3O.sub.3-.delta. for the porous fuel oxidation layer, (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.5Fe.sub.0.5O.sub.3-.delta. for the dense separation layer, and (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.3Fe.sub.0.7O.sub.3-.delta. for the porous surface exchange layer. Firing the said fuel activation and separation layers in nitrogen atmosphere unexpectedly allows the separation layer to sinter into a fully densified mass.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2016},

  month        = {11}

}

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Works referenced in this record:

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journal, May 2003

Zhu, W. Z.; Deevi, S. C.
Materials Science and Engineering: A, Vol. 348, Issue 1-2, p. 227-243
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Ion transport membrane technology for oxygen separation and syngas production
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Dyer, Paul N.; Richards, Robin E.; Russek, Steven L.
Solid State Ionics, Vol. 134, Issue 1-2, p. 21-33
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Methods for the catalytic activation of metallic structured substrates
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Catalysis Science & Technology, Vol. 4, Issue 9, p. 2846-2870
https://doi.org/10.1039/C4CY00179F

Thermomechanical, transport and anodic properties of perovskite-type (La_0.75Sr_0.25)_0.95Cr_1−xFe_xO_3−δ
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Lü, M. F.; Tsipis, E. V.; Waerenborgh, J. C.
Journal of Power Sources, Vol. 206, p. 59-69
https://doi.org/10.1016/j.jpowsour.2012.01.100

Tubular zirconia–yttria electrolyte membrane technology for oxygen separation
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Ciacchi, F. T.; Badwal, S. P. S.; Zelizko, V.
Solid State Ionics, Vol. 152-153, p. 763-768
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Stoichiometric lanthanum chromite based ceramic interconnects with low sintering temperature
journal, March 2006

Zhong, Z.
Solid State Ionics, Vol. 177, Issue 7-8, p. 757-764
https://doi.org/10.1016/j.ssi.2006.01.023

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Similar Records

Title: Composite oxygen transport membrane

Abstract

Citation Formats

Development of interconnect materials for solid oxide fuel cells journal, May 2003

Development of oxygen transport membranes for coal-based power generation journal, January 2011

Efficient Reduction of CO2 in a Solid Oxide Electrolyzer journal, January 2008

Electrolysis of carbon dioxide in Solid Oxide Electrolysis Cells journal, August 2009

Freeze-Casting of Porous Ceramics: A Review of Current Achievements and Issues journal, March 2008

Ion transport membrane technology for oxygen separation and syngas production journal, October 2000

Methods for the catalytic activation of metallic structured substrates journal, January 2014

Thermomechanical, transport and anodic properties of perovskite-type (La0.75Sr0.25)0.95Cr1−xFexO3−δ journal, May 2012

Tubular zirconia–yttria electrolyte membrane technology for oxygen separation journal, December 2002

Stoichiometric lanthanum chromite based ceramic interconnects with low sintering temperature journal, March 2006

Development of interconnect materials for solid oxide fuel cells
journal, May 2003

Development of oxygen transport membranes for coal-based power generation
journal, January 2011

Efficient Reduction of CO₂ in a Solid Oxide Electrolyzer
journal, January 2008

Electrolysis of carbon dioxide in Solid Oxide Electrolysis Cells
journal, August 2009

Freeze-Casting of Porous Ceramics: A Review of Current Achievements and Issues
journal, March 2008

Ion transport membrane technology for oxygen separation and syngas production
journal, October 2000

Methods for the catalytic activation of metallic structured substrates
journal, January 2014

Thermomechanical, transport and anodic properties of perovskite-type (La_0.75Sr_0.25)_0.95Cr_1−xFe_xO_3−δ
journal, May 2012

Tubular zirconia–yttria electrolyte membrane technology for oxygen separation
journal, December 2002

Stoichiometric lanthanum chromite based ceramic interconnects with low sintering temperature
journal, March 2006