Composite oxygen transport membrane

Christie, Gervase Maxwell; Lane, Jonathan A.

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A - human necessities
A01 - agriculture
A21 - baking
A22 - butchering
A23 - foods or foodstuffs
A24 - tobacco
A41 - wearing apparel
A42 - headwear
A43 - footwear
A44 - haberdashery
A45 - hand or travelling articles
A46 - brushware
A47 - furniture
A61 - medical or veterinary science
A62 - life-saving
A63 - sports
A99 - subject matter not otherwise provided for in this section
B - performing operations
B01 - physical or chemical processes or apparatus in general
B02 - crushing, pulverising, or disintegrating
B03 - separation of solid materials using liquids or using pneumatic tables or jigs
B04 - centrifugal apparatus or machines for carrying-out physical or chemical processes
B05 - spraying or atomising in general
B06 - generating or transmitting mechanical vibrations in general
B07 - separating solids from solids
B08 - cleaning
B09 - disposal of solid waste
B21 - mechanical metal-working without essentially removing material
B22 - casting
B23 - machine tools
B24 - grinding
B25 - hand tools
B26 - hand cutting tools
B27 - working or preserving wood or similar material
B28 - working cement, clay, or stone
B29 - working of plastics
B30 - presses
B31 - making articles of paper, cardboard or material worked in a manner analogous to paper
B32 - layered products
B33 - additive manufacturing technology
B41 - printing
B42 - bookbinding
B43 - writing or drawing implements
B44 - decorative arts
B60 - vehicles in general
B61 - railways
B62 - land vehicles for travelling otherwise than on rails
B63 - ships or other waterborne vessels
B64 - aircraft
B65 - conveying
B66 - hoisting
B67 - opening, closing {or cleaning} bottles, jars or similar containers
B68 - saddlery
B81 - microstructural technology
B82 - nanotechnology
B99 - subject matter not otherwise provided for in this section
C - chemistry
C01 - inorganic chemistry
C02 - treatment of water, waste water, sewage, or sludge
C03 - glass
C04 - cements
C05 - fertilisers
C06 - explosives
C07 - organic chemistry
C08 - organic macromolecular compounds
C09 - dyes
C10 - petroleum, gas or coke industries
C11 - animal or vegetable oils, fats, fatty substances or waxes
C12 - biochemistry
C13 - sugar industry
C14 - skins
C21 - metallurgy of iron
C22 - metallurgy
C23 - coating metallic material
C25 - electrolytic or electrophoretic processes
C30 - crystal growth
C40 - combinatorial technology
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D - textiles
D01 - natural or man-made threads or fibres
D02 - yarns
D03 - weaving
D04 - braiding
D05 - sewing
D06 - treatment of textiles or the like
D07 - ropes
D10 - indexing scheme associated with sublasses of section d, relating to textiles
D21 - paper-making
D99 - subject matter not otherwise provided for in this section
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E01 - construction of roads, railways, or bridges
E02 - hydraulic engineering
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E04 - building
E05 - locks
E06 - doors, windows, shutters, or roller blinds in general
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F - mechanical engineering
F01 - machines or engines in general
F02 - combustion engines
F03 - machines or engines for liquids
F04 - positive - displacement machines for liquids
F05 - indexing schemes relating to engines or pumps in various subclasses of classes f01-f04
F15 - fluid-pressure actuators
F16 - engineering elements and units
F17 - storing or distributing gases or liquids
F21 - lighting
F22 - steam generation
F23 - combustion apparatus
F24 - heating
F25 - refrigeration or cooling
F26 - drying
F27 - furnaces
F28 - heat exchange in general
F41 - weapons
F42 - ammunition
F99 - subject matter not otherwise provided for in this section
G - physics
G01 - measuring
G02 - optics
G03 - photography
G04 - horology
G05 - controlling
G06 - computing
G07 - checking-devices
G08 - signalling
G09 - education
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G11 - information storage
G12 - instrument details
G16 - information and communication technology [ict] specially adapted for specific application fields
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H - electricity
H01 - basic electric elements
H02 - generation
H03 - basic electronic circuitry
H04 - electric communication technique
H05 - electric techniques not otherwise provided for
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Y02 - technologies or applications for mitigation or adaptation against climate change
Y04 - information or communication technologies having an impact on other technology areas
Y10 - technical subjects covered by former uspc

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Title: Composite oxygen transport membrane

Abstract

A method of producing a composite oxygen ion membrane and a composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln.sub.1-xA.sub.x).sub.wCr.sub.1-yB.sub.yO.sub.3-.delta. and a doped zirconia. In the porous fuel oxidation layer and the optional porous surface exchange layer, A is Calcium and in the dense separation layer A is not Calcium and, preferably is Strontium. Preferred materials are (La.sub.0.8Ca.sub.0.2).sub.0.95Cr.sub.0.5Mn.sub.0.5O.sub.3-.delta. for the porous fuel oxidation and optional porous surface exchange layers and (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.5Fe.sub.0.5O.sub.3-.delta. for the dense separation layer. The use of such materials allows the membrane to sintered in air and without the use of pore formers to reduce membrane manufacturing costs. The use of materials, as described herein, for forming the porous layers have application for forming any type of porous structure, such as a catalyst support.

Inventors:: Christie, Gervase Maxwell; Lane, Jonathan A.

Issue Date:: 2014-08-05

Research Org.:: National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1150016

Patent Number(s):: 8795417

Application Number:: 13/644,666

Assignee:: Praxair Technology, Inc. (Danbury, CT)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS

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B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B01D2255/402 - Perovskites
B01D2255/407 - Zr-Ce mixed oxides
B01D2255/902 - Multilayered catalyst
B01D2256/12 - Oxygen
B01D2257/104 - Oxygen
B01D2258/06 - Polluted air
B01D2325/023 - Dense layer within the membrane
B01D53/228 - {characterised by specific membranes}
B01D67/0041 - {by agglomeration of particles in the dry state, e.g. sintering}
B01D69/02 - characterised by their properties
B01D69/12 - Composite membranes
B01D71/024 - {Oxides}
B01D71/028 - {Molecular sieves, e.g. zeolites, silicalite

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B13/0255 - {characterised by the type of membrane}

C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C04B2111/00612 - {as one or more layers of a layered structure}
C04B2111/00801 - {Membranes
C04B2111/0081 - {as catalysts or catalyst carriers}
C04B2235/3208 - Calcium oxide or oxide-forming salts thereof, e.g. lime
C04B2235/3217 - Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
C04B2235/3222 - Aluminates other than alumino-silicates, e.g. spinel
C04B2235/3224 - Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
C04B2235/3225 - Yttrium oxide or oxide-forming salts thereof
C04B2235/3227 - Lanthanum oxide or oxide-forming salts thereof
C04B2235/3229 - Cerium oxides or oxide-forming salts thereof
C04B2235/3232 - Titanium oxides or titanates, e.g. rutile or anatase
C04B2235/3234 - Titanates, not containing zirconia
C04B2235/3243 - Chromates or chromites, e.g. aluminum chromate, lanthanum strontium chromite
C04B2235/3246 - Stabilised zirconias, e.g. YSZ or cerium stabilised zirconia
C04B2235/3262 - Manganese oxides, manganates, rhenium oxides or oxide-forming salts thereof, e.g. MnO
C04B2235/3268 - Manganates, manganites, rhenates or rhenites, e.g. lithium manganite, barium manganate, rhenium oxide
C04B2235/3272 - Iron oxides or oxide forming salts thereof, e.g. hematite, magnetite
C04B2235/3274 - Ferrites
C04B2235/3275 - Cobalt oxides, cobaltates or cobaltites or oxide forming salts thereof, e.g. bismuth cobaltate, zinc cobaltite
C04B2235/5445 - submicron sized, i.e. from 0,1 to 1 micron
C04B2235/768 - Perovskite structure ABO3
C04B2235/80 - Phases present in the sintered or melt-cast ceramic products other than the main phase
C04B35/01 - based on oxide ceramics
C04B35/016 - {based on manganites}
C04B35/04 - based on magnesium oxide
C04B35/2633 - {containing barium, strontium or calcium}
C04B35/42 - based on chromites
C04B35/44 - based on aluminates
C04B35/443 - Magnesium aluminate spinel
C04B35/462 - based on titanates
C04B35/48 - based on zirconium or hafnium oxides, zirconates, {zircon} or hafnates
C04B35/488 - Composites
C04B38/00 - Porous mortars, concrete, artificial stone or ceramic ware
C04B38/0074 - {expressed as porosity percentage}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T428/1314 - Contains fabric, fiber particle, or filament made of glass, ceramic, or sintered, fused, fired, or calcined metal oxide, or metal carbide or other inorganic compound [e.g., fiber glass, mineral fiber, sand, etc.]
Y10T428/24997 - Of metal-containing material
Y10T428/24999 - Inorganic

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DOE Contract Number:: FC26-07NT43088

Resource Type:: Patent

Resource Relation:: Patent File Date: 2012 Oct 04

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

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                    Christie, Gervase Maxwell, and Lane, Jonathan A. Composite oxygen transport membrane.  United States: N. p., 2014. 
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                    Christie, Gervase Maxwell, & Lane, Jonathan A. Composite oxygen transport membrane.  United States.

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                    Christie, Gervase Maxwell, and Lane, Jonathan A. Tue .  
        "Composite oxygen transport membrane".  United States.  https://www.osti.gov/servlets/purl/1150016.

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@article{osti_1150016,

  title        = {Composite oxygen transport membrane},

  author       = {Christie, Gervase Maxwell and Lane, Jonathan A.},

  abstractNote = {A method of producing a composite oxygen ion membrane and a composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln.sub.1-xA.sub.x).sub.wCr.sub.1-yB.sub.yO.sub.3-.delta. and a doped zirconia. In the porous fuel oxidation layer and the optional porous surface exchange layer, A is Calcium and in the dense separation layer A is not Calcium and, preferably is Strontium. Preferred materials are (La.sub.0.8Ca.sub.0.2).sub.0.95Cr.sub.0.5Mn.sub.0.5O.sub.3-.delta. for the porous fuel oxidation and optional porous surface exchange layers and (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.5Fe.sub.0.5O.sub.3-.delta. for the dense separation layer. The use of such materials allows the membrane to sintered in air and without the use of pore formers to reduce membrane manufacturing costs. The use of materials, as described herein, for forming the porous layers have application for forming any type of porous structure, such as a catalyst support.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2014},

  month        = {8}

}

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