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Title: Catalysts for converting syngas into liquid hydrocarbons and methods thereof

The presently-disclosed subject matter includes methods for producing liquid hydrocarbons from syngas. In some embodiments the syngas is obtained from biomass and/or comprises a relatively high amount of nitrogen and/or carbon dioxide. In some embodiments the present methods can convert syngas into liquid hydrocarbons through a one-stage process. Also provided are catalysts for producing liquid hydrocarbons from syngas, wherein the catalysts include a base material, a transition metal, and a promoter. In some embodiments the base material includes a zeolite-iron material or a cobalt-molybdenum carbide material. In still further embodiments the promoter can include an alkali metal.
Inventors:
; ;
Issue Date:
OSTI Identifier:
1243074
Assignee:
Mississippi State University Research and Technology Corporation (Starkville, MS) GFO
Patent Number(s):
9,283,551
Application Number:
14/162,606
Contract Number:
FG36-06GO86025
Resource Relation:
Patent File Date: 2014 Jan 23
Research Org:
Mississippi State University Research and Technology Corporation, Starkville, MS (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
10 SYNTHETIC FUELS; 09 BIOMASS FUELS; 36 MATERIALS SCIENCE

Other works cited in this record:

A short review of heterogeneous catalytic process for mixed alcohols synthesis via syngas
journal, September 2009

Synthesis of higher alcohols from syngas over Fischer–Tropsch elements modified K/β-Mo2C catalysts
journal, April 2008

Synthesis and characterization of cobalt–molybdenum bimetallic carbides catalysts
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Oxygen removal from syngas by catalytic oxidation of copper catalyst
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Catalytic removal of oxygen from biomass-derived syngas
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journal, January 1986

Catalytic conversion wood syngas to synthetic aviation turbine fuels over a multifunctional catalyst
journal, January 2013

Characterization of an HZSM-5/MnAPO-11 composite and its catalytic properties in the synthesis of high-octane hydrocarbons from syngas
journal, November 2010

Direct synthesis of middle iso-paraffins from synthesis gas on hybrid catalysts
journal, June 2004

Effect of the operating conditions on the conversion of syngas into liquid hydrocarbons over a Cr2O3-ZnO/ZSM5 bifunctional catalyst
journal, June 1998

Catalytic conversion of methanol to gasoline range hydrocarbons
journal, October 2004

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journal, December 1990

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journal, July 2009
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Effect of cobalt (nickel) content on the catalytic performance of molybdenum carbides in dry-methane reforming
journal, February 2010

The influence of mass transfer conditions on the stability of molybdenum carbide for dry methane reforming
journal, October 2004

Mixed alcohol synthesis from carbon monoxide and dihydrogen over potassium-promoted molybdenum carbide catalysts
journal, August 1991

A comparative study of the catalytic performance of Co-Mo and Co(Ni)-W carbide catalysts in the hydrodenitrogenation (HDN) reaction of pyridine
journal, October 2007
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