Catalysts for conversion of syngas to liquid motor fuels

Title: Catalysts for conversion of syngas to liquid motor fuels

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Abstract

Synthesis gas comprising carbon monoxide and hydrogen is converted to C.sub.5.sup.+ hydrocarbons suitable for use as liquid motor fuels by contact with a dual catalyst composition capable of ensuring the production of only relatively minor amounts of heavy products boiling beyond the diesel oil range. The catalyst composition, having desirable stability during continuous production operation, employs a Fischer-Tropsch catalyst, together with a co-catalyst/support component. The latter component is a steam-stabilized zeolite Y catalyst of hydrophobic character, desirably in acid-extracted form.

Inventors:

Rabo, Jule A ^[1]; Coughlin, Peter K ^[2]

Armonk, NY
Yorktown Heights, NY

Issue Date:: 1987-01-01

Research Org.:: UNION CARBIDE CORP

OSTI Identifier:: 866193

Patent Number(s):: 4652538

Assignee:: Union Carbide Corporation (Danbury, CT)

Patent Classifications (CPCs):: C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

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C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C1/0435 - {containing a metal of group 8 or a compound thereof}
C07C2529/14 - Iron group metals or copper

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J29/146 - {Y-type faujasite}

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C2529/08 - of the faujasite type, e.g. type X or Y
C07C1/044 - {containing iron}

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DOE Contract Number:: AC22-81PC40077

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: catalysts; conversion; syngas; liquid; motor; fuels; synthesis; gas; comprising; carbon; monoxide; hydrogen; converted; hydrocarbons; suitable; contact; dual; catalyst; composition; capable; ensuring; production; relatively; minor; amounts; heavy; products; boiling; diesel; oil; range; desirable; stability; continuous; operation; employs; fischer-tropsch; co-catalyst; support; component; latter; steam-stabilized; zeolite; hydrophobic; character; desirably; acid-extracted; form; dual catalyst; comprising carbon; minor amounts; catalyst composition; fischer-tropsch catalyst; liquid motor; motor fuels; carbon monoxide; synthesis gas; minor amount; gas comprising; continuous production; support component; motor fuel; diesel oil; composition capable; stabilized zeolite; hydrocarbons suitable; /502/

Citation Formats


                    Rabo, Jule A, and Coughlin, Peter K. Catalysts for conversion of syngas to liquid motor fuels.  United States: N. p., 1987. 
        Web.

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                    Rabo, Jule A, & Coughlin, Peter K. Catalysts for conversion of syngas to liquid motor fuels.  United States.

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                    Rabo, Jule A, and Coughlin, Peter K. Thu .  
        "Catalysts for conversion of syngas to liquid motor fuels".  United States.  https://www.osti.gov/servlets/purl/866193.

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@article{osti_866193,

  title        = {Catalysts for conversion of syngas to liquid motor fuels},

  author       = {Rabo, Jule A and Coughlin, Peter K},

  abstractNote = {Synthesis gas comprising carbon monoxide and hydrogen is converted to C.sub.5.sup.+ hydrocarbons suitable for use as liquid motor fuels by contact with a dual catalyst composition capable of ensuring the production of only relatively minor amounts of heavy products boiling beyond the diesel oil range. The catalyst composition, having desirable stability during continuous production operation, employs a Fischer-Tropsch catalyst, together with a co-catalyst/support component. The latter component is a steam-stabilized zeolite Y catalyst of hydrophobic character, desirably in acid-extracted form.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {1987},

  month        = {1}

}

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