Catalytic conversion of alcohols to hydrocarbons with low benzene content
Abstract
A method for converting an alcohol to a hydrocarbon fraction having a lowered benzene content, the method comprising: converting said alcohol to a hydrocarbon fraction by contacting said alcohol, under conditions suitable for converting said alcohol to said hydrocarbon fraction, with a metal-loaded zeolite catalyst catalytically active for converting said alcohol to said hydrocarbon fraction, and contacting said hydrocarbon fraction with a benzene alkylation catalyst, under conditions suitable for alkylating benzene, to form alkylated benzene product in said hydrocarbon fraction. Also described is a catalyst composition useful in the method, comprising a mixture of (i) a metal-loaded zeolite catalyst catalytically active for converting said alcohol to said hydrocarbon, and (ii) a benzene alkylation catalyst, in which (i) and (ii) may be in a mixed or separated state. A reactor for housing the catalyst and conducting the reaction is also described.
- Inventors:
- Issue Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1241326
- Patent Number(s):
- 9278892
- Application Number:
- 14/263,257
- Assignee:
- UT-BATTELLE, LLC (Oak Ridge, TN)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
- DOE Contract Number:
- AC05-00OR22725
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2014 Apr 28
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 10 SYNTHETIC FUELS; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Narula, Chaitanya K., Davison, Brian H., and Keller, Martin. Catalytic conversion of alcohols to hydrocarbons with low benzene content. United States: N. p., 2016.
Web.
Narula, Chaitanya K., Davison, Brian H., & Keller, Martin. Catalytic conversion of alcohols to hydrocarbons with low benzene content. United States.
Narula, Chaitanya K., Davison, Brian H., and Keller, Martin. Tue .
"Catalytic conversion of alcohols to hydrocarbons with low benzene content". United States. https://www.osti.gov/servlets/purl/1241326.
@article{osti_1241326,
title = {Catalytic conversion of alcohols to hydrocarbons with low benzene content},
author = {Narula, Chaitanya K. and Davison, Brian H. and Keller, Martin},
abstractNote = {A method for converting an alcohol to a hydrocarbon fraction having a lowered benzene content, the method comprising: converting said alcohol to a hydrocarbon fraction by contacting said alcohol, under conditions suitable for converting said alcohol to said hydrocarbon fraction, with a metal-loaded zeolite catalyst catalytically active for converting said alcohol to said hydrocarbon fraction, and contacting said hydrocarbon fraction with a benzene alkylation catalyst, under conditions suitable for alkylating benzene, to form alkylated benzene product in said hydrocarbon fraction. Also described is a catalyst composition useful in the method, comprising a mixture of (i) a metal-loaded zeolite catalyst catalytically active for converting said alcohol to said hydrocarbon, and (ii) a benzene alkylation catalyst, in which (i) and (ii) may be in a mixed or separated state. A reactor for housing the catalyst and conducting the reaction is also described.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Mar 08 00:00:00 EST 2016},
month = {Tue Mar 08 00:00:00 EST 2016}
}
Works referenced in this record:
Theoretical Investigation of Benzene Alkylation with Ethene over H-ZSM-5
journal, September 2008
- Hansen, Niels; Brüggemann, Till; Bell, Alexis T.
- The Journal of Physical Chemistry C, Vol. 112, Issue 39
Catalytic role of different pore systems in MCM-49 zeolite for liquid alkylation of benzene with ethylene
journal, October 2011
- Liu, Kefeng; Xie, Sujuan; Liu, Shenglin
- Journal of Catalysis, Vol. 283, Issue 1, p. 68-74
Conversion of ethanol over metal-exchanged zeolites
journal, October 1993
- Schulz, Jürgen; Bandermann, Friedhelm
- Chemical Engineering & Technology, Vol. 16, Issue 5, p. 332-337
Crystalline Zeolite ZSM-5 and Method of Preparing the Same
patent, November 1972
- Argauer, Robert J.; Landolt, George R.
- US Patent Document 3,702,886
Conversion of alcohols, mercaptans, sulfides, halides and/or amines
patent, July 1975
- Butter, Stephen A.; Jurewicz, Anthony T.; Kaeding, Warren W.
- US Patent Document 3,894,107
Conversion of alcohols and ethers to hydrocarbons
patent, August 1975
- Chang, Clarence D.; Lang, William H.
- US Patent Document 3,899,544
Production of gasoline hydrocarbons
patent, December 1975
- Chang, Clarence Dayton; Silvestri, Anthony John; Smith, Robert Lloyd
- US Patent Document 3,928,483
Conversion of methanol to gasoline components
patent, January 1976
- Kuo, James C.
- US Patent Document 3,931,349
Conversion of alcohols and/or ethers to hydrocarbons
patent, July 1976
- Bell, Weldon K.; Chang, Clarence D.
- US Patent Document 3,969,427
Method for producing gasoline from methanol
patent, December 1976
- Daviduk, Nicholas; Siuta, Michael T.
- US Patent Document 3,998,899
Conversion of methanol to gasoline product
patent, July 1977
- Dwyer, Francis G.; Hanson, Francis V.; Schwartz, Albert B.
- US Patent Document 4,035,430
Conversion of methanol to gasoline components
patent, November 1977
- Chang, Clarence D.; Grover, Shamsher S.
- US Patent Document 4,058,576
Prolonging zeolite catalyst life in methanol conversion to gasoline by disposing of exothermic reaction heat
patent, January 1978
- Owen, Hartley; Venuto, Paul B.
- US Patent Document 4,071,573
Conversion of liquid alcohols and ethers with a fluid mass of ZSM-5 type catalyst
patent, February 1979
- Chang, Clarence D.; Jacob, Solomon M.; Silvestri, Anthony J.
- US Patent Document 4,138,440
Hydrocarbon manufacture from alcohols
patent, April 1979
- Chen, Nai Y.; Reagan, William J.
- US Patent Document 4,148,835
Hydrocarbon manufacture from alcohols
patent, July 1981
- Chen, Nai Y.; Reagan, William J.
- US Patent Document 4,278,565
Hydrocarbon cracking with mixture of zeolites Y and ZSM-5
patent, September 1981
- Gladrow, Elroy M.; Winter, William E.
- US Patent Document 4,289,606
Converting alcohols to hydrocarbons
patent, July 1982
- Pennington, Nicholas D.; Haddad, James H.
- US Patent Document 4,338,475
Conversion of methanol to gasoline
patent, September 1983
- Penick, Joe E.; Yurchak, Sergei; Zahner, John C.
- US Patent Document 4,404,414
Method for converting alcohols to hydrocarbons
patent, December 1983
- Daviduk, Nicholas; Haddad, James H.
- US Patent Document 4,423,274
Activation of zeolites
patent, January 1984
- Miale, Joseph N.; Chang, Clarence D.
- US Patent Document 4,427,789
Production of hydrocarbons with aluminophosphate molecular sieves
patent, June 1985
- Kaiser, Steven W.
- US Patent Document 4,524,234
Activation of zeolites
patent, June 1986
- Miale, Joseph N.; Chang, Clarence D.
- US Patent Document 4,596,704
Process for obtaining ethylene from ethanol
patent, February 1988
- Uytterhoeven, Jan B.; Jacobs, Julia M.; Tastenhoye, Paul
- US Patent Document 4,727,214
System for conversion of methanol to gasoline
patent, November 1988
- Marsh, Susan K.; Owen, Hartley; Wright, Bernard S.
- US Patent Document 4,788,042
Conversion of methanol to gasoline
patent, November 1988
- Marsh, Susan K.; Owen, Hartley; Wright, Bernard S.
- US Patent Document 4,788,369
Catalytic aromatic saturation of hydrocarbons
patent, July 1989
- Vauk, Dennis A.; Skripek, Milan
- US Patent Document 4,849,093
Catalysts for converting alcohols and/or aliphatic ether to unsaturated hydrocarbons and process for their production
patent, August 1989
- Baacke, Michael; Deller, Klaus; Kleinschmit, Peter
- US Patent Document 4,861,937
Conversion of alcohols to ether-rich gasoline
patent, August 1991
- Harandi, Mohsen N.; Owen, Hartley
- US Patent Document 5,041,690
Multireactor system for conversion of methanol to gasoline and distillate
patent, September 1991
- Harandi, Mohsen N.; Owen, Hartley
- US Patent Document 5,045,287
Integrated process for converting methanol to gasoline and distillates
patent, January 1993
- Harandi, Mohsen N.
- US Patent Document 5,177,279
Benzene reduction in gasoline by alkylation with higher olefins
patent, February 1996
- Chin, Arthur A.; Collins, Nick A.; Harandi, Mohsen N.
- US Patent Document 5,491,270
Process for producing olefins and aromatics from non-aromatics
patent, June 1998
- Drake, Charles A.; Sughrue, II, Edward L.; Kimble, James B.
- US Patent Document 5,773,676
Hydrocarbon conversion process using a zeolite bound zeolite catalyst
patent, November 1999
- Mohr, Gary D.; Chen, Tan-Jen; Clem, Kenneth R.
- US Patent Document 5,993,642
Catalytic conversion of oxygenates to olefins
patent, April 2000
- Sun, Hsiang-Ning
- US Patent Document 6,046,373
Synthesis method of chemical industrial raw material and high-octane fuel, and high-octane fuel composition
patent, November 2001
- Tsuchida, Takashi; Atsumi, Kiminori; Sakuma, Shuji
- US Patent Document 6,323,383
Catalyst for the conversion of low carbon number aliphatic hydrocarbons to higher carbon number hydrocarbons, process for preparing the catalyst and process using the catalyst
patent, July 2002
- Ichikawa, Masaru; Ohnishi, Ryuichiro; Wang, Linsheng
- US Patent Document 6,426,442
Honeycomb structure and catalytic converter
patent, October 2008
- Kato, Yasushi
- US Patent Document 7,438,868
High porosity honeycomb and method
patent, October 2008
- Fu, Xiaodong; Hou, Jun; Wight, Jr., John Forrest
- US Patent Document 7,442,425
Method for producing bio-fuel that integrates heat from carbon-carbon bond-forming reactions to drive biomass gasification reactions
patent, January 2011
- Cortright, Randy D.; Dumesic, James A.
- US Patent Document 7,872,054
Catalytic body and manufacturing method of the same
patent, April 2011
- Miyairi, Yukio; Noda, Naomi; Makino, Mikio
- US Patent Document 7,927,551
Reactive Distillation Process for the Alkylation of Aromatic Hydrocarbons
patent-application, September 2003
- Winder, J. Barry; Wharry, Donald L.; Schell, John R.
- US Patent Application 10/091199; 20030171630
Porous composite materials having micro and meso/macroporosity
patent-application, April 2007
- Martens, Luc; Kremer, Sebastien
- US Patent Application 11/250166; 20070087934
Processes for Converting Oxygenates to Olefins Using Aluminosilicate Catalysts
patent-application, May 2008
- Levin, Doron; Hall, Richard B.
- US Patent Application 11/855476; 20080103345
Alkylaromatics Production
patent-application, November 2008
- Clark, Michael C.
- US Patent Application 12/185503; 20080287720
Process for Converting Aliphatic Oxygenates to Aromatics
patent-application, July 2010
- Karim, Khalid; Al-Otaibi, Naif; Zaheer, Syed
- US Patent Application 12/733107; 20100185033
Ethanol producing process and apparatus
patent-application, December 2010
- Inoue, Hiroyuki; Kitao, Chiaki; Yano, Shinichi
- US Patent Application 12/445735; 20100304455
Aviation-Grade Kerosene from Independently Produced Blendstocks
patent-application, March 2011
- Aulich, Ted R.; Timpe, Ron C.; Wocken, Chad A.
- US Patent Application 12/950795; 20110061290
Conversion Of Carbohydrates To Hydrocarbons
patent-application, June 2011
- Yao, Jianhua; Sughrue, II, Edward L.; Bao, Yun
- US Patent Application 12/912164; 20110152513
Process to Make Olefins from Methanol and Isobutanol
patent-application, August 2013
- Adam, Cindy; Minoux, Delphine; Nesterenko, Nikolai
- US Patent Application 13/813170; 20130217935
Process to Make Olefins from Isobutanol
patent-application, May 2014
- Adam, Cindy; Minoux, Delphine; Nesterenko, Nikolai
- US Patent Application 13/813168; 20140148630
Synthesis of Drop-In Liquid Fuels and Chemicals from Methanol, Ethanol or Syngas Using Mixed Catalysts
patent-application, June 2014
- Kortan, Adam M.; Kelly, Michael T.; Rose, Heather A.
- US Patent Application 14/103615; 20140171691
Zeolithic Catalytic Conversion of Alcohols to Hydrocarbons
patent-application, September 2014
- Narula, Chaitanya K.; Davison, Brian H.; Keller, Martin
- US Patent Application 14/293248; 20140273146
Catalytic Conversion of Alcohols Having at Least Three Carbon Atoms to Hydrocarbon Blendstock
patent-application, January 2015
- Narula, Chaitanya K.; Davison, Brian H.
- US Patent Application 14/321012; 20150011813