Catalytic conversion of alcohols having at least three carbon atoms to hydrocarbon blendstock

Narula, Chaitanya K.; Davison, Brian H.

Title: Catalytic conversion of alcohols having at least three carbon atoms to hydrocarbon blendstock

Abstract

A method for producing a hydrocarbon blendstock, the method comprising contacting at least one saturated acyclic alcohol having at least three and up to ten carbon atoms with a metal-loaded zeolite catalyst at a temperature of at least 100.degree. C. and up to 550.degree. C., wherein the metal is a positively-charged metal ion, and the metal-loaded zeolite catalyst is catalytically active for converting the alcohol to the hydrocarbon blendstock, wherein the method directly produces a hydrocarbon blendstock having less than 1 vol % ethylene and at least 35 vol % of hydrocarbon compounds containing at least eight carbon atoms.

Inventors:: Narula, Chaitanya K.; Davison, Brian H.

Issue Date:: 2018-04-17

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1435782

Patent Number(s):: 9944861

Application Number:: 14/878,663

Assignee:: UT-BATTELLE, LLC (Oak Ridge, TN)

Patent Classifications (CPCs):: C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS

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C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS
C10G2400/02 - Gasoline
C10G2400/20 - C2-C4 olefins
C10G2400/22 - Higher olefins
C10G3/00 - Production of liquid hydrocarbon mixtures from oxygen-containing or organic materials, e.g. fatty oils, fatty acids
C10G3/45 - {containing iron group metals or compounds thereof}
C10G3/49 - {containing crystalline aluminosilicates, e.g. molecular sieves}
C10G45/44 - Hydrogenation of the aromatic hydrocarbons
C10G50/00 - Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation

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DOE Contract Number:: AC05-00OR22725

Resource Type:: Patent

Resource Relation:: Patent File Date: 2015 Oct 08

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Narula, Chaitanya K., and Davison, Brian H.. Catalytic conversion of alcohols having at least three carbon atoms to hydrocarbon blendstock.  United States: N. p., 2018. 
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                    Narula, Chaitanya K., & Davison, Brian H.. Catalytic conversion of alcohols having at least three carbon atoms to hydrocarbon blendstock.  United States.

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                    Narula, Chaitanya K., and Davison, Brian H.. Tue .  
        "Catalytic conversion of alcohols having at least three carbon atoms to hydrocarbon blendstock".  United States.  https://www.osti.gov/servlets/purl/1435782.

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@article{osti_1435782,

  title        = {Catalytic conversion of alcohols having at least three carbon atoms to hydrocarbon blendstock},

  author       = {Narula, Chaitanya K. and Davison, Brian H.},

  abstractNote = {A method for producing a hydrocarbon blendstock, the method comprising contacting at least one saturated acyclic alcohol having at least three and up to ten carbon atoms with a metal-loaded zeolite catalyst at a temperature of at least 100.degree. C. and up to 550.degree. C., wherein the metal is a positively-charged metal ion, and the metal-loaded zeolite catalyst is catalytically active for converting the alcohol to the hydrocarbon blendstock, wherein the method directly produces a hydrocarbon blendstock having less than 1 vol % ethylene and at least 35 vol % of hydrocarbon compounds containing at least eight carbon atoms.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2018},

  month        = {4}

}

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Similar Records

Title: Catalytic conversion of alcohols having at least three carbon atoms to hydrocarbon blendstock

Abstract

Citation Formats

Conversion of light alcohols to hydrocarbons over ZSM-5 zeolite and asbestos-derived zeolite catalysts journal, September 1989

Conversion of ethanol over metal-exchanged zeolites journal, October 1993

Ethylene from ethanol over zeolite catalysts journal, January 1987

Conversion of methanol to gasoline components patent, January 1976

Process to Make Olefins from Methanol and Isobutanol patent-application, August 2013

Manufacture of hydrocarbons patent, May 1977

Method for producing bio-fuel that integrates heat from carbon-carbon bond-forming reactions to drive biomass gasification reactions patent, January 2011

Processes for Converting Oxygenates to Olefins Using Aluminosilicate Catalysts patent-application, May 2008

Porous composite materials having micro and meso/macroporosity patent-application, April 2007

Hydrocarbon conversion catalyst patent, August 1986

Crystalline Zeolite ZSM-5 and Method of Preparing the Same patent, November 1972

Alkylaromatics Production patent-application, November 2008

Process for producing olefins and aromatics from non-aromatics patent, June 1998

Catalytic conversion of oxygenates to olefins patent, April 2000

Production of hydrocarbons with aluminophosphate molecular sieves patent, June 1985

Integrated process for converting methanol to gasoline and distillates patent, January 1993

Catalyst for the conversion of low carbon number aliphatic hydrocarbons to higher carbon number hydrocarbons, process for preparing the catalyst and process using the catalyst patent, July 2002

Method for producing gasoline from methanol patent, December 1976

Conversion of liquid alcohols and ethers with a fluid mass of ZSM-5 type catalyst patent, February 1979

Aviation-Grade Kerosene from Independently Produced Blendstocks patent-application, March 2011

Conversion Of Carbohydrates To Hydrocarbons patent-application, June 2011

Catalytic converter patent, May 1994

Conversion of methanol to gasoline patent, September 1983

Process to Make Olefins from Isobutanol patent-application, May 2014

Hydrocarbon manufacture from alcohols patent, July 1981

Catalyst composition for treating heavy feedstocks patent, December 2008

High porosity honeycomb and method patent, October 2008

Catalysts for converting alcohols and/or aliphatic ether to unsaturated hydrocarbons and process for their production patent, August 1989

Reactive Distillation Process for the Alkylation of Aromatic Hydrocarbons patent-application, September 2003

Activation of zeolites patent, June 1986

Conversion of alcohols to ether-rich gasoline patent, August 1991

Conversion of alcohols and ethers to hydrocarbons patent, August 1975

Hydrocarbon manufacture from alcohols patent, April 1979

Conversion of methanol to gasoline product patent, July 1977

Method for converting alcohols to hydrocarbons patent, December 1983

Prolonging zeolite catalyst life in methanol conversion to gasoline by disposing of exothermic reaction heat patent, January 1978

Process for obtaining ethylene from ethanol patent, February 1988

Production of gasoline hydrocarbons patent, December 1975

Synthesis of Drop-In Liquid Fuels and Chemicals from Methanol, Ethanol or Syngas Using Mixed Catalysts patent-application, June 2014

Multireactor system for conversion of methanol to gasoline and distillate patent, September 1991

Compositions and Methods for Fermentation of Biomass patent-application, October 2010

Sonic spark plug patent, June 1977

Process for Converting Aliphatic Oxygenates to Aromatics patent-application, July 2010

Benzene reduction in gasoline by alkylation with higher olefins patent, February 1996

Process for preparing a pentasil zeolite patent, January 1988

Method and Systems for Making Distillate Fuels from Biomass patent-application, August 2012

Honeycomb structure and catalytic converter patent, October 2008

Conversion of alcohols and/or ethers to hydrocarbons patent, July 1976

Activation of zeolites patent, January 1984

Production of light olefins patent, February 1985

Catalytic aromatic saturation of hydrocarbons patent, July 1989

System for conversion of methanol to gasoline patent, November 1988

Conversion of alcohols, mercaptans, sulfides, halides and/or amines patent, July 1975

Synthesis method of chemical industrial raw material and high-octane fuel, and high-octane fuel composition patent, November 2001

Conversion of methanol to gasoline patent, November 1988

Conversion of light alcohols to hydrocarbons over ZSM-5 zeolite and asbestos-derived zeolite catalysts
journal, September 1989

Conversion of ethanol over metal-exchanged zeolites
journal, October 1993

Ethylene from ethanol over zeolite catalysts
journal, January 1987

Conversion of methanol to gasoline components
patent, January 1976

Process to Make Olefins from Methanol and Isobutanol
patent-application, August 2013

Manufacture of hydrocarbons
patent, May 1977

Method for producing bio-fuel that integrates heat from carbon-carbon bond-forming reactions to drive biomass gasification reactions
patent, January 2011

Processes for Converting Oxygenates to Olefins Using Aluminosilicate Catalysts
patent-application, May 2008

Porous composite materials having micro and meso/macroporosity
patent-application, April 2007

Hydrocarbon conversion catalyst
patent, August 1986

Crystalline Zeolite ZSM-5 and Method of Preparing the Same
patent, November 1972

Alkylaromatics Production
patent-application, November 2008

Process for producing olefins and aromatics from non-aromatics
patent, June 1998

Catalytic conversion of oxygenates to olefins
patent, April 2000

Production of hydrocarbons with aluminophosphate molecular sieves
patent, June 1985

Integrated process for converting methanol to gasoline and distillates
patent, January 1993

Catalyst for the conversion of low carbon number aliphatic hydrocarbons to higher carbon number hydrocarbons, process for preparing the catalyst and process using the catalyst
patent, July 2002

Method for producing gasoline from methanol
patent, December 1976

Conversion of liquid alcohols and ethers with a fluid mass of ZSM-5 type catalyst
patent, February 1979

Aviation-Grade Kerosene from Independently Produced Blendstocks
patent-application, March 2011

Conversion Of Carbohydrates To Hydrocarbons
patent-application, June 2011

Catalytic converter
patent, May 1994

Conversion of methanol to gasoline
patent, September 1983

Process to Make Olefins from Isobutanol
patent-application, May 2014

Hydrocarbon manufacture from alcohols
patent, July 1981

Catalyst composition for treating heavy feedstocks
patent, December 2008

High porosity honeycomb and method
patent, October 2008

Catalysts for converting alcohols and/or aliphatic ether to unsaturated hydrocarbons and process for their production
patent, August 1989

Reactive Distillation Process for the Alkylation of Aromatic Hydrocarbons
patent-application, September 2003

Activation of zeolites
patent, June 1986

Conversion of alcohols to ether-rich gasoline
patent, August 1991

Conversion of alcohols and ethers to hydrocarbons
patent, August 1975

Hydrocarbon manufacture from alcohols
patent, April 1979

Conversion of methanol to gasoline product
patent, July 1977

Method for converting alcohols to hydrocarbons
patent, December 1983

Prolonging zeolite catalyst life in methanol conversion to gasoline by disposing of exothermic reaction heat
patent, January 1978

Process for obtaining ethylene from ethanol
patent, February 1988

Production of gasoline hydrocarbons
patent, December 1975

Synthesis of Drop-In Liquid Fuels and Chemicals from Methanol, Ethanol or Syngas Using Mixed Catalysts
patent-application, June 2014

Multireactor system for conversion of methanol to gasoline and distillate
patent, September 1991

Compositions and Methods for Fermentation of Biomass
patent-application, October 2010

Sonic spark plug
patent, June 1977

Process for Converting Aliphatic Oxygenates to Aromatics
patent-application, July 2010

Benzene reduction in gasoline by alkylation with higher olefins
patent, February 1996

Process for preparing a pentasil zeolite
patent, January 1988

Method and Systems for Making Distillate Fuels from Biomass
patent-application, August 2012

Honeycomb structure and catalytic converter
patent, October 2008

Conversion of alcohols and/or ethers to hydrocarbons
patent, July 1976

Activation of zeolites
patent, January 1984

Production of light olefins
patent, February 1985

Catalytic aromatic saturation of hydrocarbons
patent, July 1989

System for conversion of methanol to gasoline
patent, November 1988

Conversion of alcohols, mercaptans, sulfides, halides and/or amines
patent, July 1975

Synthesis method of chemical industrial raw material and high-octane fuel, and high-octane fuel composition
patent, November 2001

Conversion of methanol to gasoline
patent, November 1988