High power and high energy electrodes using carbon nanotubes

Martini, Fabrizio; Brambilla, Nicolo Michele; Signorelli, Riccardo

Title: High power and high energy electrodes using carbon nanotubes

Abstract

An electrode useful in an energy storage system, such as a capacitor, includes an electrode that includes at least one to a plurality of layers of compressed carbon nanotube aggregate. Methods of fabrication are provided. The resulting electrode exhibits superior electrical performance in terms of gravimetric and volumetric power density.

Inventors:: Martini, Fabrizio; Brambilla, Nicolo Michele; Signorelli, Riccardo

Issue Date:: Tue Apr 07 00:00:00 EDT 2015

Research Org.:: FASTCAP Systems Corporation, Boston, MA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1177505

Patent Number(s):: 9001495

Application Number:: 13/587,037

Assignee:: FASTCAP Systems Corporation (Boston, MA)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B32 - LAYERED PRODUCTS B32B - LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM

B - PERFORMING OPERATIONS B82 - NANOTECHNOLOGY B82Y - SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES

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B - PERFORMING OPERATIONS B32 - LAYERED PRODUCTS B32B - LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
B32B37/025 - {Transfer laminating}

B - PERFORMING OPERATIONS B82 - NANOTECHNOLOGY B82Y - SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES
B82Y30/00 - Nanotechnology for materials or surface science, e.g. nanocomposites

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01G - CAPACITORS
H01G11/28 - arranged or disposed on a current collector
H01G11/36 - Nanostructures, e.g. nanofibres, nanotubes or fullerenes
H01G11/68 - characterised by their materials
H01G11/70 - characterised by their structures
H01G11/86 - specially adapted for electrodes

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/13 - Ultracapacitors, supercapacitors, double-layer capacitors

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DOE Contract Number:: AR0000035/0001

Resource Type:: Patent

Resource Relation:: Patent File Date: 2012 Aug 16

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE; 36 MATERIALS SCIENCE

Citation Formats


                    Martini, Fabrizio, Brambilla, Nicolo Michele, and Signorelli, Riccardo. High power and high energy electrodes using carbon nanotubes.  United States: N. p., 2015. 
        Web.

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                    Martini, Fabrizio, Brambilla, Nicolo Michele, & Signorelli, Riccardo. High power and high energy electrodes using carbon nanotubes.  United States.

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                    Martini, Fabrizio, Brambilla, Nicolo Michele, and Signorelli, Riccardo. Tue .  
        "High power and high energy electrodes using carbon nanotubes".  United States.  https://www.osti.gov/servlets/purl/1177505.

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@article{osti_1177505,

  title        = {High power and high energy electrodes using carbon nanotubes},

  author       = {Martini, Fabrizio and Brambilla, Nicolo Michele and Signorelli, Riccardo},

  abstractNote = {An electrode useful in an energy storage system, such as a capacitor, includes an electrode that includes at least one to a plurality of layers of compressed carbon nanotube aggregate. Methods of fabrication are provided. The resulting electrode exhibits superior electrical performance in terms of gravimetric and volumetric power density.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Tue Apr 07 00:00:00 EDT 2015},

  month        = {Tue Apr 07 00:00:00 EDT 2015}

}

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Applied Physics Letters, Vol. 70, Issue 11, p. 1480-1482
https://doi.org/10.1063/1.118568

The influence of air and its components on the cathodic stability of N-butyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide
journal, December 2007

Randström, S.; Appetecchi, G. B.; Lagergren, C.
Electrochimica Acta, Vol. 53, Issue 4, p. 1837-1842
https://doi.org/10.1016/j.electacta.2007.08.029

Realistic applications of CNTs
journal, October 2004

Robertson, John
Materials Today, Vol. 7, Issue 10
https://doi.org/10.1016/S1369-7021(04)00448-1

Physical and electrochemical properties of ionic liquids 1-ethyl-3-methylimidazolium tetrafluoroborate, 1-butyl-3-methylimidazolium trifluoromethanesulfonate and 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide
journal, November 2010

Shamsipur, Mojtaba; Beigi, Ali Akbar Miran; Teymouri, Mohammad
Journal of Molecular Liquids, Vol. 157, Issue 1, p. 43-50
https://doi.org/10.1016/j.molliq.2010.08.005

Application of Low-Viscosity Ionic Liquid to the Electrolyte of Double-Layer Capacitors
journal, January 2003

Ue, Makoto; Takeda, Masayuki; Toriumi, Akiko
Journal of The Electrochemical Society, Vol. 150, Issue 4
https://doi.org/10.1149/1.1559069

Direct Growth of Single-Walled Carbon Nanotube Networks on Alumina Substrate: A Novel Route to Ultrasensitive Gas Sensor Fabrication
journal, November 2005

Wongwiriyapan, Winadda; Honda, Shin-ichi; Konishi, Hirofumi
Japanese Journal of Applied Physics, Vol. 44, Issue 11
https://doi.org/10.1143/JJAP.44.8227

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Title: High power and high energy electrodes using carbon nanotubes

Abstract

Citation Formats

Conductivity cell for particle study device patent, September 1976

Method and apparatus for orientation of electrode joint threads patent, September 1982

Electrochemical double-layer capacitor patent, October 1983

Feedthrough connector for implantable medical device patent, June 1990

High temperature feed-through system and method for making same patent, August 1995

Transparent regenerating photoelectrochemical cell patent, August 1995

Polymeric insulating material and formed article making use of the material patent, December 1995

Energy storage device and its methods of manufacture patent, January 1998

Generator patent, July 1999

Method of making a high performance ultracapacitor patent, May 2000

Tantalum powder, method for producing same powder and sintered anodes obtained from it patent, February 2001

Fibril composite electrode for electrochemical capacitors patent, March 2001

Self-oriented bundles of carbon nanotubes and method of making same patent, May 2001

Well management system patent, July 2001

Combinations of materials to minimize ESR and maximize ESR stability of surface mount valve-metal capacitors after exposure to heat and/or humidity patent, October 2001

Mass synthesis method of high purity carbon nanotubes vertically aligned over large-size substrate using thermal chemical vapor deposition patent, February 2002

Battery monitor and open circuit protector patent, May 2002

Layered arrangements of lithium electrodes patent, July 2002

Surface modification of solid supports through the thermal decomposition and functionalization of silanes patent, September 2002

Supercapacitor using electrode of new material and method of manufacturing the same patent, September 2002

Method of pretreating activated carbon for polarized electrode patent, December 2002

Method of passivating a gas vessel or component of a gas transfer system using a silicon overlay coating patent, January 2003

White light source using carbon nanotubes and fabrication method thereof patent, February 2003

Ultracapacitor current collector patent, May 2003

Graphitic nanofibers in electrochemical capacitors patent, December 2003

Method for chemical vapor deposition of single walled carbon nanotubes patent, July 2004

Apparatus for measuring and recording data from boreholes patent, January 2005

Modification of nanotubes oxidation with peroxygen compounds patent, March 2005

Electric double layer capacitor and process for its production patent, June 2005

Rotational inertia aided electric generator patent, July 2005

Rechargeable lithium battery patent, August 2005

Methods of making, positioning and orienting nanostructures, nanostructure arrays and nanostructure devices patent, November 2005

Method for chemical vapor deposition of silicon on to substrates for use in corrosive and vacuum environments patent, July 2006

Capacitor with carbon nanotubes patent, October 2006

Method for manufacturing ultrafine carbon fiber and field emission element patent, April 2007

Carbon-coated aluminum and method for producing same patent, February 2008

Methods of using pre-formed nanotubes to make carbon nanotube films, layers, fabrics, ribbons, elements and articles patent, February 2008

Aluminum electrolytic capacitor having an anode having a uniform array of micron-sized pores patent, June 2008

Ultrasonic sealed fill hole patent, March 2009

Rechargeable energy storage device in a downhole operation patent, April 2010

Method of manufacturing carbon nanostructure patent, August 2010

Apparatus and method for producing aligned carbon-nanotube aggregates patent, March 2011

System for energy harvesting and/or generation, storage, and delivery patent, July 2011

Surface real-time processing of downhole data patent, August 2011

Fibrous columnar structure aggregate and pressure-sensitive adhesive member using the aggregate patent, September 2011

Electrochemical element for use at high temperatures patent, May 2012

Electric double layer capacitor and method for manufacturing the same patent, September 2013

Electrochemical double-layer capacitor for high temperature applications patent, June 2014

Utilization of energy from flowing fluids patent-application, July 2001

Petroleum well having downhole sensors, communication and power patent-application, April 2002

Method for forming an array of single-wall carbon nanotubes and compositions thereof patent-application, October 2002

Fuel Cell Power System, Method of Distributing Power and Method of Operating a Fuel Cell Power System patent-application, November 2002

Pregel compositions for polymer gel electrolytes, method of dehydrating pregel compositons, secondary cell, and electrical double-layer capacitor patent-application, January 2003

Battery case, cover, and feedthrough patent-application, February 2003

Multi-electrode double layer capacitor having hermetic electrolyte seal patent-application, February 2003

Electric double layer capacitor and method for preparing the same patent-application, May 2003

Lithium ion battery comprising nanomaterials patent-application, July 2004

Purification or work-up of ionic liquids by means of adsorptive separation processes patent-application, September 2004

Electrochemical cell stack patent-application, November 2004

Multi-electrode double-layer capacitor having hermetic electrolyte seal patent-application, July 2005

Method of producing electrode for capacitor patent-application, September 2005

Carbon nanotube nanoelectrode arrays patent-application, October 2005

Electric double layer capacitor enclosed in polymer housing patent-application, October 2005

Highly-stable polymeric electrolyte and use thereof in electrochemical systems patent-application, October 2005

Nanotube/metal substrate composites and methods for producing such composites patent-application, October 2005

Corrosion protection using protected electron collector patent-application, January 2006

Battery patent-application, June 2006

Resistive balance for an energy storage device patent-application, August 2006

Solid electrolyte capacitor and process for producing same patent-application, November 2006

More Energy Dense Electrolytic Capacitor patent-application, December 2006

Method of making a multi-electrode double layer capacitor having hermetic electrolyte seal patent-application, January 2007

Electrochemical double-layer capacitor using organosilicon electrolytes patent-application, April 2007

Direct process for the manufacture of tetraalkylammonium tetrafluoroborate-containing electrolyte compositions patent-application, May 2007

Ultracapacitor pressure control system patent-application, June 2007

Electrolyte for Electrolytic Capacitor, Electrolytic Capacitor and Process for Producing Tetrafluroaluminate Salt of Organic Onium patent-application, August 2007

Electrochemical Element for Use at High Temperatures patent-application, November 2007

Supercapacitors Using Single-Walled Carbon Nanotube Electrodes journal, April 2001

Conductivity cell for particle study device
patent, September 1976

Method and apparatus for orientation of electrode joint threads
patent, September 1982

Electrochemical double-layer capacitor
patent, October 1983

Feedthrough connector for implantable medical device
patent, June 1990

High temperature feed-through system and method for making same
patent, August 1995

Transparent regenerating photoelectrochemical cell
patent, August 1995

Polymeric insulating material and formed article making use of the material
patent, December 1995

Energy storage device and its methods of manufacture
patent, January 1998

Generator
patent, July 1999

Method of making a high performance ultracapacitor
patent, May 2000

Tantalum powder, method for producing same powder and sintered anodes obtained from it
patent, February 2001

Fibril composite electrode for electrochemical capacitors
patent, March 2001

Self-oriented bundles of carbon nanotubes and method of making same
patent, May 2001

Well management system
patent, July 2001

Combinations of materials to minimize ESR and maximize ESR stability of surface mount valve-metal capacitors after exposure to heat and/or humidity
patent, October 2001

Mass synthesis method of high purity carbon nanotubes vertically aligned over large-size substrate using thermal chemical vapor deposition
patent, February 2002

Battery monitor and open circuit protector
patent, May 2002

Layered arrangements of lithium electrodes
patent, July 2002

Surface modification of solid supports through the thermal decomposition and functionalization of silanes
patent, September 2002

Supercapacitor using electrode of new material and method of manufacturing the same
patent, September 2002

Method of pretreating activated carbon for polarized electrode
patent, December 2002

Method of passivating a gas vessel or component of a gas transfer system using a silicon overlay coating
patent, January 2003

White light source using carbon nanotubes and fabrication method thereof
patent, February 2003

Ultracapacitor current collector
patent, May 2003

Graphitic nanofibers in electrochemical capacitors
patent, December 2003

Method for chemical vapor deposition of single walled carbon nanotubes
patent, July 2004

Apparatus for measuring and recording data from boreholes
patent, January 2005

Modification of nanotubes oxidation with peroxygen compounds
patent, March 2005

Electric double layer capacitor and process for its production
patent, June 2005

Rotational inertia aided electric generator
patent, July 2005

Rechargeable lithium battery
patent, August 2005

Methods of making, positioning and orienting nanostructures, nanostructure arrays and nanostructure devices
patent, November 2005

Method for chemical vapor deposition of silicon on to substrates for use in corrosive and vacuum environments
patent, July 2006

Capacitor with carbon nanotubes
patent, October 2006

Method for manufacturing ultrafine carbon fiber and field emission element
patent, April 2007

Carbon-coated aluminum and method for producing same
patent, February 2008

Methods of using pre-formed nanotubes to make carbon nanotube films, layers, fabrics, ribbons, elements and articles
patent, February 2008

Aluminum electrolytic capacitor having an anode having a uniform array of micron-sized pores
patent, June 2008

Ultrasonic sealed fill hole
patent, March 2009

Rechargeable energy storage device in a downhole operation
patent, April 2010

Method of manufacturing carbon nanostructure
patent, August 2010

Apparatus and method for producing aligned carbon-nanotube aggregates
patent, March 2011

System for energy harvesting and/or generation, storage, and delivery
patent, July 2011

Surface real-time processing of downhole data
patent, August 2011

Fibrous columnar structure aggregate and pressure-sensitive adhesive member using the aggregate
patent, September 2011

Electrochemical element for use at high temperatures
patent, May 2012

Electric double layer capacitor and method for manufacturing the same
patent, September 2013

Electrochemical double-layer capacitor for high temperature applications
patent, June 2014

Utilization of energy from flowing fluids
patent-application, July 2001

Petroleum well having downhole sensors, communication and power
patent-application, April 2002

Method for forming an array of single-wall carbon nanotubes and compositions thereof
patent-application, October 2002

Fuel Cell Power System, Method of Distributing Power and Method of Operating a Fuel Cell Power System
patent-application, November 2002

Pregel compositions for polymer gel electrolytes, method of dehydrating pregel compositons, secondary cell, and electrical double-layer capacitor
patent-application, January 2003

Battery case, cover, and feedthrough
patent-application, February 2003

Multi-electrode double layer capacitor having hermetic electrolyte seal
patent-application, February 2003

Electric double layer capacitor and method for preparing the same
patent-application, May 2003

Lithium ion battery comprising nanomaterials
patent-application, July 2004

Purification or work-up of ionic liquids by means of adsorptive separation processes
patent-application, September 2004

Electrochemical cell stack
patent-application, November 2004

Multi-electrode double-layer capacitor having hermetic electrolyte seal
patent-application, July 2005

Method of producing electrode for capacitor
patent-application, September 2005

Carbon nanotube nanoelectrode arrays
patent-application, October 2005

Electric double layer capacitor enclosed in polymer housing
patent-application, October 2005

Highly-stable polymeric electrolyte and use thereof in electrochemical systems
patent-application, October 2005

Nanotube/metal substrate composites and methods for producing such composites
patent-application, October 2005

Corrosion protection using protected electron collector
patent-application, January 2006

Battery
patent-application, June 2006

Resistive balance for an energy storage device
patent-application, August 2006

Solid electrolyte capacitor and process for producing same
patent-application, November 2006

More Energy Dense Electrolytic Capacitor
patent-application, December 2006

Method of making a multi-electrode double layer capacitor having hermetic electrolyte seal
patent-application, January 2007

Electrochemical double-layer capacitor using organosilicon electrolytes
patent-application, April 2007

Direct process for the manufacture of tetraalkylammonium tetrafluoroborate-containing electrolyte compositions
patent-application, May 2007

Ultracapacitor pressure control system
patent-application, June 2007

Electrolyte for Electrolytic Capacitor, Electrolytic Capacitor and Process for Producing Tetrafluroaluminate Salt of Organic Onium
patent-application, August 2007

Electrochemical Element for Use at High Temperatures
patent-application, November 2007

Supercapacitors Using Single-Walled Carbon Nanotube Electrodes
journal, April 2001

Thermal degradation studies of alkyl-imidazolium salts and their application in nanocomposites
journal, January 2004

High temperature carbon–carbon supercapacitor using ionic liquid as electrolyte
journal, March 2007

Investigation of electrochemical double-layer (ECDL) capacitors electrodes based on carbon nanotubes and activated carbon materials
journal, October 2003