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Title: Aligned carbon nanotube with electro-catalytic activity for oxygen reduction reaction

Abstract

A catalyst for an electro-chemical oxygen reduction reaction (ORR) of a bundle of longitudinally aligned carbon nanotubes having a catalytically active transition metal incorporated longitudinally in said nanotubes. A method of making an electro-chemical catalyst for an oxygen reduction reaction (ORR) having a bundle of longitudinally aligned carbon nanotubes with a catalytically active transition metal incorporated throughout the nanotubes, where a substrate is in a first reaction zone, and a combination selected from one or more of a hydrocarbon and an organometallic compound containing an catalytically active transition metal and a nitrogen containing compound and an inert gas and a reducing gas is introduced into the first reaction zone which is maintained at a first reaction temperature for a time sufficient to vaporize material therein. The vaporized material is then introduced to a second reaction zone maintained at a second reaction temperature for a time sufficient to grow longitudinally aligned carbon nanotubes over the substrate with a catalytically active transition metal incorporated throughout the nanotubes.

Inventors:
 [1];  [2];  [1]
  1. Naperville, IL
  2. Westmont, IL
Issue Date:
Research Org.:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1013850
Patent Number(s):
7767616
Application Number:
11/368,120
Assignee:
UChicago Argonne, LLC (Chicago, IL)
Patent Classifications (CPCs):
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
DOE Contract Number:  
W-31-109-ENG-38
Resource Type:
Patent
Country of Publication:
United States
Language:
English

Citation Formats

Liu, Di-Jia, Yang, Junbing, and Wang, Xiaoping. Aligned carbon nanotube with electro-catalytic activity for oxygen reduction reaction. United States: N. p., 2010. Web.
Liu, Di-Jia, Yang, Junbing, & Wang, Xiaoping. Aligned carbon nanotube with electro-catalytic activity for oxygen reduction reaction. United States.
Liu, Di-Jia, Yang, Junbing, and Wang, Xiaoping. Tue . "Aligned carbon nanotube with electro-catalytic activity for oxygen reduction reaction". United States. https://www.osti.gov/servlets/purl/1013850.
@article{osti_1013850,
title = {Aligned carbon nanotube with electro-catalytic activity for oxygen reduction reaction},
author = {Liu, Di-Jia and Yang, Junbing and Wang, Xiaoping},
abstractNote = {A catalyst for an electro-chemical oxygen reduction reaction (ORR) of a bundle of longitudinally aligned carbon nanotubes having a catalytically active transition metal incorporated longitudinally in said nanotubes. A method of making an electro-chemical catalyst for an oxygen reduction reaction (ORR) having a bundle of longitudinally aligned carbon nanotubes with a catalytically active transition metal incorporated throughout the nanotubes, where a substrate is in a first reaction zone, and a combination selected from one or more of a hydrocarbon and an organometallic compound containing an catalytically active transition metal and a nitrogen containing compound and an inert gas and a reducing gas is introduced into the first reaction zone which is maintained at a first reaction temperature for a time sufficient to vaporize material therein. The vaporized material is then introduced to a second reaction zone maintained at a second reaction temperature for a time sufficient to grow longitudinally aligned carbon nanotubes over the substrate with a catalytically active transition metal incorporated throughout the nanotubes.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Aug 03 00:00:00 EDT 2010},
month = {Tue Aug 03 00:00:00 EDT 2010}
}

Works referenced in this record:

Activation and characterization of Fe-based catalysts for the reduction of oxygen in polymer electrolyte fuel cells
journal, May 1998


Growth of Vertically Aligned Nitrogen-Doped Carbon Nanotubes:  Control of the Nitrogen Content over the Temperature Range 900−1100 °C
journal, November 2003


A New Fuel Cell Cathode Catalyst
journal, March 1964


Thin-film catalyst layers for polymer electrolyte fuel cell electrodes
journal, January 1992


Oxygen reduction on monomeric transition metal phthalocyanines in acid electrolyte
journal, September 1979