Carbon supported single atom carbon dioxide reduction electro catalysts

Liu, Di-Jia; Xu, Tao; Rebollar, Dominic; Xu, Haiping

Title: Carbon supported single atom carbon dioxide reduction electro catalysts

Abstract

Electrocatalysts composed of single atoms dispersed over porous carbon support were prepared by a lithium-melt method. The new catalysts demonstrated high selectivity, high Faradic efficiency and low overpotential toward to the electrocatalytic reduction of carbon dioxide to fuels.

Inventors:: Liu, Di-Jia; Xu, Tao; Rebollar, Dominic; Xu, Haiping

Issue Date:: 2020-11-24

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1771676

Patent Number(s):: 10844501

Application Number:: 15/915,259

Assignee:: UChicago Argonne, LLC (Chicago, IL); Board of Trustees of Northern Illinois University (DeKalb, IL)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS

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B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J19/087 - {employing electric or magnetic energy}
B01J2219/0803 - employing electric or magnetic energy
B01J2219/0875 - Gas
B01J2219/0892 - involving catalytically active material

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C1/12 - from carbon dioxide with hydrogen
C07C29/154 - containing copper, silver, gold, or compounds thereof
C07C29/158 - containing rhodium or compounds thereof
C07C45/00 - Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms
C07C51/00 - Preparation of carboxylic acids or their salts, halides or anhydrides

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DOE Contract Number:: AC02-06CH11357; W-31-109-ENG-38

Resource Type:: Patent

Resource Relation:: Patent File Date: 03/08/2018

Country of Publication:: United States

Language:: English

Citation Formats


                    Liu, Di-Jia, Xu, Tao, Rebollar, Dominic, and Xu, Haiping. Carbon supported single atom carbon dioxide reduction electro catalysts.  United States: N. p., 2020. 
        Web.

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                    Liu, Di-Jia, Xu, Tao, Rebollar, Dominic, & Xu, Haiping. Carbon supported single atom carbon dioxide reduction electro catalysts.  United States.

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                    Liu, Di-Jia, Xu, Tao, Rebollar, Dominic, and Xu, Haiping. Tue .  
        "Carbon supported single atom carbon dioxide reduction electro catalysts".  United States.  https://www.osti.gov/servlets/purl/1771676.

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@article{osti_1771676,

  title        = {Carbon supported single atom carbon dioxide reduction electro catalysts},

  author       = {Liu, Di-Jia and Xu, Tao and Rebollar, Dominic and Xu, Haiping},

  abstractNote = {Electrocatalysts composed of single atoms dispersed over porous carbon support were prepared by a lithium-melt method. The new catalysts demonstrated high selectivity, high Faradic efficiency and low overpotential toward to the electrocatalytic reduction of carbon dioxide to fuels.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2020},

  month        = {11}

}

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Works referenced in this record:

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Similar Records

Title: Carbon supported single atom carbon dioxide reduction electro catalysts

Abstract

Citation Formats

Carbon Dioxide Reduction Electro Catalysts Prepared for Metal Organic Frameworks patent-application, February 2019

Method for producing metal by molten salt electrolysis and apparatus used for the production method patent-application, October 2014

Synthesis of Supported Platinum Nanoparticles from Li−Pt Solid Solution journal, February 2010

Tailoring the Edge Structure of Molybdenum Disulfide toward Electrocatalytic Reduction of Carbon Dioxide journal, December 2016

Amorphizing of Cu Nanoparticles toward Highly Efficient and Robust Electrocatalyst for CO 2 Reduction to Liquid Fuels with High Faradaic Efficiencies journal, February 2018

Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction journal, February 2018

Method of Operating Fuel Cell with Molten-Oxygen-Containing Electrolyte and Non-Porous Hydrogen-Diffusing Nickel Electrode patent, December 1971

Method for producing catalysts patent, December 1991

Lithium Assisted “Dissolution–Alloying” Synthesis of Nanoalloys from Individual Bulk Metals journal, March 2016

CO 2 reduction to acetate in mixtures of ultrasmall (Cu) n ,(Ag) m bimetallic nanoparticles journal, December 2017

Copper nanoparticle ensembles for selective electroreduction of CO 2 to C 2 –C 3 products journal, September 2017

Carbon Supported Single Atom Carbon Dioxide Reduction Electro Catalysts patent-application, September 2019

Ultrafine Iridium Oxide Nanorods Synthesized by Molten Salt Method toward Electrocatalytic Oxygen and Hydrogen Evolution Reactions journal, September 2016

Materials discovery by crystal growth: Lanthanide metal containing oxides of the platinum group metals (Ru, Os, Ir, Rh, Pd, Pt) from molten alkali metal hydroxides journal, July 2009

Selective CO 2 reduction to C 3 and C 4 oxyhydrocarbons on nickel phosphides at overpotentials as low as 10 mV journal, January 2018

Positive Active Material for Use in a Lithium Ion Battery and Method for Preparing the Same patent-application, October 2015

Direct Synthesis of Bimetallic Pd 3 Ag Nanoalloys from Bulk Pd 3 Ag Alloy journal, November 2012

Molten salt synthesis of lithium meta-aluminate powder patent, May 1980

Carbon Dioxide Reduction Electro Catalysts Prepared for Metal Organic Frameworks
patent-application, February 2019

Method for producing metal by molten salt electrolysis and apparatus used for the production method
patent-application, October 2014

Synthesis of Supported Platinum Nanoparticles from Li−Pt Solid Solution
journal, February 2010

Tailoring the Edge Structure of Molybdenum Disulfide toward Electrocatalytic Reduction of Carbon Dioxide
journal, December 2016

Amorphizing of Cu Nanoparticles toward Highly Efficient and Robust Electrocatalyst for CO ₂ Reduction to Liquid Fuels with High Faradaic Efficiencies
journal, February 2018

Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction
journal, February 2018

Method of Operating Fuel Cell with Molten-Oxygen-Containing Electrolyte and Non-Porous Hydrogen-Diffusing Nickel Electrode
patent, December 1971

Method for producing catalysts
patent, December 1991

Lithium Assisted “Dissolution–Alloying” Synthesis of Nanoalloys from Individual Bulk Metals
journal, March 2016

CO ₂ reduction to acetate in mixtures of ultrasmall (Cu) _n ,(Ag) _m bimetallic nanoparticles
journal, December 2017

Copper nanoparticle ensembles for selective electroreduction of CO ₂ to C ₂ –C ₃ products
journal, September 2017

Carbon Supported Single Atom Carbon Dioxide Reduction Electro Catalysts
patent-application, September 2019

Ultrafine Iridium Oxide Nanorods Synthesized by Molten Salt Method toward Electrocatalytic Oxygen and Hydrogen Evolution Reactions
journal, September 2016

Materials discovery by crystal growth: Lanthanide metal containing oxides of the platinum group metals (Ru, Os, Ir, Rh, Pd, Pt) from molten alkali metal hydroxides
journal, July 2009

Selective CO ₂ reduction to C ₃ and C ₄ oxyhydrocarbons on nickel phosphides at overpotentials as low as 10 mV
journal, January 2018

Positive Active Material for Use in a Lithium Ion Battery and Method for Preparing the Same
patent-application, October 2015

Direct Synthesis of Bimetallic Pd ₃ Ag Nanoalloys from Bulk Pd ₃ Ag Alloy
journal, November 2012

Molten salt synthesis of lithium meta-aluminate powder
patent, May 1980