Replication Data for: Mechanistic and Electronic Insights into a Working NiAu Single-Atom Alloy Ethanol Dehydrogenation Catalyst

Giannakakis, Georgios; Kress, Paul; Duanmu, Kaining; Ngan, Hio Tong; Yan, George; Hoffman, Adam S.; Qi, Zhen; Trimpalis, Antonios; Annamalai, Leelavathi; Ouyang, Mengyao; Liu, Jilei; Eagan, Nathaniel; Biener, Juergen; Sokaras, Dimosthenis; Flytzani-Stephanopoulos, Maria; Bare, Simon R.; Sautet, Philippe; Sykes, E. Charles H.

doi:10.7910/DVN/CHXIVV

Title: Replication Data for: Mechanistic and Electronic Insights into a Working NiAu Single-Atom Alloy Ethanol Dehydrogenation Catalyst

Dataset
Other Related Research

Abstract

The data underlying this published work have been made publicly available in this repository as part of the IMASC Data Management Plan. This work was supported as part of the Integrated Mesoscale Architectures for Sustainable Catalysis (IMASC), an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Basic Energy Sciences under Award # DE-SC0012573.

Authors:

Giannakakis, Georgios; Kress, Paul; Duanmu, Kaining; Ngan, Hio Tong; Yan, George; Hoffman, Adam S.; Qi, Zhen; Trimpalis, Antonios; Annamalai, Leelavathi; Ouyang, Mengyao; Liu, Jilei; Eagan, Nathaniel; Biener, Juergen; Sokaras, Dimosthenis; Flytzani-Stephanopoulos, Maria; Bare, Simon R.; Sautet, Philippe; Sykes, E. Charles H.

Tufts Univ., Medford, MA (United States); OSTI
Tufts Univ., Medford, MA (United States)
Univ. of California, Los Angeles, CA (United States)
SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Synchrotron Radiation Lightsource (SSRL)
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

Publication Date:: Mon Jan 10 23:00:00 EST 2022

DOE Contract Number:: SC0012573

Research Org.:: Harvard Univ., Cambridge, MA (United States). Integrated Mesoscale Architectures for Sustainable Catalysis (IMASC) (EFRC)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

OSTI Identifier:: 1878476

DOI:: https://doi.org/10.7910/DVN/CHXIVV

Citation Formats


                    Giannakakis, Georgios, Kress, Paul, Duanmu, Kaining, Ngan, Hio Tong, Yan, George, Hoffman, Adam S., Qi, Zhen, Trimpalis, Antonios, Annamalai, Leelavathi, Ouyang, Mengyao, Liu, Jilei, Eagan, Nathaniel, Biener, Juergen, Sokaras, Dimosthenis, Flytzani-Stephanopoulos, Maria, Bare, Simon R., Sautet, Philippe, and Sykes, E. Charles H. Replication Data for: Mechanistic and Electronic Insights into a Working NiAu Single-Atom Alloy Ethanol Dehydrogenation Catalyst.  United States: N. p., 2022. 
        Web.  doi:10.7910/DVN/CHXIVV.

Copy to clipboard


                    Giannakakis, Georgios, Kress, Paul, Duanmu, Kaining, Ngan, Hio Tong, Yan, George, Hoffman, Adam S., Qi, Zhen, Trimpalis, Antonios, Annamalai, Leelavathi, Ouyang, Mengyao, Liu, Jilei, Eagan, Nathaniel, Biener, Juergen, Sokaras, Dimosthenis, Flytzani-Stephanopoulos, Maria, Bare, Simon R., Sautet, Philippe, & Sykes, E. Charles H. Replication Data for: Mechanistic and Electronic Insights into a Working NiAu Single-Atom Alloy Ethanol Dehydrogenation Catalyst.  United States.  doi:https://doi.org/10.7910/DVN/CHXIVV

Copy to clipboard


                    Giannakakis, Georgios, Kress, Paul, Duanmu, Kaining, Ngan, Hio Tong, Yan, George, Hoffman, Adam S., Qi, Zhen, Trimpalis, Antonios, Annamalai, Leelavathi, Ouyang, Mengyao, Liu, Jilei, Eagan, Nathaniel, Biener, Juergen, Sokaras, Dimosthenis, Flytzani-Stephanopoulos, Maria, Bare, Simon R., Sautet, Philippe, and Sykes, E. Charles H. 2022.  
"Replication Data for: Mechanistic and Electronic Insights into a Working NiAu Single-Atom Alloy Ethanol Dehydrogenation Catalyst".  United States.  doi:https://doi.org/10.7910/DVN/CHXIVV.  https://www.osti.gov/servlets/purl/1878476. Pub date:Mon Jan 10 23:00:00 EST 2022

Copy to clipboard


                    
@article{osti_1878476,

  title        = {Replication Data for: Mechanistic and Electronic Insights into a Working NiAu Single-Atom Alloy Ethanol Dehydrogenation Catalyst},

  author       = {Giannakakis, Georgios and Kress, Paul and Duanmu, Kaining and Ngan, Hio Tong and Yan, George and Hoffman, Adam S. and Qi, Zhen and Trimpalis, Antonios and Annamalai, Leelavathi and Ouyang, Mengyao and Liu, Jilei and Eagan, Nathaniel and Biener, Juergen and Sokaras, Dimosthenis and Flytzani-Stephanopoulos, Maria and Bare, Simon R. and Sautet, Philippe and Sykes, E. Charles H.},

  abstractNote = {The data underlying this published work have been made publicly available in this repository as part of the IMASC Data Management Plan. This work was supported as part of the Integrated Mesoscale Architectures for Sustainable Catalysis (IMASC), an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Basic Energy Sciences under Award # DE-SC0012573.},

  doi          = {10.7910/DVN/CHXIVV},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {Mon Jan 10 23:00:00 EST 2022},

  month        = {Mon Jan 10 23:00:00 EST 2022}

}

Copy to clipboard

Dataset:

View Dataset

DOI: https://doi.org/10.7910/DVN/CHXIVV

Save / Share:

Export Metadata

Save to My Library

Similar records in DOE Data Explorer and OSTI.GOV collections:

Mechanistic and Electronic Insights into a Working NiAu Single-Atom Alloy Ethanol Dehydrogenation Catalyst

Journal Article Giannakakis, Georgios ; Kress, Paul ; Duanmu, Kaining ; ... - Journal of the American Chemical Society

Elucidation of reaction mechanisms and the geometric and electronic structure of the active sites themselves is a challenging, yet essential task in the design of new heterogeneous catalysts. Such investigations are best implemented via a multi-pronged approach that comprises ambient pressure catalysis, surface science, and theory. Herein, we employ this strategy to understand the workings of NiAu single-atom alloy (SAA) catalysts for the selective non-oxidative dehydrogenation of ethanol to acetaldehyde and hydrogen. The atomic dispersion of Ni is paramount for selective ethanol to acetaldehyde conversion, and we show that even the presence of small Ni ensembles in the Au surfacemore »« less
Mechanistic and Electronic Insights into a Working NiAu Single-Atom Alloy Ethanol Dehydrogenation Catalyst

Journal Article Giannakakis, Georgios ; Kress, Paul ; Duanmu, Kaining ; ... - Journal of the American Chemical Society

Elucidation of reaction mechanisms and the geometric and electronic structure of the active sites themselves is a challenging, yet essential task in the design of new heterogeneous catalysts. Such investigations are best implemented via a multi-pronged approach that comprises ambient pressure catalysis, surface science, and theory. Herein, we employ this strategy to understand the workings of NiAu single-atom alloy (SAA) catalysts for the selective non-oxidative dehydrogenation of ethanol to acetaldehyde and hydrogen. The atomic dispersion of Ni is paramount for selective ethanol to acetaldehyde conversion, and we show that even the presence of small Ni ensembles in the Au surfacemore »« less
Replication Data for: Mechanistic insights into carbon-carbon coupling on NiAu and PdAu single-atom alloys

Dataset Kress, Paul ; Reocreux, Romain ; Hannagan, Ryan ; ...

The data underlying this published work have been made publicly available in this repository as part of the IMASC Data Management Plan. This work was supported as part of the Integrated Mesoscale Architectures for Sustainable Catalysis (IMASC), an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Basic Energy Sciences under Award # DE-SC0012573.
Replication Data for: NiAu single atom alloys for the selective oxidation of methacrolein with methanol to methyl methacrylate

Dataset Trimpalis, A . ; Giannakakis, G. ; Cao, M. ; ...

The data underlying this published work have been made publicly available in this repository as part of the IMASC Data Management Plan. This work was supported as part of the Integrated Mesoscale Architectures for Sustainable Catalysis (IMASC), an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Basic Energy Sciences under Award # DE-SC0012573.
Replication Data for: Stabilization of a nanoporous NiCu dilute alloy catalyst for non-oxidative ethanol dehydrogenation

Dataset Janvelyan, Nare ; van Spronsen, Matthijs A. ; Wu, Cheng Hao ; ...

The data underlying this published work have been made publicly available in this repository as part of the IMASC Data Management Plan. This work was supported as part of the Integrated Mesoscale Architectures for Sustainable Catalysis (IMASC), an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Basic Energy Sciences under Award # DE-SC0012573.

Similar Records