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Title: Influence of Agricultural Managed Aquifer Recharge (AgMAR) and Stratigraphic Heterogeneities on Nitrate Reduction in the Deep Subsurface

Abstract

This data package contains input files for TOUGHREACT for a modeling study examining the effects of managed aquifer recharge on agricultural lands on nitrate cycling and transport in the Central Valley of CA near Modesto. The files contain all the geochemical species, reactions, and hydrological parameters for the model. The files are text files used for the TOUGH family of code created by LBNL. To use the files a license is required. https://tough.lbl.gov/licensing-download/toughreact-licensing-download/Accompanying Paper Abstract: Agricultural managed aquifer recharge (AgMAR) is a proposed management strategy whereby surface water flows are used to intentionally flood croplands with the purpose of recharging underlying aquifers. However, legacy nitrate (NO3-) contamination in agriculturally-intensive regions poses a threat to groundwater resources under AgMAR. To address these concerns, we use a reactive transport modeling framework to better understand the effects of AgMAR management strategies (i.e., by varying the frequency, duration between flooding events, and amount of water) on N leaching to groundwater under different stratigraphic configurations and antecedent moisture conditions. In particular, we examine the potential of denitrification and nitrogen retention in deep vadose zone sediments (~15 m) using variable AgMAR application rates on two-dimensional representations of differently textured soils, soils with discontinuous bands/channels, and soilsmore » with preferential flow paths characteristic of typical agricultural field sites. Our results indicate that finer textured sediments, such as silt loams, alone or embedded within high flow regions, are important reducing zones providing conditions needed for denitrification. Simulation results further suggest that applying water all-at-once rather than in increments for a fixed volume of recharge transports higher concentrations of NO3- deeper into the profile, which has the potential to exacerbate groundwater quality. This transport into deeper depths can be aggravated by wetter antecedent soil moisture conditions. However, applying water all-at-once also increases denitrification within the vadose zone by promoting anoxic conditions. We conclude that AgMAR management strategies can be designed to enhance denitrification in the subsurface and reduce N leaching to groundwater, while specifically accounting for lithologic heterogeneity, antecedent soil moisture conditions, and depth to the water table. Our findings are potentially relevant to other systems that experience flooding inundation such as riparian corridors, floodplains, wetlands, and other managed landscapes like dedicated recharge basins.« less

Authors:
ORCiD logo
  1. University of California Berkeley; UC Berkeley
Publication Date:
Other Number(s):
paf_697
Research Org.:
Environmental System Science Data Infrastructure for a Virtual Ecosystem; Watershed Function SFA
Sponsoring Org.:
U.S. DOE > Office of Science > Biological and Environmental Research (BER)
Subject:
54 ENVIRONMENTAL SCIENCES; AgMAR; Agricultural Lands; Groundwater Quality; Managed Aquifer Recharge; Modeling; Nitrogen Cycling and Transport
OSTI Identifier:
1774081
DOI:
https://doi.org/10.15485/1774081

Citation Formats

Waterhouse, Hannah. Influence of Agricultural Managed Aquifer Recharge (AgMAR) and Stratigraphic Heterogeneities on Nitrate Reduction in the Deep Subsurface. United States: N. p., 2020. Web. doi:10.15485/1774081.
Waterhouse, Hannah. Influence of Agricultural Managed Aquifer Recharge (AgMAR) and Stratigraphic Heterogeneities on Nitrate Reduction in the Deep Subsurface. United States. doi:https://doi.org/10.15485/1774081
Waterhouse, Hannah. 2020. "Influence of Agricultural Managed Aquifer Recharge (AgMAR) and Stratigraphic Heterogeneities on Nitrate Reduction in the Deep Subsurface". United States. doi:https://doi.org/10.15485/1774081. https://www.osti.gov/servlets/purl/1774081. Pub date:Thu Dec 31 23:00:00 EST 2020
@article{osti_1774081,
title = {Influence of Agricultural Managed Aquifer Recharge (AgMAR) and Stratigraphic Heterogeneities on Nitrate Reduction in the Deep Subsurface},
author = {Waterhouse, Hannah},
abstractNote = {This data package contains input files for TOUGHREACT for a modeling study examining the effects of managed aquifer recharge on agricultural lands on nitrate cycling and transport in the Central Valley of CA near Modesto. The files contain all the geochemical species, reactions, and hydrological parameters for the model. The files are text files used for the TOUGH family of code created by LBNL. To use the files a license is required. https://tough.lbl.gov/licensing-download/toughreact-licensing-download/Accompanying Paper Abstract: Agricultural managed aquifer recharge (AgMAR) is a proposed management strategy whereby surface water flows are used to intentionally flood croplands with the purpose of recharging underlying aquifers. However, legacy nitrate (NO3-) contamination in agriculturally-intensive regions poses a threat to groundwater resources under AgMAR. To address these concerns, we use a reactive transport modeling framework to better understand the effects of AgMAR management strategies (i.e., by varying the frequency, duration between flooding events, and amount of water) on N leaching to groundwater under different stratigraphic configurations and antecedent moisture conditions. In particular, we examine the potential of denitrification and nitrogen retention in deep vadose zone sediments (~15 m) using variable AgMAR application rates on two-dimensional representations of differently textured soils, soils with discontinuous bands/channels, and soils with preferential flow paths characteristic of typical agricultural field sites. Our results indicate that finer textured sediments, such as silt loams, alone or embedded within high flow regions, are important reducing zones providing conditions needed for denitrification. Simulation results further suggest that applying water all-at-once rather than in increments for a fixed volume of recharge transports higher concentrations of NO3- deeper into the profile, which has the potential to exacerbate groundwater quality. This transport into deeper depths can be aggravated by wetter antecedent soil moisture conditions. However, applying water all-at-once also increases denitrification within the vadose zone by promoting anoxic conditions. We conclude that AgMAR management strategies can be designed to enhance denitrification in the subsurface and reduce N leaching to groundwater, while specifically accounting for lithologic heterogeneity, antecedent soil moisture conditions, and depth to the water table. Our findings are potentially relevant to other systems that experience flooding inundation such as riparian corridors, floodplains, wetlands, and other managed landscapes like dedicated recharge basins.},
doi = {10.15485/1774081},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Thu Dec 31 23:00:00 EST 2020},
month = {Thu Dec 31 23:00:00 EST 2020}
}