DOE Data Explorer title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Materials Data on U(MoO6)2 by Materials Project

Abstract

(UMo2O9)2(O2)3 crystallizes in the orthorhombic Pbcm space group. The structure is two-dimensional and consists of four trioxidane molecules and two UMo2O9 sheets oriented in the (0, 0, 1) direction. In each UMo2O9 sheet, U is bonded in a distorted pentagonal bipyramidal geometry to seven O atoms. There are a spread of U–O bond distances ranging from 1.79–2.48 Å. Mo is bonded in a 5-coordinate geometry to five O atoms. There are a spread of Mo–O bond distances ranging from 1.70–2.15 Å. There are six inequivalent O sites. In the first O site, O is bonded in a distorted trigonal planar geometry to one U and two equivalent Mo atoms. In the second O site, O is bonded in a single-bond geometry to one U atom. In the third O site, O is bonded in a single-bond geometry to one U atom. In the fourth O site, O is bonded in a single-bond geometry to one Mo atom. In the fifth O site, O is bonded in a bent 150 degrees geometry to one U and one Mo atom. In the sixth O site, O is bonded in a distorted trigonal non-coplanar geometry to one U and two equivalent Mo atoms.

Publication Date:
Other Number(s):
mp-1179232
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; U(MoO6)2; Mo-O-U
OSTI Identifier:
1752828
DOI:
https://doi.org/10.17188/1752828

Citation Formats

The Materials Project. Materials Data on U(MoO6)2 by Materials Project. United States: N. p., 2019. Web. doi:10.17188/1752828.
The Materials Project. Materials Data on U(MoO6)2 by Materials Project. United States. doi:https://doi.org/10.17188/1752828
The Materials Project. 2019. "Materials Data on U(MoO6)2 by Materials Project". United States. doi:https://doi.org/10.17188/1752828. https://www.osti.gov/servlets/purl/1752828. Pub date:Sat Nov 16 00:00:00 EST 2019
@article{osti_1752828,
title = {Materials Data on U(MoO6)2 by Materials Project},
author = {The Materials Project},
abstractNote = {(UMo2O9)2(O2)3 crystallizes in the orthorhombic Pbcm space group. The structure is two-dimensional and consists of four trioxidane molecules and two UMo2O9 sheets oriented in the (0, 0, 1) direction. In each UMo2O9 sheet, U is bonded in a distorted pentagonal bipyramidal geometry to seven O atoms. There are a spread of U–O bond distances ranging from 1.79–2.48 Å. Mo is bonded in a 5-coordinate geometry to five O atoms. There are a spread of Mo–O bond distances ranging from 1.70–2.15 Å. There are six inequivalent O sites. In the first O site, O is bonded in a distorted trigonal planar geometry to one U and two equivalent Mo atoms. In the second O site, O is bonded in a single-bond geometry to one U atom. In the third O site, O is bonded in a single-bond geometry to one U atom. In the fourth O site, O is bonded in a single-bond geometry to one Mo atom. In the fifth O site, O is bonded in a bent 150 degrees geometry to one U and one Mo atom. In the sixth O site, O is bonded in a distorted trigonal non-coplanar geometry to one U and two equivalent Mo atoms.},
doi = {10.17188/1752828},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {11}
}