Materials Data on Bi2O3 by Materials Project

doi:10.17188/1751675

Title: Materials Data on Bi2O3 by Materials Project

Abstract

Bi2O3 is Corundum-like structured and crystallizes in the trigonal R-3c space group. The structure is three-dimensional. Bi3+ is bonded in a 6-coordinate geometry to six equivalent O2- atoms. There are three shorter (2.29 Å) and three longer (2.53 Å) Bi–O bond lengths. O2- is bonded to four equivalent Bi3+ atoms to form a mixture of distorted corner and edge-sharing OBi4 tetrahedra.

Authors:: The Materials Project

Publication Date:: 2020-05-02

Other Number(s):: mp-1183524

DOE Contract Number:: AC02-05CH11231; EDCBEE

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Collaborations:: MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE

Keywords:: crystal structure; Bi2O3; Bi-O

OSTI Identifier:: 1751675

DOI:: https://doi.org/10.17188/1751675

Citation Formats


                    The Materials Project. Materials Data on Bi2O3 by Materials Project.  United States: N. p., 2020. 
        Web.  doi:10.17188/1751675.

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                    The Materials Project. Materials Data on Bi2O3 by Materials Project.  United States.  doi:https://doi.org/10.17188/1751675

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                    The Materials Project. 2020.  
"Materials Data on Bi2O3 by Materials Project".  United States.  doi:https://doi.org/10.17188/1751675.  https://www.osti.gov/servlets/purl/1751675. Pub date:Sat May 02 00:00:00 EDT 2020

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@article{osti_1751675,

  title        = {Materials Data on Bi2O3 by Materials Project},

  author       = {The Materials Project},

  abstractNote = {Bi2O3 is Corundum-like structured and crystallizes in the trigonal R-3c space group. The structure is three-dimensional. Bi3+ is bonded in a 6-coordinate geometry to six equivalent O2- atoms. There are three shorter (2.29 Å) and three longer (2.53 Å) Bi–O bond lengths. O2- is bonded to four equivalent Bi3+ atoms to form a mixture of distorted corner and edge-sharing OBi4 tetrahedra.},

  doi          = {10.17188/1751675},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {2020},

  month        = {5}

}

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DOI: https://doi.org/10.17188/1751675

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Works referenced in this record:

Synthesis and properties of glasses in the K2O–SiO2–Bi2O3–TiO2 system and bismuth titanate (Bi4Ti3O12) nano glass–ceramics thereof
journal, December 2010

Molla, Atiar Rahaman; Tarafder, Anal; Karmakar, Basudeb
Journal of Materials Science, Vol. 46, Issue 9
https://doi.org/10.1007/s10853-010-5173-1

Electrochemical reaction of lithium with orthorhombic bismuth tungstate thin films fabricated by radio-frequency sputtering
journal, December 2009

Li, Chi-Lin; Sun, Ke; Yu, Le
Electrochimica Acta, Vol. 55, Issue 1
https://doi.org/10.1016/j.electacta.2009.04.037

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Materials Data on Bi2O3 by Materials Project

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Bi2O3 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. there are two inequivalent Bi3+ sites. In the first Bi3+ site, Bi3+ is bonded in a 6-coordinate geometry to six O2- atoms. There are a spread of Bi–O bond distances ranging from 2.18–2.81 Å. In the second Bi3+ site, Bi3+ is bonded to five O2- atoms to form a mixture of distorted corner and edge-sharing BiO5 square pyramids. There are a spread of Bi–O bond distances ranging from 2.17–2.60 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a 4-coordinate geometrymore »« less
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Similar Records

Title: Materials Data on Bi2O3 by Materials Project

Abstract

Citation Formats

Synthesis and properties of glasses in the K2O–SiO2–Bi2O3–TiO2 system and bismuth titanate (Bi4Ti3O12) nano glass–ceramics thereof journal, December 2010

Electrochemical reaction of lithium with orthorhombic bismuth tungstate thin films fabricated by radio-frequency sputtering journal, December 2009

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journal, December 2010

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journal, December 2009