Materials Data on Th(BOs)2 by Materials Project

doi:10.17188/1750466

Title: Materials Data on Th(BOs)2 by Materials Project

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Abstract

Th(BOs)2 crystallizes in the tetragonal P4_2/n space group. The structure is zero-dimensional and consists of four thorium molecules and eight BOs clusters. In each BOs cluster, Os2- is bonded in a single-bond geometry to one B atom. The Os–B bond length is 1.78 Å. B is bonded in a single-bond geometry to one Os2- atom.

Publication Date:: Sat Jan 12 04:00:00 UTC 2019

Other Number(s):: mp-1210637

DOE Contract Number:: AC02-05CH11231

Research Org.:: LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Collaborations:: The Materials Project; MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE; B-Os-Th; Th(BOs)2; crystal structure

OSTI Identifier:: 1750466

DOI:: https://doi.org/10.17188/1750466

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                    Materials Data on Th(BOs)2 by Materials Project.  United States: N. p., 2019. 
        Web.  doi:10.17188/1750466.

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                    Materials Data on Th(BOs)2 by Materials Project.  United States.  doi:https://doi.org/10.17188/1750466

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                    2019.  
"Materials Data on Th(BOs)2 by Materials Project".  United States.  doi:https://doi.org/10.17188/1750466.  https://www.osti.gov/servlets/purl/1750466. Pub date:Sat Jan 12 04:00:00 UTC 2019

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@article{osti_1750466,

  title        = {Materials Data on Th(BOs)2 by Materials Project},

  
  abstractNote = {Th(BOs)2 crystallizes in the tetragonal P4_2/n space group. The structure is zero-dimensional and consists of four thorium molecules and eight BOs clusters. In each BOs cluster, Os2- is bonded in a single-bond geometry to one B atom. The Os–B bond length is 1.78 Å. B is bonded in a single-bond geometry to one Os2- atom.},

  doi          = {10.17188/1750466},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {Sat Jan 12 04:00:00 UTC 2019},

  month        = {Sat Jan 12 04:00:00 UTC 2019}

}

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DOI: https://doi.org/10.17188/1750466

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Materials Data on Th(BOs)2 by Materials Project

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Th(OsB)2 crystallizes in the orthorhombic Fddd space group. The structure is three-dimensional. Th4+ is bonded in a 4-coordinate geometry to four equivalent Os2- atoms. All Th–Os bond lengths are 3.04 Å. Os2- is bonded in a 4-coordinate geometry to two equivalent Th4+ and four equivalent B atoms. There are two shorter (2.10 Å) and two longer (2.18 Å) Os–B bond lengths. B is bonded to four equivalent Os2- atoms to form a mixture of distorted edge and corner-sharing BOs4 trigonal pyramids.
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Materials Data on Sm(BOs)2 by Materials Project

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