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Title: Materials Data on Ag(OsO3)2 by Materials Project

Abstract

Ag(OsO3)2 crystallizes in the orthorhombic Ima2 space group. The structure is three-dimensional. there are two inequivalent Os+5.50+ sites. In the first Os+5.50+ site, Os+5.50+ is bonded to six O2- atoms to form corner-sharing OsO6 octahedra. The corner-sharing octahedra tilt angles range from 35–46°. There are a spread of Os–O bond distances ranging from 1.87–1.96 Å. In the second Os+5.50+ site, Os+5.50+ is bonded to six O2- atoms to form corner-sharing OsO6 octahedra. The corner-sharing octahedra tilt angles range from 35–46°. There are a spread of Os–O bond distances ranging from 1.89–1.97 Å. Ag1+ is bonded in a hexagonal planar geometry to six O2- atoms. There are a spread of Ag–O bond distances ranging from 2.50–2.79 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a 4-coordinate geometry to two equivalent Os+5.50+ and two equivalent Ag1+ atoms. In the second O2- site, O2- is bonded in a bent 150 degrees geometry to two equivalent Os+5.50+ atoms. In the third O2- site, O2- is bonded in a distorted bent 150 degrees geometry to two Os+5.50+ and one Ag1+ atom. In the fourth O2- site, O2- is bonded in a 3-coordinate geometry to two Os+5.50+ andmore » one Ag1+ atom.« less

Authors:
Publication Date:
Other Number(s):
mp-1229205
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Ag(OsO3)2; Ag-O-Os
OSTI Identifier:
1742037
DOI:
https://doi.org/10.17188/1742037

Citation Formats

The Materials Project. Materials Data on Ag(OsO3)2 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1742037.
The Materials Project. Materials Data on Ag(OsO3)2 by Materials Project. United States. doi:https://doi.org/10.17188/1742037
The Materials Project. 2020. "Materials Data on Ag(OsO3)2 by Materials Project". United States. doi:https://doi.org/10.17188/1742037. https://www.osti.gov/servlets/purl/1742037. Pub date:Sun May 03 00:00:00 EDT 2020
@article{osti_1742037,
title = {Materials Data on Ag(OsO3)2 by Materials Project},
author = {The Materials Project},
abstractNote = {Ag(OsO3)2 crystallizes in the orthorhombic Ima2 space group. The structure is three-dimensional. there are two inequivalent Os+5.50+ sites. In the first Os+5.50+ site, Os+5.50+ is bonded to six O2- atoms to form corner-sharing OsO6 octahedra. The corner-sharing octahedra tilt angles range from 35–46°. There are a spread of Os–O bond distances ranging from 1.87–1.96 Å. In the second Os+5.50+ site, Os+5.50+ is bonded to six O2- atoms to form corner-sharing OsO6 octahedra. The corner-sharing octahedra tilt angles range from 35–46°. There are a spread of Os–O bond distances ranging from 1.89–1.97 Å. Ag1+ is bonded in a hexagonal planar geometry to six O2- atoms. There are a spread of Ag–O bond distances ranging from 2.50–2.79 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a 4-coordinate geometry to two equivalent Os+5.50+ and two equivalent Ag1+ atoms. In the second O2- site, O2- is bonded in a bent 150 degrees geometry to two equivalent Os+5.50+ atoms. In the third O2- site, O2- is bonded in a distorted bent 150 degrees geometry to two Os+5.50+ and one Ag1+ atom. In the fourth O2- site, O2- is bonded in a 3-coordinate geometry to two Os+5.50+ and one Ag1+ atom.},
doi = {10.17188/1742037},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}