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Title: Materials Data on Rb2Co3S4 by Materials Project

Abstract

Rb2Co3S4 crystallizes in the orthorhombic Ibam space group. The structure is three-dimensional. Rb1+ is bonded in a body-centered cubic geometry to eight equivalent S2- atoms. There are a spread of Rb–S bond distances ranging from 3.39–3.47 Å. There are two inequivalent Co2+ sites. In the first Co2+ site, Co2+ is bonded to four equivalent S2- atoms to form a mixture of edge and corner-sharing CoS4 tetrahedra. All Co–S bond lengths are 2.20 Å. In the second Co2+ site, Co2+ is bonded to four equivalent S2- atoms to form a mixture of edge and corner-sharing CoS4 tetrahedra. There are two shorter (2.18 Å) and two longer (2.22 Å) Co–S bond lengths. S2- is bonded in a 3-coordinate geometry to four equivalent Rb1+ and three Co2+ atoms.

Publication Date:
Other Number(s):
mp-1179796
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Rb2Co3S4; Co-Rb-S
OSTI Identifier:
1716902
DOI:
https://doi.org/10.17188/1716902

Citation Formats

The Materials Project. Materials Data on Rb2Co3S4 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1716902.
The Materials Project. Materials Data on Rb2Co3S4 by Materials Project. United States. doi:https://doi.org/10.17188/1716902
The Materials Project. 2020. "Materials Data on Rb2Co3S4 by Materials Project". United States. doi:https://doi.org/10.17188/1716902. https://www.osti.gov/servlets/purl/1716902. Pub date:Sat May 02 00:00:00 EDT 2020
@article{osti_1716902,
title = {Materials Data on Rb2Co3S4 by Materials Project},
author = {The Materials Project},
abstractNote = {Rb2Co3S4 crystallizes in the orthorhombic Ibam space group. The structure is three-dimensional. Rb1+ is bonded in a body-centered cubic geometry to eight equivalent S2- atoms. There are a spread of Rb–S bond distances ranging from 3.39–3.47 Å. There are two inequivalent Co2+ sites. In the first Co2+ site, Co2+ is bonded to four equivalent S2- atoms to form a mixture of edge and corner-sharing CoS4 tetrahedra. All Co–S bond lengths are 2.20 Å. In the second Co2+ site, Co2+ is bonded to four equivalent S2- atoms to form a mixture of edge and corner-sharing CoS4 tetrahedra. There are two shorter (2.18 Å) and two longer (2.22 Å) Co–S bond lengths. S2- is bonded in a 3-coordinate geometry to four equivalent Rb1+ and three Co2+ atoms.},
doi = {10.17188/1716902},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}