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Title: Materials Data on Rh(ClO7)3 by Materials Project

Abstract

(RhO6)2(O2)3(ClO4)6 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of twelve water molecules, twelve ClO4 clusters, and four RhO6 clusters. In each ClO4 cluster, there are four inequivalent O sites. In the first O site, O is bonded in a single-bond geometry to one Cl atom. The O–Cl bond length is 1.46 Å. In the second O site, O is bonded in a single-bond geometry to one Cl atom. The O–Cl bond length is 1.46 Å. In the third O site, O is bonded in a single-bond geometry to one Cl atom. The O–Cl bond length is 1.46 Å. In the fourth O site, O is bonded in a single-bond geometry to one Cl atom. The O–Cl bond length is 1.45 Å. Cl is bonded in a tetrahedral geometry to four O atoms. In each RhO6 cluster, Rh is bonded in a distorted octahedral geometry to six O atoms. There is four shorter (1.93 Å) and two longer (1.94 Å) Rh–O bond length. There are five inequivalent O sites. In the first O site, O is bonded in a single-bond geometry to one Rh atom. In the second O site,more » O is bonded in a single-bond geometry to one Rh atom. In the third O site, O is bonded in a single-bond geometry to one Rh atom. In the fourth O site, O is bonded in a single-bond geometry to one Rh atom. In the fifth O site, O is bonded in a single-bond geometry to one Rh atom.« less

Authors:
Publication Date:
Other Number(s):
mp-1219626
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Rh(ClO7)3; Cl-O-Rh
OSTI Identifier:
1711228
DOI:
https://doi.org/10.17188/1711228

Citation Formats

The Materials Project. Materials Data on Rh(ClO7)3 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1711228.
The Materials Project. Materials Data on Rh(ClO7)3 by Materials Project. United States. doi:https://doi.org/10.17188/1711228
The Materials Project. 2020. "Materials Data on Rh(ClO7)3 by Materials Project". United States. doi:https://doi.org/10.17188/1711228. https://www.osti.gov/servlets/purl/1711228. Pub date:Thu Apr 30 00:00:00 EDT 2020
@article{osti_1711228,
title = {Materials Data on Rh(ClO7)3 by Materials Project},
author = {The Materials Project},
abstractNote = {(RhO6)2(O2)3(ClO4)6 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of twelve water molecules, twelve ClO4 clusters, and four RhO6 clusters. In each ClO4 cluster, there are four inequivalent O sites. In the first O site, O is bonded in a single-bond geometry to one Cl atom. The O–Cl bond length is 1.46 Å. In the second O site, O is bonded in a single-bond geometry to one Cl atom. The O–Cl bond length is 1.46 Å. In the third O site, O is bonded in a single-bond geometry to one Cl atom. The O–Cl bond length is 1.46 Å. In the fourth O site, O is bonded in a single-bond geometry to one Cl atom. The O–Cl bond length is 1.45 Å. Cl is bonded in a tetrahedral geometry to four O atoms. In each RhO6 cluster, Rh is bonded in a distorted octahedral geometry to six O atoms. There is four shorter (1.93 Å) and two longer (1.94 Å) Rh–O bond length. There are five inequivalent O sites. In the first O site, O is bonded in a single-bond geometry to one Rh atom. In the second O site, O is bonded in a single-bond geometry to one Rh atom. In the third O site, O is bonded in a single-bond geometry to one Rh atom. In the fourth O site, O is bonded in a single-bond geometry to one Rh atom. In the fifth O site, O is bonded in a single-bond geometry to one Rh atom.},
doi = {10.17188/1711228},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}