U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on MnPbO3 by Materials Project
Abstract
MnPbO3 crystallizes in the monoclinic P2/c space group. The structure is three-dimensional. there are two inequivalent Mn4+ sites. In the first Mn4+ site, Mn4+ is bonded to six O2- atoms to form edge-sharing MnO6 octahedra. There are a spread of Mn–O bond distances ranging from 1.96–2.09 Å. In the second Mn4+ site, Mn4+ is bonded to six O2- atoms to form edge-sharing MnO6 octahedra. There are a spread of Mn–O bond distances ranging from 1.95–2.03 Å. Pb2+ is bonded in a 5-coordinate geometry to five O2- atoms. There are a spread of Pb–O bond distances ranging from 2.33–2.93 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a 4-coordinate geometry to three Mn4+ and one Pb2+ atom. In the second O2- site, O2- is bonded in a distorted trigonal non-coplanar geometry to three Mn4+ atoms. In the third O2- site, O2- is bonded to four equivalent Pb2+ atoms to form a mixture of edge and corner-sharing OPb4 tetrahedra. In the fourth O2- site, O2- is bonded to four equivalent Pb2+ atoms to form a mixture of edge and corner-sharing OPb4 tetrahedra.
- Authors:
- Publication Date:
- Other Number(s):
- mp-1188613
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; MnPbO3; Mn-O-Pb
- OSTI Identifier:
- 1709861
- DOI:
- https://doi.org/10.17188/1709861
Citation Formats
The Materials Project. Materials Data on MnPbO3 by Materials Project. United States: N. p., 2019.
Web. doi:10.17188/1709861.
The Materials Project. Materials Data on MnPbO3 by Materials Project. United States. doi:https://doi.org/10.17188/1709861
The Materials Project. 2019.
"Materials Data on MnPbO3 by Materials Project". United States. doi:https://doi.org/10.17188/1709861. https://www.osti.gov/servlets/purl/1709861. Pub date:Fri Jan 11 00:00:00 EST 2019
@article{osti_1709861,
title = {Materials Data on MnPbO3 by Materials Project},
author = {The Materials Project},
abstractNote = {MnPbO3 crystallizes in the monoclinic P2/c space group. The structure is three-dimensional. there are two inequivalent Mn4+ sites. In the first Mn4+ site, Mn4+ is bonded to six O2- atoms to form edge-sharing MnO6 octahedra. There are a spread of Mn–O bond distances ranging from 1.96–2.09 Å. In the second Mn4+ site, Mn4+ is bonded to six O2- atoms to form edge-sharing MnO6 octahedra. There are a spread of Mn–O bond distances ranging from 1.95–2.03 Å. Pb2+ is bonded in a 5-coordinate geometry to five O2- atoms. There are a spread of Pb–O bond distances ranging from 2.33–2.93 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a 4-coordinate geometry to three Mn4+ and one Pb2+ atom. In the second O2- site, O2- is bonded in a distorted trigonal non-coplanar geometry to three Mn4+ atoms. In the third O2- site, O2- is bonded to four equivalent Pb2+ atoms to form a mixture of edge and corner-sharing OPb4 tetrahedra. In the fourth O2- site, O2- is bonded to four equivalent Pb2+ atoms to form a mixture of edge and corner-sharing OPb4 tetrahedra.},
doi = {10.17188/1709861},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Fri Jan 11 00:00:00 EST 2019},
month = {Fri Jan 11 00:00:00 EST 2019}
}