Materials Data on KAu(CN)2 by Materials Project

doi:10.17188/1687655

Title: Materials Data on KAu(CN)2 by Materials Project

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Abstract

KAu(CN)2 crystallizes in the trigonal R-3 space group. The structure is two-dimensional and consists of three potassium molecules and three K2Au3(CN)6 sheets oriented in the (0, 0, 1) direction. In each K2Au3(CN)6 sheet, K1+ is bonded in a 6-coordinate geometry to three equivalent Au1- and three equivalent N3- atoms. All K–Au bond lengths are 3.19 Å. All K–N bond lengths are 3.10 Å. Au1- is bonded in a linear geometry to two equivalent K1+ atoms. C3+ is bonded in a single-bond geometry to one N3- atom. The C–N bond length is 1.17 Å. N3- is bonded in a distorted single-bond geometry to one K1+ and one C3+ atom.

Authors:: The Materials Project

Publication Date:: 2019-01-11

Other Number(s):: mp-1181708

DOE Contract Number:: AC02-05CH11231; EDCBEE

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Collaborations:: MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE

Keywords:: crystal structure; KAu(CN)2; Au-C-K-N

OSTI Identifier:: 1687655

DOI:: https://doi.org/10.17188/1687655

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                    The Materials Project. Materials Data on KAu(CN)2 by Materials Project.  United States: N. p., 2019. 
        Web.  doi:10.17188/1687655.

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                    The Materials Project. Materials Data on KAu(CN)2 by Materials Project.  United States.  doi:https://doi.org/10.17188/1687655

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                    The Materials Project. 2019.  
"Materials Data on KAu(CN)2 by Materials Project".  United States.  doi:https://doi.org/10.17188/1687655.  https://www.osti.gov/servlets/purl/1687655. Pub date:Fri Jan 11 00:00:00 EST 2019

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@article{osti_1687655,

  title        = {Materials Data on KAu(CN)2 by Materials Project},

  author       = {The Materials Project},

  abstractNote = {KAu(CN)2 crystallizes in the trigonal R-3 space group. The structure is two-dimensional and consists of three potassium molecules and three K2Au3(CN)6 sheets oriented in the (0, 0, 1) direction. In each K2Au3(CN)6 sheet, K1+ is bonded in a 6-coordinate geometry to three equivalent Au1- and three equivalent N3- atoms. All K–Au bond lengths are 3.19 Å. All K–N bond lengths are 3.10 Å. Au1- is bonded in a linear geometry to two equivalent K1+ atoms. C3+ is bonded in a single-bond geometry to one N3- atom. The C–N bond length is 1.17 Å. N3- is bonded in a distorted single-bond geometry to one K1+ and one C3+ atom.},

  doi          = {10.17188/1687655},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {2019},

  month        = {1}

}

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DOI: https://doi.org/10.17188/1687655

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