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Title: Materials Data on RbB2SbO6 by Materials Project

Abstract

RbB2SbO6 crystallizes in the orthorhombic Pmn2_1 space group. The structure is three-dimensional. Rb1+ is bonded in a 8-coordinate geometry to eight O2- atoms. There are a spread of Rb–O bond distances ranging from 3.01–3.26 Å. B3+ is bonded in a trigonal planar geometry to three O2- atoms. There are a spread of B–O bond distances ranging from 1.35–1.41 Å. Sb5+ is bonded to six O2- atoms to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles are 2°. There are a spread of Sb–O bond distances ranging from 1.94–2.01 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a 2-coordinate geometry to two equivalent Rb1+, one B3+, and one Sb5+ atom. In the second O2- site, O2- is bonded in a distorted bent 120 degrees geometry to two equivalent Rb1+ and two equivalent B3+ atoms. In the third O2- site, O2- is bonded in a linear geometry to two equivalent Sb5+ atoms. In the fourth O2- site, O2- is bonded in a 2-coordinate geometry to one Rb1+, one B3+, and one Sb5+ atom.

Publication Date:
Other Number(s):
mp-1209317
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; RbB2SbO6; B-O-Rb-Sb
OSTI Identifier:
1680549
DOI:
https://doi.org/10.17188/1680549

Citation Formats

The Materials Project. Materials Data on RbB2SbO6 by Materials Project. United States: N. p., 2019. Web. doi:10.17188/1680549.
The Materials Project. Materials Data on RbB2SbO6 by Materials Project. United States. doi:https://doi.org/10.17188/1680549
The Materials Project. 2019. "Materials Data on RbB2SbO6 by Materials Project". United States. doi:https://doi.org/10.17188/1680549. https://www.osti.gov/servlets/purl/1680549. Pub date:Sat Jan 12 00:00:00 EST 2019
@article{osti_1680549,
title = {Materials Data on RbB2SbO6 by Materials Project},
author = {The Materials Project},
abstractNote = {RbB2SbO6 crystallizes in the orthorhombic Pmn2_1 space group. The structure is three-dimensional. Rb1+ is bonded in a 8-coordinate geometry to eight O2- atoms. There are a spread of Rb–O bond distances ranging from 3.01–3.26 Å. B3+ is bonded in a trigonal planar geometry to three O2- atoms. There are a spread of B–O bond distances ranging from 1.35–1.41 Å. Sb5+ is bonded to six O2- atoms to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles are 2°. There are a spread of Sb–O bond distances ranging from 1.94–2.01 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a 2-coordinate geometry to two equivalent Rb1+, one B3+, and one Sb5+ atom. In the second O2- site, O2- is bonded in a distorted bent 120 degrees geometry to two equivalent Rb1+ and two equivalent B3+ atoms. In the third O2- site, O2- is bonded in a linear geometry to two equivalent Sb5+ atoms. In the fourth O2- site, O2- is bonded in a 2-coordinate geometry to one Rb1+, one B3+, and one Sb5+ atom.},
doi = {10.17188/1680549},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}