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Title: Materials Data on Rb4SbRhCl12 by Materials Project

Abstract

Rb4RhSbCl12 crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. Rb1+ is bonded in a 12-coordinate geometry to twelve Cl1- atoms. There are a spread of Rb–Cl bond distances ranging from 3.39–3.98 Å. Rh3+ is bonded in an octahedral geometry to six Cl1- atoms. All Rh–Cl bond lengths are 2.38 Å. Sb5+ is bonded in an octahedral geometry to six Cl1- atoms. There are four shorter (2.42 Å) and two longer (2.44 Å) Sb–Cl bond lengths. There are four inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a distorted single-bond geometry to four equivalent Rb1+ and one Rh3+ atom. In the second Cl1- site, Cl1- is bonded in a distorted single-bond geometry to four equivalent Rb1+ and one Sb5+ atom. In the third Cl1- site, Cl1- is bonded in a single-bond geometry to four equivalent Rb1+ and one Sb5+ atom. In the fourth Cl1- site, Cl1- is bonded to four equivalent Rb1+ and one Rh3+ atom to form a mixture of distorted edge, corner, and face-sharing ClRb4Rh square pyramids.

Publication Date:
Other Number(s):
mp-1219625
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Rb4SbRhCl12; Cl-Rb-Rh-Sb
OSTI Identifier:
1667116
DOI:
https://doi.org/10.17188/1667116

Citation Formats

The Materials Project. Materials Data on Rb4SbRhCl12 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1667116.
The Materials Project. Materials Data on Rb4SbRhCl12 by Materials Project. United States. doi:https://doi.org/10.17188/1667116
The Materials Project. 2020. "Materials Data on Rb4SbRhCl12 by Materials Project". United States. doi:https://doi.org/10.17188/1667116. https://www.osti.gov/servlets/purl/1667116. Pub date:Sat May 02 00:00:00 EDT 2020
@article{osti_1667116,
title = {Materials Data on Rb4SbRhCl12 by Materials Project},
author = {The Materials Project},
abstractNote = {Rb4RhSbCl12 crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. Rb1+ is bonded in a 12-coordinate geometry to twelve Cl1- atoms. There are a spread of Rb–Cl bond distances ranging from 3.39–3.98 Å. Rh3+ is bonded in an octahedral geometry to six Cl1- atoms. All Rh–Cl bond lengths are 2.38 Å. Sb5+ is bonded in an octahedral geometry to six Cl1- atoms. There are four shorter (2.42 Å) and two longer (2.44 Å) Sb–Cl bond lengths. There are four inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a distorted single-bond geometry to four equivalent Rb1+ and one Rh3+ atom. In the second Cl1- site, Cl1- is bonded in a distorted single-bond geometry to four equivalent Rb1+ and one Sb5+ atom. In the third Cl1- site, Cl1- is bonded in a single-bond geometry to four equivalent Rb1+ and one Sb5+ atom. In the fourth Cl1- site, Cl1- is bonded to four equivalent Rb1+ and one Rh3+ atom to form a mixture of distorted edge, corner, and face-sharing ClRb4Rh square pyramids.},
doi = {10.17188/1667116},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}