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Title: Materials Data on CoH4S(NO2)2 by Materials Project

Abstract

CoSO4(NH2)2 crystallizes in the orthorhombic Pccn space group. The structure is three-dimensional and consists of eight ammonia molecules and one CoSO4 framework. In the CoSO4 framework, Co4+ is bonded in a square co-planar geometry to four O2- atoms. There are two shorter (2.12 Å) and two longer (2.13 Å) Co–O bond lengths. S2- is bonded in a tetrahedral geometry to four O2- atoms. There is two shorter (1.49 Å) and two longer (1.50 Å) S–O bond length. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted bent 120 degrees geometry to one Co4+ and one S2- atom. In the second O2- site, O2- is bonded in a bent 150 degrees geometry to one Co4+ and one S2- atom.

Authors:
Publication Date:
Other Number(s):
mp-1199194
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; CoH4S(NO2)2; Co-H-N-O-S
OSTI Identifier:
1666539
DOI:
https://doi.org/10.17188/1666539

Citation Formats

The Materials Project. Materials Data on CoH4S(NO2)2 by Materials Project. United States: N. p., 2019. Web. doi:10.17188/1666539.
The Materials Project. Materials Data on CoH4S(NO2)2 by Materials Project. United States. doi:https://doi.org/10.17188/1666539
The Materials Project. 2019. "Materials Data on CoH4S(NO2)2 by Materials Project". United States. doi:https://doi.org/10.17188/1666539. https://www.osti.gov/servlets/purl/1666539. Pub date:Sat Jan 12 00:00:00 EST 2019
@article{osti_1666539,
title = {Materials Data on CoH4S(NO2)2 by Materials Project},
author = {The Materials Project},
abstractNote = {CoSO4(NH2)2 crystallizes in the orthorhombic Pccn space group. The structure is three-dimensional and consists of eight ammonia molecules and one CoSO4 framework. In the CoSO4 framework, Co4+ is bonded in a square co-planar geometry to four O2- atoms. There are two shorter (2.12 Å) and two longer (2.13 Å) Co–O bond lengths. S2- is bonded in a tetrahedral geometry to four O2- atoms. There is two shorter (1.49 Å) and two longer (1.50 Å) S–O bond length. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted bent 120 degrees geometry to one Co4+ and one S2- atom. In the second O2- site, O2- is bonded in a bent 150 degrees geometry to one Co4+ and one S2- atom.},
doi = {10.17188/1666539},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}