Materials Data on RbAl(H2N)4 by Materials Project

doi:10.17188/1655250

Title: Materials Data on RbAl(H2N)4 by Materials Project

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Abstract

RbAl(NH2)4 crystallizes in the tetragonal P4/n space group. The structure is two-dimensional and consists of one RbAl(NH2)4 sheet oriented in the (0, 0, 1) direction. Rb1+ is bonded in a square co-planar geometry to four equivalent N3- atoms. All Rb–N bond lengths are 3.17 Å. Al3+ is bonded in a tetrahedral geometry to four equivalent N3- atoms. All Al–N bond lengths are 1.87 Å. N3- is bonded in a 3-coordinate geometry to one Rb1+, one Al3+, and two H1+ atoms. Both N–H bond lengths are 1.02 Å. There are two inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom.

Publication Date:: Fri Jan 11 04:00:00 UTC 2019

Other Number(s):: mp-1193778

DOE Contract Number:: AC02-05CH11231

Research Org.:: LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Collaborations:: The Materials Project; MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE; Al-H-N-Rb; RbAl(H2N)4; crystal structure

OSTI Identifier:: 1655250

DOI:: https://doi.org/10.17188/1655250

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                    Materials Data on RbAl(H2N)4 by Materials Project.  United States: N. p., 2019. 
        Web.  doi:10.17188/1655250.

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                    Materials Data on RbAl(H2N)4 by Materials Project.  United States.  doi:https://doi.org/10.17188/1655250

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                    2019.  
"Materials Data on RbAl(H2N)4 by Materials Project".  United States.  doi:https://doi.org/10.17188/1655250.  https://www.osti.gov/servlets/purl/1655250. Pub date:Fri Jan 11 04:00:00 UTC 2019

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@article{osti_1655250,

  title        = {Materials Data on RbAl(H2N)4 by Materials Project},

  
  abstractNote = {RbAl(NH2)4 crystallizes in the tetragonal P4/n space group. The structure is two-dimensional and consists of one RbAl(NH2)4 sheet oriented in the (0, 0, 1) direction. Rb1+ is bonded in a square co-planar geometry to four equivalent N3- atoms. All Rb–N bond lengths are 3.17 Å. Al3+ is bonded in a tetrahedral geometry to four equivalent N3- atoms. All Al–N bond lengths are 1.87 Å. N3- is bonded in a 3-coordinate geometry to one Rb1+, one Al3+, and two H1+ atoms. Both N–H bond lengths are 1.02 Å. There are two inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom.},

  doi          = {10.17188/1655250},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {Fri Jan 11 04:00:00 UTC 2019},

  month        = {Fri Jan 11 04:00:00 UTC 2019}

}

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DOI: https://doi.org/10.17188/1655250

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