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Title: Materials Data on Co2N16O9 by Materials Project

Abstract

Co2N5(N2)4(NO3)3 crystallizes in the tetragonal P4_2nm space group. The structure is zero-dimensional and consists of four ammonia molecules, six nitric acid molecules, four triazane molecules, and two Co2N5 clusters. In each Co2N5 cluster, Co2+ is bonded in a trigonal planar geometry to three N+0.88+ atoms. There is two shorter (1.59 Å) and one longer (1.67 Å) Co–N bond length. There are two inequivalent N+0.88+ sites. In the first N+0.88+ site, N+0.88+ is bonded in a bent 150 degrees geometry to two equivalent Co2+ atoms. In the second N+0.88+ site, N+0.88+ is bonded in a single-bond geometry to one Co2+ atom.

Publication Date:
Other Number(s):
mp-1182683
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Co2N16O9; Co-N-O
OSTI Identifier:
1652289
DOI:
https://doi.org/10.17188/1652289

Citation Formats

The Materials Project. Materials Data on Co2N16O9 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1652289.
The Materials Project. Materials Data on Co2N16O9 by Materials Project. United States. doi:https://doi.org/10.17188/1652289
The Materials Project. 2020. "Materials Data on Co2N16O9 by Materials Project". United States. doi:https://doi.org/10.17188/1652289. https://www.osti.gov/servlets/purl/1652289. Pub date:Wed Apr 29 00:00:00 EDT 2020
@article{osti_1652289,
title = {Materials Data on Co2N16O9 by Materials Project},
author = {The Materials Project},
abstractNote = {Co2N5(N2)4(NO3)3 crystallizes in the tetragonal P4_2nm space group. The structure is zero-dimensional and consists of four ammonia molecules, six nitric acid molecules, four triazane molecules, and two Co2N5 clusters. In each Co2N5 cluster, Co2+ is bonded in a trigonal planar geometry to three N+0.88+ atoms. There is two shorter (1.59 Å) and one longer (1.67 Å) Co–N bond length. There are two inequivalent N+0.88+ sites. In the first N+0.88+ site, N+0.88+ is bonded in a bent 150 degrees geometry to two equivalent Co2+ atoms. In the second N+0.88+ site, N+0.88+ is bonded in a single-bond geometry to one Co2+ atom.},
doi = {10.17188/1652289},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}