U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Co2N16O9 by Materials Project
Abstract
Co2N5(N2)4(NO3)3 crystallizes in the tetragonal P4_2nm space group. The structure is zero-dimensional and consists of four ammonia molecules, six nitric acid molecules, four triazane molecules, and two Co2N5 clusters. In each Co2N5 cluster, Co2+ is bonded in a trigonal planar geometry to three N+0.88+ atoms. There is two shorter (1.59 Å) and one longer (1.67 Å) Co–N bond length. There are two inequivalent N+0.88+ sites. In the first N+0.88+ site, N+0.88+ is bonded in a bent 150 degrees geometry to two equivalent Co2+ atoms. In the second N+0.88+ site, N+0.88+ is bonded in a single-bond geometry to one Co2+ atom.
- Publication Date:
- Other Number(s):
- mp-1182683
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Co-N-O; Co2N16O9; crystal structure
- OSTI Identifier:
- 1652289
- DOI:
- https://doi.org/10.17188/1652289
Citation Formats
Materials Data on Co2N16O9 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1652289.
Materials Data on Co2N16O9 by Materials Project. United States. doi:https://doi.org/10.17188/1652289
2020.
"Materials Data on Co2N16O9 by Materials Project". United States. doi:https://doi.org/10.17188/1652289. https://www.osti.gov/servlets/purl/1652289. Pub date:Wed Apr 29 00:00:00 EDT 2020
@article{osti_1652289,
title = {Materials Data on Co2N16O9 by Materials Project},
abstractNote = {Co2N5(N2)4(NO3)3 crystallizes in the tetragonal P4_2nm space group. The structure is zero-dimensional and consists of four ammonia molecules, six nitric acid molecules, four triazane molecules, and two Co2N5 clusters. In each Co2N5 cluster, Co2+ is bonded in a trigonal planar geometry to three N+0.88+ atoms. There is two shorter (1.59 Å) and one longer (1.67 Å) Co–N bond length. There are two inequivalent N+0.88+ sites. In the first N+0.88+ site, N+0.88+ is bonded in a bent 150 degrees geometry to two equivalent Co2+ atoms. In the second N+0.88+ site, N+0.88+ is bonded in a single-bond geometry to one Co2+ atom.},
doi = {10.17188/1652289},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}
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