Materials Data on AgClO2 by Materials Project
Abstract
AgO2Cl crystallizes in the monoclinic P2_1/m space group. The structure is two-dimensional and consists of one AgO2Cl sheet oriented in the (0, 0, 1) direction. Ag is bonded to one O and five equivalent Cl atoms to form a mixture of edge and corner-sharing AgCl5O octahedra. The corner-sharing octahedral tilt angles are 3°. The Ag–O bond length is 2.75 Å. There are four shorter (2.71 Å) and one longer (2.87 Å) Ag–Cl bond lengths. There are two inequivalent O sites. In the first O site, O is bonded in a bent 120 degrees geometry to one Ag and one O atom. The O–O bond length is 1.24 Å. In the second O site, O is bonded in a single-bond geometry to one O atom. Cl is bonded to five equivalent Ag atoms to form a mixture of edge and corner-sharing ClAg5 square pyramids.
- Authors:
- Publication Date:
- Other Number(s):
- mp-997013
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; AgClO2; Ag-Cl-O
- OSTI Identifier:
- 1317131
- DOI:
- https://doi.org/10.17188/1317131
Citation Formats
The Materials Project. Materials Data on AgClO2 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1317131.
The Materials Project. Materials Data on AgClO2 by Materials Project. United States. doi:https://doi.org/10.17188/1317131
The Materials Project. 2020.
"Materials Data on AgClO2 by Materials Project". United States. doi:https://doi.org/10.17188/1317131. https://www.osti.gov/servlets/purl/1317131. Pub date:Thu Jul 23 00:00:00 EDT 2020
@article{osti_1317131,
title = {Materials Data on AgClO2 by Materials Project},
author = {The Materials Project},
abstractNote = {AgO2Cl crystallizes in the monoclinic P2_1/m space group. The structure is two-dimensional and consists of one AgO2Cl sheet oriented in the (0, 0, 1) direction. Ag is bonded to one O and five equivalent Cl atoms to form a mixture of edge and corner-sharing AgCl5O octahedra. The corner-sharing octahedral tilt angles are 3°. The Ag–O bond length is 2.75 Å. There are four shorter (2.71 Å) and one longer (2.87 Å) Ag–Cl bond lengths. There are two inequivalent O sites. In the first O site, O is bonded in a bent 120 degrees geometry to one Ag and one O atom. The O–O bond length is 1.24 Å. In the second O site, O is bonded in a single-bond geometry to one O atom. Cl is bonded to five equivalent Ag atoms to form a mixture of edge and corner-sharing ClAg5 square pyramids.},
doi = {10.17188/1317131},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}