U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Sr(SbPd)2 by Materials Project
Abstract
Sr(PdSb)2 crystallizes in the tetragonal P4/nmm space group. The structure is three-dimensional. Sr2+ is bonded in a 8-coordinate geometry to eight Sb3- atoms. There are four shorter (3.56 Å) and four longer (3.66 Å) Sr–Sb bond lengths. There are two inequivalent Pd2+ sites. In the first Pd2+ site, Pd2+ is bonded to four equivalent Sb3- atoms to form a mixture of edge and corner-sharing PdSb4 tetrahedra. All Pd–Sb bond lengths are 2.72 Å. In the second Pd2+ site, Pd2+ is bonded in a 5-coordinate geometry to five Sb3- atoms. There are one shorter (2.65 Å) and four longer (2.74 Å) Pd–Sb bond lengths. There are two inequivalent Sb3- sites. In the first Sb3- site, Sb3- is bonded in a 4-coordinate geometry to four equivalent Sr2+ and four equivalent Pd2+ atoms. In the second Sb3- site, Sb3- is bonded in a 9-coordinate geometry to four equivalent Sr2+ and five Pd2+ atoms.
- Authors:
- Publication Date:
- Other Number(s):
- mp-8468
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Sr(SbPd)2; Pd-Sb-Sr
- OSTI Identifier:
- 1308121
- DOI:
- https://doi.org/10.17188/1308121
Citation Formats
The Materials Project. Materials Data on Sr(SbPd)2 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1308121.
The Materials Project. Materials Data on Sr(SbPd)2 by Materials Project. United States. doi:https://doi.org/10.17188/1308121
The Materials Project. 2020.
"Materials Data on Sr(SbPd)2 by Materials Project". United States. doi:https://doi.org/10.17188/1308121. https://www.osti.gov/servlets/purl/1308121. Pub date:Thu Jul 16 00:00:00 EDT 2020
@article{osti_1308121,
title = {Materials Data on Sr(SbPd)2 by Materials Project},
author = {The Materials Project},
abstractNote = {Sr(PdSb)2 crystallizes in the tetragonal P4/nmm space group. The structure is three-dimensional. Sr2+ is bonded in a 8-coordinate geometry to eight Sb3- atoms. There are four shorter (3.56 Å) and four longer (3.66 Å) Sr–Sb bond lengths. There are two inequivalent Pd2+ sites. In the first Pd2+ site, Pd2+ is bonded to four equivalent Sb3- atoms to form a mixture of edge and corner-sharing PdSb4 tetrahedra. All Pd–Sb bond lengths are 2.72 Å. In the second Pd2+ site, Pd2+ is bonded in a 5-coordinate geometry to five Sb3- atoms. There are one shorter (2.65 Å) and four longer (2.74 Å) Pd–Sb bond lengths. There are two inequivalent Sb3- sites. In the first Sb3- site, Sb3- is bonded in a 4-coordinate geometry to four equivalent Sr2+ and four equivalent Pd2+ atoms. In the second Sb3- site, Sb3- is bonded in a 9-coordinate geometry to four equivalent Sr2+ and five Pd2+ atoms.},
doi = {10.17188/1308121},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}