U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Bi2(SO4)3 by Materials Project
Abstract
Bi2(SO4)3 crystallizes in the trigonal R-3c space group. The structure is three-dimensional. Bi3+ is bonded to six O2- atoms to form BiO6 octahedra that share corners with six equivalent SO4 tetrahedra. There are three shorter (2.33 Å) and three longer (2.37 Å) Bi–O bond lengths. S6+ is bonded to four O2- atoms to form SO4 tetrahedra that share corners with four equivalent BiO6 octahedra. The corner-sharing octahedra tilt angles range from 22–41°. There is two shorter (1.48 Å) and two longer (1.49 Å) S–O bond length. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one Bi3+ and one S6+ atom. In the second O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one Bi3+ and one S6+ atom.
- Publication Date:
- Other Number(s):
- mp-768482
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Bi-O-S; Bi2(SO4)3; crystal structure
- OSTI Identifier:
- 1298432
- DOI:
- https://doi.org/10.17188/1298432
Citation Formats
Materials Data on Bi2(SO4)3 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1298432.
Materials Data on Bi2(SO4)3 by Materials Project. United States. doi:https://doi.org/10.17188/1298432
2020.
"Materials Data on Bi2(SO4)3 by Materials Project". United States. doi:https://doi.org/10.17188/1298432. https://www.osti.gov/servlets/purl/1298432. Pub date:Sun May 03 04:00:00 UTC 2020
@article{osti_1298432,
title = {Materials Data on Bi2(SO4)3 by Materials Project},
abstractNote = {Bi2(SO4)3 crystallizes in the trigonal R-3c space group. The structure is three-dimensional. Bi3+ is bonded to six O2- atoms to form BiO6 octahedra that share corners with six equivalent SO4 tetrahedra. There are three shorter (2.33 Å) and three longer (2.37 Å) Bi–O bond lengths. S6+ is bonded to four O2- atoms to form SO4 tetrahedra that share corners with four equivalent BiO6 octahedra. The corner-sharing octahedra tilt angles range from 22–41°. There is two shorter (1.48 Å) and two longer (1.49 Å) S–O bond length. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one Bi3+ and one S6+ atom. In the second O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one Bi3+ and one S6+ atom.},
doi = {10.17188/1298432},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sun May 03 04:00:00 UTC 2020},
month = {Sun May 03 04:00:00 UTC 2020}
}