U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Li3Mn2(NiO4)2 by Materials Project
Abstract
LiMnO2(LiNiO2)2MnO2 crystallizes in the triclinic P-1 space group. The structure is one-dimensional and consists of one manganese hydroxide (mn(oh)2) molecule; one LiMnO2 ribbon oriented in the (1, 1, 1) direction; and two LiNiO2 ribbons oriented in the (1, 1, 1) direction. In the LiMnO2 ribbon, Li1+ is bonded in a distorted linear geometry to two equivalent O2- atoms. Both Li–O bond lengths are 1.60 Å. Mn+4.50+ is bonded in a distorted linear geometry to two equivalent O2- atoms. Both Mn–O bond lengths are 1.37 Å. O2- is bonded in a distorted linear geometry to one Li1+ and one Mn+4.50+ atom. In each LiNiO2 ribbon, Li1+ is bonded in a linear geometry to two equivalent O2- atoms. Both Li–O bond lengths are 1.45 Å. Ni2+ is bonded in a distorted linear geometry to two equivalent O2- atoms. Both Ni–O bond lengths are 1.56 Å. O2- is bonded in a 2-coordinate geometry to one Li1+ and one Ni2+ atom.
- Authors:
- Publication Date:
- Other Number(s):
- mp-763752
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Li3Mn2(NiO4)2; Li-Mn-Ni-O
- OSTI Identifier:
- 1293856
- DOI:
- https://doi.org/10.17188/1293856
Citation Formats
The Materials Project. Materials Data on Li3Mn2(NiO4)2 by Materials Project. United States: N. p., 2019.
Web. doi:10.17188/1293856.
The Materials Project. Materials Data on Li3Mn2(NiO4)2 by Materials Project. United States. doi:https://doi.org/10.17188/1293856
The Materials Project. 2019.
"Materials Data on Li3Mn2(NiO4)2 by Materials Project". United States. doi:https://doi.org/10.17188/1293856. https://www.osti.gov/servlets/purl/1293856. Pub date:Fri Jan 11 00:00:00 EST 2019
@article{osti_1293856,
title = {Materials Data on Li3Mn2(NiO4)2 by Materials Project},
author = {The Materials Project},
abstractNote = {LiMnO2(LiNiO2)2MnO2 crystallizes in the triclinic P-1 space group. The structure is one-dimensional and consists of one manganese hydroxide (mn(oh)2) molecule; one LiMnO2 ribbon oriented in the (1, 1, 1) direction; and two LiNiO2 ribbons oriented in the (1, 1, 1) direction. In the LiMnO2 ribbon, Li1+ is bonded in a distorted linear geometry to two equivalent O2- atoms. Both Li–O bond lengths are 1.60 Å. Mn+4.50+ is bonded in a distorted linear geometry to two equivalent O2- atoms. Both Mn–O bond lengths are 1.37 Å. O2- is bonded in a distorted linear geometry to one Li1+ and one Mn+4.50+ atom. In each LiNiO2 ribbon, Li1+ is bonded in a linear geometry to two equivalent O2- atoms. Both Li–O bond lengths are 1.45 Å. Ni2+ is bonded in a distorted linear geometry to two equivalent O2- atoms. Both Ni–O bond lengths are 1.56 Å. O2- is bonded in a 2-coordinate geometry to one Li1+ and one Ni2+ atom.},
doi = {10.17188/1293856},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {1}
}