U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Sb2H4AuF16 by Materials Project
Abstract
AuSb2H4F16 crystallizes in the triclinic P-1 space group. The structure is two-dimensional and consists of one AuSb2H4F16 sheet oriented in the (0, 1, 0) direction. Au2+ is bonded in a distorted square co-planar geometry to six F1- atoms. There are a spread of Au–F bond distances ranging from 2.15–2.80 Å. Sb5+ is bonded in an octahedral geometry to six F1- atoms. There are a spread of Sb–F bond distances ranging from 1.89–2.02 Å. There are two inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a linear geometry to two F1- atoms. There is one shorter (1.03 Å) and one longer (1.35 Å) H–F bond length. In the second H1+ site, H1+ is bonded in a distorted single-bond geometry to two F1- atoms. There is one shorter (0.98 Å) and one longer (1.56 Å) H–F bond length. There are eight inequivalent F1- sites. In the first F1- site, F1- is bonded in a bent 120 degrees geometry to two H1+ atoms. In the second F1- site, F1- is bonded in a distorted single-bond geometry to one Au2+ and one H1+ atom. In the third F1- site, F1- is bonded in a bent 150 degrees geometry to onemore »
- Authors:
- Publication Date:
- Other Number(s):
- mp-760678
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Sb2H4AuF16; Au-F-H-Sb
- OSTI Identifier:
- 1291683
- DOI:
- https://doi.org/10.17188/1291683
Citation Formats
The Materials Project. Materials Data on Sb2H4AuF16 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1291683.
The Materials Project. Materials Data on Sb2H4AuF16 by Materials Project. United States. doi:https://doi.org/10.17188/1291683
The Materials Project. 2020.
"Materials Data on Sb2H4AuF16 by Materials Project". United States. doi:https://doi.org/10.17188/1291683. https://www.osti.gov/servlets/purl/1291683. Pub date:Sat Jul 18 00:00:00 EDT 2020
@article{osti_1291683,
title = {Materials Data on Sb2H4AuF16 by Materials Project},
author = {The Materials Project},
abstractNote = {AuSb2H4F16 crystallizes in the triclinic P-1 space group. The structure is two-dimensional and consists of one AuSb2H4F16 sheet oriented in the (0, 1, 0) direction. Au2+ is bonded in a distorted square co-planar geometry to six F1- atoms. There are a spread of Au–F bond distances ranging from 2.15–2.80 Å. Sb5+ is bonded in an octahedral geometry to six F1- atoms. There are a spread of Sb–F bond distances ranging from 1.89–2.02 Å. There are two inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a linear geometry to two F1- atoms. There is one shorter (1.03 Å) and one longer (1.35 Å) H–F bond length. In the second H1+ site, H1+ is bonded in a distorted single-bond geometry to two F1- atoms. There is one shorter (0.98 Å) and one longer (1.56 Å) H–F bond length. There are eight inequivalent F1- sites. In the first F1- site, F1- is bonded in a bent 120 degrees geometry to two H1+ atoms. In the second F1- site, F1- is bonded in a distorted single-bond geometry to one Au2+ and one H1+ atom. In the third F1- site, F1- is bonded in a bent 150 degrees geometry to one Sb5+ and one H1+ atom. In the fourth F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the fifth F1- site, F1- is bonded in a distorted single-bond geometry to one Au2+ and one Sb5+ atom. In the sixth F1- site, F1- is bonded in a bent 120 degrees geometry to one Au2+ and one Sb5+ atom. In the seventh F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the eighth F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom.},
doi = {10.17188/1291683},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sat Jul 18 00:00:00 EDT 2020},
month = {Sat Jul 18 00:00:00 EDT 2020}
}