U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on RbLiF2 by Materials Project
Abstract
RbLiF2 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. Rb1+ is bonded in a 8-coordinate geometry to eight F1- atoms. There are a spread of Rb–F bond distances ranging from 2.87–3.17 Å. Li1+ is bonded to four F1- atoms to form a mixture of corner and edge-sharing LiF4 tetrahedra. There are a spread of Li–F bond distances ranging from 1.84–1.92 Å. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a distorted bent 120 degrees geometry to four equivalent Rb1+ and two equivalent Li1+ atoms. In the second F1- site, F1- is bonded in a distorted linear geometry to four equivalent Rb1+ and two equivalent Li1+ atoms. In the third F1- site, F1- is bonded in a 2-coordinate geometry to four equivalent Rb1+ and two equivalent Li1+ atoms.
- Publication Date:
- Other Number(s):
- mp-7593
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; F-Li-Rb; RbLiF2; crystal structure
- OSTI Identifier:
- 1291383
- DOI:
- https://doi.org/10.17188/1291383
Citation Formats
Materials Data on RbLiF2 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1291383.
Materials Data on RbLiF2 by Materials Project. United States. doi:https://doi.org/10.17188/1291383
2020.
"Materials Data on RbLiF2 by Materials Project". United States. doi:https://doi.org/10.17188/1291383. https://www.osti.gov/servlets/purl/1291383. Pub date:Tue Jul 14 04:00:00 UTC 2020
@article{osti_1291383,
title = {Materials Data on RbLiF2 by Materials Project},
abstractNote = {RbLiF2 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. Rb1+ is bonded in a 8-coordinate geometry to eight F1- atoms. There are a spread of Rb–F bond distances ranging from 2.87–3.17 Å. Li1+ is bonded to four F1- atoms to form a mixture of corner and edge-sharing LiF4 tetrahedra. There are a spread of Li–F bond distances ranging from 1.84–1.92 Å. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a distorted bent 120 degrees geometry to four equivalent Rb1+ and two equivalent Li1+ atoms. In the second F1- site, F1- is bonded in a distorted linear geometry to four equivalent Rb1+ and two equivalent Li1+ atoms. In the third F1- site, F1- is bonded in a 2-coordinate geometry to four equivalent Rb1+ and two equivalent Li1+ atoms.},
doi = {10.17188/1291383},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}