U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Nb2SbO6 by Materials Project
Abstract
Nb2SbO6 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. Nb+4.50+ is bonded to six O2- atoms to form a mixture of edge and corner-sharing NbO6 octahedra. The corner-sharing octahedra tilt angles range from 37–54°. There are a spread of Nb–O bond distances ranging from 1.88–2.22 Å. Sb3+ is bonded in a distorted rectangular see-saw-like geometry to four equivalent O2- atoms. There are two shorter (2.04 Å) and two longer (2.24 Å) Sb–O bond lengths. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted trigonal planar geometry to three equivalent Nb+4.50+ atoms. In the second O2- site, O2- is bonded in a bent 150 degrees geometry to two equivalent Nb+4.50+ atoms. In the third O2- site, O2- is bonded in a distorted trigonal planar geometry to one Nb+4.50+ and two equivalent Sb3+ atoms.
- Publication Date:
- Other Number(s):
- mp-755840
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Nb-O-Sb; Nb2SbO6; crystal structure
- OSTI Identifier:
- 1290242
- DOI:
- https://doi.org/10.17188/1290242
Citation Formats
Materials Data on Nb2SbO6 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1290242.
Materials Data on Nb2SbO6 by Materials Project. United States. doi:https://doi.org/10.17188/1290242
2020.
"Materials Data on Nb2SbO6 by Materials Project". United States. doi:https://doi.org/10.17188/1290242. https://www.osti.gov/servlets/purl/1290242. Pub date:Sun May 03 04:00:00 UTC 2020
@article{osti_1290242,
title = {Materials Data on Nb2SbO6 by Materials Project},
abstractNote = {Nb2SbO6 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. Nb+4.50+ is bonded to six O2- atoms to form a mixture of edge and corner-sharing NbO6 octahedra. The corner-sharing octahedra tilt angles range from 37–54°. There are a spread of Nb–O bond distances ranging from 1.88–2.22 Å. Sb3+ is bonded in a distorted rectangular see-saw-like geometry to four equivalent O2- atoms. There are two shorter (2.04 Å) and two longer (2.24 Å) Sb–O bond lengths. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted trigonal planar geometry to three equivalent Nb+4.50+ atoms. In the second O2- site, O2- is bonded in a bent 150 degrees geometry to two equivalent Nb+4.50+ atoms. In the third O2- site, O2- is bonded in a distorted trigonal planar geometry to one Nb+4.50+ and two equivalent Sb3+ atoms.},
doi = {10.17188/1290242},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {5}
}