U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on U(MoO4)2 by Materials Project
Abstract
UMo2O8 crystallizes in the orthorhombic Pbca space group. The structure is three-dimensional. U4+ is bonded in a 8-coordinate geometry to eight O2- atoms. There are a spread of U–O bond distances ranging from 2.29–2.42 Å. There are two inequivalent Mo6+ sites. In the first Mo6+ site, Mo6+ is bonded in a tetrahedral geometry to four O2- atoms. There are a spread of Mo–O bond distances ranging from 1.79–1.83 Å. In the second Mo6+ site, Mo6+ is bonded in a tetrahedral geometry to four O2- atoms. There is three shorter (1.80 Å) and one longer (1.81 Å) Mo–O bond length. There are eight inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one U4+ and one Mo6+ atom. In the second O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one U4+ and one Mo6+ atom. In the third O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one U4+ and one Mo6+ atom. In the fourth O2- site, O2- is bonded in a distorted linear geometry to one U4+ and one Mo6+ atom. In the fifth O2- site, O2- is bonded inmore »
- Publication Date:
- Other Number(s):
- mp-704511
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Mo-O-U; U(MoO4)2; crystal structure
- OSTI Identifier:
- 1285731
- DOI:
- https://doi.org/10.17188/1285731
Citation Formats
Materials Data on U(MoO4)2 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1285731.
Materials Data on U(MoO4)2 by Materials Project. United States. doi:https://doi.org/10.17188/1285731
2020.
"Materials Data on U(MoO4)2 by Materials Project". United States. doi:https://doi.org/10.17188/1285731. https://www.osti.gov/servlets/purl/1285731. Pub date:Thu Apr 30 00:00:00 EDT 2020
@article{osti_1285731,
title = {Materials Data on U(MoO4)2 by Materials Project},
abstractNote = {UMo2O8 crystallizes in the orthorhombic Pbca space group. The structure is three-dimensional. U4+ is bonded in a 8-coordinate geometry to eight O2- atoms. There are a spread of U–O bond distances ranging from 2.29–2.42 Å. There are two inequivalent Mo6+ sites. In the first Mo6+ site, Mo6+ is bonded in a tetrahedral geometry to four O2- atoms. There are a spread of Mo–O bond distances ranging from 1.79–1.83 Å. In the second Mo6+ site, Mo6+ is bonded in a tetrahedral geometry to four O2- atoms. There is three shorter (1.80 Å) and one longer (1.81 Å) Mo–O bond length. There are eight inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one U4+ and one Mo6+ atom. In the second O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one U4+ and one Mo6+ atom. In the third O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one U4+ and one Mo6+ atom. In the fourth O2- site, O2- is bonded in a distorted linear geometry to one U4+ and one Mo6+ atom. In the fifth O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one U4+ and one Mo6+ atom. In the sixth O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one U4+ and one Mo6+ atom. In the seventh O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one U4+ and one Mo6+ atom. In the eighth O2- site, O2- is bonded in a distorted bent 120 degrees geometry to one U4+ and one Mo6+ atom.},
doi = {10.17188/1285731},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}