U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on K2H2RhCl5O by Materials Project
Abstract
K2RhH2OCl5 crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. K1+ is bonded in a 6-coordinate geometry to six Cl1- atoms. There are a spread of K–Cl bond distances ranging from 3.18–3.71 Å. Rh3+ is bonded in a distorted rectangular see-saw-like geometry to one O2- and three Cl1- atoms. The Rh–O bond length is 1.76 Å. There are two shorter (2.44 Å) and one longer (2.45 Å) Rh–Cl bond lengths. H1+ is bonded in a single-bond geometry to one Cl1- atom. The H–Cl bond length is 1.29 Å. O2- is bonded in a single-bond geometry to one Rh3+ atom. There are four inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one K1+ and one H1+ atom. In the second Cl1- site, Cl1- is bonded in a 5-coordinate geometry to four equivalent K1+ and one Rh3+ atom. In the third Cl1- site, Cl1- is bonded in a 5-coordinate geometry to four equivalent K1+ and one Rh3+ atom. In the fourth Cl1- site, Cl1- is bonded in a distorted single-bond geometry to two equivalent K1+ and one Rh3+ atom.
- Publication Date:
- Other Number(s):
- mp-703299
- DOE Contract Number:
- AC02-05CH11231
- Research Org.:
- LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Collaborations:
- The Materials Project; MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE; Cl-H-K-O-Rh; K2H2RhCl5O; crystal structure
- OSTI Identifier:
- 1285607
- DOI:
- https://doi.org/10.17188/1285607
Citation Formats
Materials Data on K2H2RhCl5O by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1285607.
Materials Data on K2H2RhCl5O by Materials Project. United States. doi:https://doi.org/10.17188/1285607
2020.
"Materials Data on K2H2RhCl5O by Materials Project". United States. doi:https://doi.org/10.17188/1285607. https://www.osti.gov/servlets/purl/1285607. Pub date:Thu Apr 30 00:00:00 EDT 2020
@article{osti_1285607,
title = {Materials Data on K2H2RhCl5O by Materials Project},
abstractNote = {K2RhH2OCl5 crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. K1+ is bonded in a 6-coordinate geometry to six Cl1- atoms. There are a spread of K–Cl bond distances ranging from 3.18–3.71 Å. Rh3+ is bonded in a distorted rectangular see-saw-like geometry to one O2- and three Cl1- atoms. The Rh–O bond length is 1.76 Å. There are two shorter (2.44 Å) and one longer (2.45 Å) Rh–Cl bond lengths. H1+ is bonded in a single-bond geometry to one Cl1- atom. The H–Cl bond length is 1.29 Å. O2- is bonded in a single-bond geometry to one Rh3+ atom. There are four inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one K1+ and one H1+ atom. In the second Cl1- site, Cl1- is bonded in a 5-coordinate geometry to four equivalent K1+ and one Rh3+ atom. In the third Cl1- site, Cl1- is bonded in a 5-coordinate geometry to four equivalent K1+ and one Rh3+ atom. In the fourth Cl1- site, Cl1- is bonded in a distorted single-bond geometry to two equivalent K1+ and one Rh3+ atom.},
doi = {10.17188/1285607},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {4}
}