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Title: Materials Data on Na3(WO3)4 by Materials Project

Abstract

Na3(WO3)4 crystallizes in the cubic Im-3m space group. The structure is three-dimensional. Na1+ is bonded to twelve equivalent O2- atoms to form NaO12 cuboctahedra that share corners with eight equivalent NaO12 cuboctahedra, faces with four equivalent NaO12 cuboctahedra, and faces with eight equivalent WO6 octahedra. There are four shorter (2.75 Å) and eight longer (2.78 Å) Na–O bond lengths. W+5.25+ is bonded to six equivalent O2- atoms to form WO6 octahedra that share corners with six equivalent WO6 octahedra and faces with six equivalent NaO12 cuboctahedra. The corner-sharing octahedral tilt angles are 2°. All W–O bond lengths are 1.97 Å. O2- is bonded to three equivalent Na1+ and two equivalent W+5.25+ atoms to form a mixture of distorted corner, edge, and face-sharing ONa3W2 square pyramids.

Publication Date:
Other Number(s):
mp-35005
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Na3(WO3)4; Na-O-W
OSTI Identifier:
1206922
DOI:
https://doi.org/10.17188/1206922

Citation Formats

The Materials Project. Materials Data on Na3(WO3)4 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1206922.
The Materials Project. Materials Data on Na3(WO3)4 by Materials Project. United States. doi:https://doi.org/10.17188/1206922
The Materials Project. 2020. "Materials Data on Na3(WO3)4 by Materials Project". United States. doi:https://doi.org/10.17188/1206922. https://www.osti.gov/servlets/purl/1206922. Pub date:Wed Jul 15 00:00:00 EDT 2020
@article{osti_1206922,
title = {Materials Data on Na3(WO3)4 by Materials Project},
author = {The Materials Project},
abstractNote = {Na3(WO3)4 crystallizes in the cubic Im-3m space group. The structure is three-dimensional. Na1+ is bonded to twelve equivalent O2- atoms to form NaO12 cuboctahedra that share corners with eight equivalent NaO12 cuboctahedra, faces with four equivalent NaO12 cuboctahedra, and faces with eight equivalent WO6 octahedra. There are four shorter (2.75 Å) and eight longer (2.78 Å) Na–O bond lengths. W+5.25+ is bonded to six equivalent O2- atoms to form WO6 octahedra that share corners with six equivalent WO6 octahedra and faces with six equivalent NaO12 cuboctahedra. The corner-sharing octahedral tilt angles are 2°. All W–O bond lengths are 1.97 Å. O2- is bonded to three equivalent Na1+ and two equivalent W+5.25+ atoms to form a mixture of distorted corner, edge, and face-sharing ONa3W2 square pyramids.},
doi = {10.17188/1206922},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}