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Title: Materials Data on Sb2Rh by Materials Project

Abstract

RhSb2 is Marcasite-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. Rh4+ is bonded to six Sb2- atoms to form a mixture of edge and corner-sharing RhSb6 octahedra. The corner-sharing octahedra tilt angles range from 51–57°. There are a spread of Rh–Sb bond distances ranging from 2.62–2.71 Å. There are two inequivalent Sb2- sites. In the first Sb2- site, Sb2- is bonded in a 4-coordinate geometry to three equivalent Rh4+ atoms. In the second Sb2- site, Sb2- is bonded in a 4-coordinate geometry to three equivalent Rh4+ atoms.

Publication Date:
Other Number(s):
mp-2682
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Sb2Rh; Rh-Sb
OSTI Identifier:
1201244
DOI:
10.17188/1201244

Citation Formats

The Materials Project. Materials Data on Sb2Rh by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1201244.
The Materials Project. Materials Data on Sb2Rh by Materials Project. United States. doi:10.17188/1201244.
The Materials Project. 2020. "Materials Data on Sb2Rh by Materials Project". United States. doi:10.17188/1201244. https://www.osti.gov/servlets/purl/1201244. Pub date:Thu Jul 16 00:00:00 EDT 2020
@article{osti_1201244,
title = {Materials Data on Sb2Rh by Materials Project},
author = {The Materials Project},
abstractNote = {RhSb2 is Marcasite-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. Rh4+ is bonded to six Sb2- atoms to form a mixture of edge and corner-sharing RhSb6 octahedra. The corner-sharing octahedra tilt angles range from 51–57°. There are a spread of Rh–Sb bond distances ranging from 2.62–2.71 Å. There are two inequivalent Sb2- sites. In the first Sb2- site, Sb2- is bonded in a 4-coordinate geometry to three equivalent Rh4+ atoms. In the second Sb2- site, Sb2- is bonded in a 4-coordinate geometry to three equivalent Rh4+ atoms.},
doi = {10.17188/1201244},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}

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