Materials Data on Ge(Bi3O5)4 by Materials Project

doi:10.17188/1199446

Title: Materials Data on Ge(Bi3O5)4 by Materials Project

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Abstract

Bi12GeO20 crystallizes in the cubic I23 space group. The structure is three-dimensional. Ge4+ is bonded in a tetrahedral geometry to four equivalent O2- atoms. All Ge–O bond lengths are 1.80 Å. Bi3+ is bonded in a 5-coordinate geometry to five O2- atoms. There are a spread of Bi–O bond distances ranging from 2.11–2.66 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a 3-coordinate geometry to three equivalent Bi3+ atoms. In the second O2- site, O2- is bonded to one Ge4+ and three equivalent Bi3+ atoms to form distorted corner-sharing OGeBi3 tetrahedra. In the third O2- site, O2- is bonded in a trigonal planar geometry to three equivalent Bi3+ atoms.

Publication Date:: Thu Jul 23 04:00:00 UTC 2020

Other Number(s):: mp-23352

DOE Contract Number:: AC02-05CH11231

Research Org.:: LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Collaborations:: The Materials Project; MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE; Bi-Ge-O; Ge(Bi3O5)4; crystal structure

OSTI Identifier:: 1199446

DOI:: https://doi.org/10.17188/1199446

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                    Materials Data on Ge(Bi3O5)4 by Materials Project.  United States: N. p., 2020. 
        Web.  doi:10.17188/1199446.

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                    Materials Data on Ge(Bi3O5)4 by Materials Project.  United States.  doi:https://doi.org/10.17188/1199446

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                    2020.  
"Materials Data on Ge(Bi3O5)4 by Materials Project".  United States.  doi:https://doi.org/10.17188/1199446.  https://www.osti.gov/servlets/purl/1199446. Pub date:Thu Jul 23 04:00:00 UTC 2020

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@article{osti_1199446,

  title        = {Materials Data on Ge(Bi3O5)4 by Materials Project},

  
  abstractNote = {Bi12GeO20 crystallizes in the cubic I23 space group. The structure is three-dimensional. Ge4+ is bonded in a tetrahedral geometry to four equivalent O2- atoms. All Ge–O bond lengths are 1.80 Å. Bi3+ is bonded in a 5-coordinate geometry to five O2- atoms. There are a spread of Bi–O bond distances ranging from 2.11–2.66 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a 3-coordinate geometry to three equivalent Bi3+ atoms. In the second O2- site, O2- is bonded to one Ge4+ and three equivalent Bi3+ atoms to form distorted corner-sharing OGeBi3 tetrahedra. In the third O2- site, O2- is bonded in a trigonal planar geometry to three equivalent Bi3+ atoms.},

  doi          = {10.17188/1199446},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {Thu Jul 23 04:00:00 UTC 2020},

  month        = {Thu Jul 23 04:00:00 UTC 2020}

}

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DOI: https://doi.org/10.17188/1199446

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