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Title: Materials Data on K3Ir(NO2)6 by Materials Project

Abstract

KIr(K(NO2)3)2 crystallizes in the cubic Fm-3m space group. The structure is three-dimensional and consists of four iridium molecules, four potassium molecules, and one K(NO2)3 framework. In the K(NO2)3 framework, K1+ is bonded in a distorted q4 geometry to twelve equivalent O2- atoms. All K–O bond lengths are 2.69 Å. N3+ is bonded in a rectangular see-saw-like geometry to four equivalent O2- atoms. All N–O bond lengths are 2.14 Å. O2- is bonded in a 5-coordinate geometry to two equivalent K1+, two equivalent N3+, and one O2- atom. The O–O bond length is 1.32 Å.

Publication Date:
Other Number(s):
mp-20017
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Product Type:
Dataset
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; K3Ir(NO2)6; Ir-K-N-O
OSTI Identifier:
1195190
DOI:
https://doi.org/10.17188/1195190

Citation Formats

The Materials Project. Materials Data on K3Ir(NO2)6 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1195190.
The Materials Project. Materials Data on K3Ir(NO2)6 by Materials Project. United States. doi:https://doi.org/10.17188/1195190
The Materials Project. 2020. "Materials Data on K3Ir(NO2)6 by Materials Project". United States. doi:https://doi.org/10.17188/1195190. https://www.osti.gov/servlets/purl/1195190. Pub date:Wed Jul 15 00:00:00 EDT 2020
@article{osti_1195190,
title = {Materials Data on K3Ir(NO2)6 by Materials Project},
author = {The Materials Project},
abstractNote = {KIr(K(NO2)3)2 crystallizes in the cubic Fm-3m space group. The structure is three-dimensional and consists of four iridium molecules, four potassium molecules, and one K(NO2)3 framework. In the K(NO2)3 framework, K1+ is bonded in a distorted q4 geometry to twelve equivalent O2- atoms. All K–O bond lengths are 2.69 Å. N3+ is bonded in a rectangular see-saw-like geometry to four equivalent O2- atoms. All N–O bond lengths are 2.14 Å. O2- is bonded in a 5-coordinate geometry to two equivalent K1+, two equivalent N3+, and one O2- atom. The O–O bond length is 1.32 Å.},
doi = {10.17188/1195190},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}