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Title: Materials Data on Rh2S3 by Materials Project

Abstract

Rh2S3 is Corundum-like structured and crystallizes in the orthorhombic Pbcn space group. The structure is three-dimensional. Rh3+ is bonded to six S2- atoms to form a mixture of face, edge, and corner-sharing RhS6 octahedra. The corner-sharing octahedra tilt angles range from 49–70°. There are a spread of Rh–S bond distances ranging from 2.33–2.43 Å. There are two inequivalent S2- sites. In the first S2- site, S2- is bonded to four equivalent Rh3+ atoms to form a mixture of distorted edge and corner-sharing SRh4 trigonal pyramids. In the second S2- site, S2- is bonded to four equivalent Rh3+ atoms to form a mixture of distorted edge and corner-sharing SRh4 tetrahedra.

Authors:
Publication Date:
Other Number(s):
mp-17173
DOE Contract Number:  
AC02-05CH11231; EDCBEE
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Collaborations:
MIT; UC Berkeley; Duke; U Louvain
Subject:
36 MATERIALS SCIENCE
Keywords:
crystal structure; Rh2S3; Rh-S
OSTI Identifier:
1192373
DOI:
https://doi.org/10.17188/1192373

Citation Formats

The Materials Project. Materials Data on Rh2S3 by Materials Project. United States: N. p., 2020. Web. doi:10.17188/1192373.
The Materials Project. Materials Data on Rh2S3 by Materials Project. United States. doi:https://doi.org/10.17188/1192373
The Materials Project. 2020. "Materials Data on Rh2S3 by Materials Project". United States. doi:https://doi.org/10.17188/1192373. https://www.osti.gov/servlets/purl/1192373. Pub date:Fri Jul 17 00:00:00 EDT 2020
@article{osti_1192373,
title = {Materials Data on Rh2S3 by Materials Project},
author = {The Materials Project},
abstractNote = {Rh2S3 is Corundum-like structured and crystallizes in the orthorhombic Pbcn space group. The structure is three-dimensional. Rh3+ is bonded to six S2- atoms to form a mixture of face, edge, and corner-sharing RhS6 octahedra. The corner-sharing octahedra tilt angles range from 49–70°. There are a spread of Rh–S bond distances ranging from 2.33–2.43 Å. There are two inequivalent S2- sites. In the first S2- site, S2- is bonded to four equivalent Rh3+ atoms to form a mixture of distorted edge and corner-sharing SRh4 trigonal pyramids. In the second S2- site, S2- is bonded to four equivalent Rh3+ atoms to form a mixture of distorted edge and corner-sharing SRh4 tetrahedra.},
doi = {10.17188/1192373},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {7}
}