Materials Data on Eu3(SF2)2 by Materials Project

doi:10.17188/1715529

Title: Materials Data on Eu3(SF2)2 by Materials Project

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Abstract

Eu3F4S2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. there are two inequivalent Eu+2.67+ sites. In the first Eu+2.67+ site, Eu+2.67+ is bonded in a body-centered cubic geometry to eight equivalent F1- atoms. All Eu–F bond lengths are 2.42 Å. In the second Eu+2.67+ site, Eu+2.67+ is bonded in a 9-coordinate geometry to five equivalent S2- and four equivalent F1- atoms. There are one shorter (2.84 Å) and four longer (2.92 Å) Eu–S bond lengths. All Eu–F bond lengths are 2.62 Å. S2- is bonded in a 5-coordinate geometry to five equivalent Eu+2.67+ atoms. F1- is bonded to four Eu+2.67+ atoms to form a mixture of distorted edge and corner-sharing FEu4 tetrahedra.

Publication Date:: Thu Jun 04 04:00:00 UTC 2020

Other Number(s):: mp-1080739

DOE Contract Number:: AC02-05CH11231

Research Org.:: LBNL Materials Project; Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Collaborations:: The Materials Project; MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE; Eu-F-S; Eu3(SF2)2; crystal structure

OSTI Identifier:: 1715529

DOI:: https://doi.org/10.17188/1715529

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                    Materials Data on Eu3(SF2)2 by Materials Project.  United States: N. p., 2020. 
        Web.  doi:10.17188/1715529.

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                    Materials Data on Eu3(SF2)2 by Materials Project.  United States.  doi:https://doi.org/10.17188/1715529

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                    2020.  
"Materials Data on Eu3(SF2)2 by Materials Project".  United States.  doi:https://doi.org/10.17188/1715529.  https://www.osti.gov/servlets/purl/1715529. Pub date:Thu Jun 04 04:00:00 UTC 2020

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@article{osti_1715529,

  title        = {Materials Data on Eu3(SF2)2 by Materials Project},

  
  abstractNote = {Eu3F4S2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. there are two inequivalent Eu+2.67+ sites. In the first Eu+2.67+ site, Eu+2.67+ is bonded in a body-centered cubic geometry to eight equivalent F1- atoms. All Eu–F bond lengths are 2.42 Å. In the second Eu+2.67+ site, Eu+2.67+ is bonded in a 9-coordinate geometry to five equivalent S2- and four equivalent F1- atoms. There are one shorter (2.84 Å) and four longer (2.92 Å) Eu–S bond lengths. All Eu–F bond lengths are 2.62 Å. S2- is bonded in a 5-coordinate geometry to five equivalent Eu+2.67+ atoms. F1- is bonded to four Eu+2.67+ atoms to form a mixture of distorted edge and corner-sharing FEu4 tetrahedra.},

  doi          = {10.17188/1715529},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {Thu Jun 04 04:00:00 UTC 2020},

  month        = {Thu Jun 04 04:00:00 UTC 2020}

}

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DOI: https://doi.org/10.17188/1715529

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