U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on CePS by Materials Project
Abstract
CePS crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. there are two inequivalent Ce3+ sites. In the first Ce3+ site, Ce3+ is bonded in a 9-coordinate geometry to four equivalent P1- and five S2- atoms. There are two shorter (2.93 Å) and two longer (3.07 Å) Ce–P bond lengths. There are a spread of Ce–S bond distances ranging from 2.82–2.91 Å. In the second Ce3+ site, Ce3+ is bonded in a 9-coordinate geometry to four equivalent P1- and five S2- atoms. There are two shorter (3.09 Å) and two longer (3.10 Å) Ce–P bond lengths. There are a spread of Ce–S bond distances ranging from 2.84–2.97 Å. P1- is bonded in a distorted hexagonal planar geometry to four Ce3+ and two equivalent P1- atoms. There are one shorter (2.27 Å) and one longer (2.38 Å) P–P bond lengths. There are two inequivalent S2- sites. In the first S2- site, S2- is bonded to five Ce3+ atoms to form a mixture of distorted corner and edge-sharing SCe5 trigonal bipyramids. In the second S2- site, S2- is bonded to five Ce3+ atoms to form a mixture of distorted corner and edge-sharing SCe5 trigonal bipyramids.
- Authors:
- Publication Date:
- Other Number(s):
- mp-1006371
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; CePS; Ce-P-S
- OSTI Identifier:
- 1317191
- DOI:
- https://doi.org/10.17188/1317191
Citation Formats
The Materials Project. Materials Data on CePS by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1317191.
The Materials Project. Materials Data on CePS by Materials Project. United States. doi:https://doi.org/10.17188/1317191
The Materials Project. 2020.
"Materials Data on CePS by Materials Project". United States. doi:https://doi.org/10.17188/1317191. https://www.osti.gov/servlets/purl/1317191. Pub date:Thu Jul 23 00:00:00 EDT 2020
@article{osti_1317191,
title = {Materials Data on CePS by Materials Project},
author = {The Materials Project},
abstractNote = {CePS crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. there are two inequivalent Ce3+ sites. In the first Ce3+ site, Ce3+ is bonded in a 9-coordinate geometry to four equivalent P1- and five S2- atoms. There are two shorter (2.93 Å) and two longer (3.07 Å) Ce–P bond lengths. There are a spread of Ce–S bond distances ranging from 2.82–2.91 Å. In the second Ce3+ site, Ce3+ is bonded in a 9-coordinate geometry to four equivalent P1- and five S2- atoms. There are two shorter (3.09 Å) and two longer (3.10 Å) Ce–P bond lengths. There are a spread of Ce–S bond distances ranging from 2.84–2.97 Å. P1- is bonded in a distorted hexagonal planar geometry to four Ce3+ and two equivalent P1- atoms. There are one shorter (2.27 Å) and one longer (2.38 Å) P–P bond lengths. There are two inequivalent S2- sites. In the first S2- site, S2- is bonded to five Ce3+ atoms to form a mixture of distorted corner and edge-sharing SCe5 trigonal bipyramids. In the second S2- site, S2- is bonded to five Ce3+ atoms to form a mixture of distorted corner and edge-sharing SCe5 trigonal bipyramids.},
doi = {10.17188/1317191},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Thu Jul 23 00:00:00 EDT 2020},
month = {Thu Jul 23 00:00:00 EDT 2020}
}