U.S. Department of EnergyOffice of Scientific and Technical Information
Materials Data on Mn(SbO3)2 by Materials Project
Abstract
MnSb2O6 is Hydrophilite-derived structured and crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. Mn2+ is bonded to six O2- atoms to form MnO6 octahedra that share corners with eight SbO6 octahedra, an edgeedge with one MnO6 octahedra, and an edgeedge with one SbO6 octahedra. The corner-sharing octahedra tilt angles range from 46–55°. There are a spread of Mn–O bond distances ranging from 2.05–2.18 Å. There are three inequivalent Sb5+ sites. In the first Sb5+ site, Sb5+ is bonded to six O2- atoms to form SbO6 octahedra that share corners with three equivalent SbO6 octahedra, corners with five equivalent MnO6 octahedra, and edges with two SbO6 octahedra. The corner-sharing octahedra tilt angles range from 46–52°. There are a spread of Sb–O bond distances ranging from 1.93–2.14 Å. In the second Sb5+ site, Sb5+ is bonded to six O2- atoms to form SbO6 octahedra that share corners with two equivalent SbO6 octahedra, corners with six equivalent MnO6 octahedra, and edges with two equivalent SbO6 octahedra. The corner-sharing octahedra tilt angles range from 48–55°. There are four shorter (2.02 Å) and two longer (2.06 Å) Sb–O bond lengths. In the third Sb5+ site, Sb5+ is bonded to six O2- atomsmore »
- Authors:
- Publication Date:
- Other Number(s):
- mp-690561
- DOE Contract Number:
- AC02-05CH11231; EDCBEE
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Collaborations:
- MIT; UC Berkeley; Duke; U Louvain
- Subject:
- 36 MATERIALS SCIENCE
- Keywords:
- crystal structure; Mn(SbO3)2; Mn-O-Sb
- OSTI Identifier:
- 1284536
- DOI:
- https://doi.org/10.17188/1284536
Citation Formats
The Materials Project. Materials Data on Mn(SbO3)2 by Materials Project. United States: N. p., 2020.
Web. doi:10.17188/1284536.
The Materials Project. Materials Data on Mn(SbO3)2 by Materials Project. United States. doi:https://doi.org/10.17188/1284536
The Materials Project. 2020.
"Materials Data on Mn(SbO3)2 by Materials Project". United States. doi:https://doi.org/10.17188/1284536. https://www.osti.gov/servlets/purl/1284536. Pub date:Sat May 02 00:00:00 EDT 2020
@article{osti_1284536,
title = {Materials Data on Mn(SbO3)2 by Materials Project},
author = {The Materials Project},
abstractNote = {MnSb2O6 is Hydrophilite-derived structured and crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. Mn2+ is bonded to six O2- atoms to form MnO6 octahedra that share corners with eight SbO6 octahedra, an edgeedge with one MnO6 octahedra, and an edgeedge with one SbO6 octahedra. The corner-sharing octahedra tilt angles range from 46–55°. There are a spread of Mn–O bond distances ranging from 2.05–2.18 Å. There are three inequivalent Sb5+ sites. In the first Sb5+ site, Sb5+ is bonded to six O2- atoms to form SbO6 octahedra that share corners with three equivalent SbO6 octahedra, corners with five equivalent MnO6 octahedra, and edges with two SbO6 octahedra. The corner-sharing octahedra tilt angles range from 46–52°. There are a spread of Sb–O bond distances ranging from 1.93–2.14 Å. In the second Sb5+ site, Sb5+ is bonded to six O2- atoms to form SbO6 octahedra that share corners with two equivalent SbO6 octahedra, corners with six equivalent MnO6 octahedra, and edges with two equivalent SbO6 octahedra. The corner-sharing octahedra tilt angles range from 48–55°. There are four shorter (2.02 Å) and two longer (2.06 Å) Sb–O bond lengths. In the third Sb5+ site, Sb5+ is bonded to six O2- atoms to form SbO6 octahedra that share corners with eight SbO6 octahedra and edges with two equivalent MnO6 octahedra. The corner-sharing octahedra tilt angles range from 48–51°. There are a spread of Sb–O bond distances ranging from 2.00–2.14 Å. There are five inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted trigonal planar geometry to one Mn2+ and two Sb5+ atoms. In the second O2- site, O2- is bonded in a distorted trigonal planar geometry to one Mn2+ and two Sb5+ atoms. In the third O2- site, O2- is bonded in a distorted trigonal planar geometry to two equivalent Mn2+ and one Sb5+ atom. In the fourth O2- site, O2- is bonded in a trigonal planar geometry to one Mn2+ and two Sb5+ atoms. In the fifth O2- site, O2- is bonded in a trigonal planar geometry to three Sb5+ atoms.},
doi = {10.17188/1284536},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sat May 02 00:00:00 EDT 2020},
month = {Sat May 02 00:00:00 EDT 2020}
}