Materials Data on Te6MoBr3 by Materials Project

doi:10.17188/1278117

Title: Materials Data on Te6MoBr3 by Materials Project

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Abstract

MoTe6Br3 crystallizes in the triclinic P-1 space group. The structure is three-dimensional. there are two inequivalent Mo3+ sites. In the first Mo3+ site, Mo3+ is bonded in a 8-coordinate geometry to eight Te atoms. There are a spread of Mo–Te bond distances ranging from 2.74–2.89 Å. In the second Mo3+ site, Mo3+ is bonded in a 8-coordinate geometry to eight Te atoms. There are a spread of Mo–Te bond distances ranging from 2.75–2.88 Å. There are twelve inequivalent Te sites. In the first Te site, Te is bonded in a 2-coordinate geometry to one Mo3+, two Te, and two Br1- atoms. There are one shorter (2.79 Å) and one longer (2.88 Å) Te–Te bond lengths. There are one shorter (2.80 Å) and one longer (3.26 Å) Te–Br bond lengths. In the second Te site, Te is bonded in a 5-coordinate geometry to one Mo3+, two Te, and two Br1- atoms. Both Te–Te bond lengths are 2.81 Å. There are one shorter (3.18 Å) and one longer (3.19 Å) Te–Br bond lengths. In the third Te site, Te is bonded in a 1-coordinate geometry to one Mo3+, two Te, and two Br1- atoms. There are one shorter (2.79 Å) and onemore »« less

Authors:: The Materials Project

Publication Date:: Thu Apr 30 00:00:00 EDT 2020

Other Number(s):: mp-622262

DOE Contract Number:: AC02-05CH11231; EDCBEE

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Collaborations:: MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE

Keywords:: crystal structure; Te6MoBr3; Br-Mo-Te

OSTI Identifier:: 1278117

DOI:: https://doi.org/10.17188/1278117

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                    The Materials Project. Materials Data on Te6MoBr3 by Materials Project.  United States: N. p., 2020. 
        Web.  doi:10.17188/1278117.

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                    The Materials Project. Materials Data on Te6MoBr3 by Materials Project.  United States.  doi:https://doi.org/10.17188/1278117

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                    The Materials Project. 2020.  
"Materials Data on Te6MoBr3 by Materials Project".  United States.  doi:https://doi.org/10.17188/1278117.  https://www.osti.gov/servlets/purl/1278117. Pub date:Thu Apr 30 00:00:00 EDT 2020

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@article{osti_1278117,

  title        = {Materials Data on Te6MoBr3 by Materials Project},

  author       = {The Materials Project},

  abstractNote = {MoTe6Br3 crystallizes in the triclinic P-1 space group. The structure is three-dimensional. there are two inequivalent Mo3+ sites. In the first Mo3+ site, Mo3+ is bonded in a 8-coordinate geometry to eight Te atoms. There are a spread of Mo–Te bond distances ranging from 2.74–2.89 Å. In the second Mo3+ site, Mo3+ is bonded in a 8-coordinate geometry to eight Te atoms. There are a spread of Mo–Te bond distances ranging from 2.75–2.88 Å. There are twelve inequivalent Te sites. In the first Te site, Te is bonded in a 2-coordinate geometry to one Mo3+, two Te, and two Br1- atoms. There are one shorter (2.79 Å) and one longer (2.88 Å) Te–Te bond lengths. There are one shorter (2.80 Å) and one longer (3.26 Å) Te–Br bond lengths. In the second Te site, Te is bonded in a 5-coordinate geometry to one Mo3+, two Te, and two Br1- atoms. Both Te–Te bond lengths are 2.81 Å. There are one shorter (3.18 Å) and one longer (3.19 Å) Te–Br bond lengths. In the third Te site, Te is bonded in a 1-coordinate geometry to one Mo3+, two Te, and two Br1- atoms. There are one shorter (2.79 Å) and one longer (2.89 Å) Te–Te bond lengths. There are one shorter (2.80 Å) and one longer (3.39 Å) Te–Br bond lengths. In the fourth Te site, Te is bonded in a 6-coordinate geometry to one Mo3+, two Te, and three Br1- atoms. The Te–Te bond length is 2.81 Å. There are a spread of Te–Br bond distances ranging from 3.24–3.84 Å. In the fifth Te site, Te is bonded in a 5-coordinate geometry to two equivalent Mo3+, one Te, and two Br1- atoms. The Te–Te bond length is 2.80 Å. There are one shorter (3.75 Å) and one longer (3.82 Å) Te–Br bond lengths. In the sixth Te site, Te is bonded in a 6-coordinate geometry to one Mo3+, two Te, and three Br1- atoms. There are a spread of Te–Br bond distances ranging from 3.35–3.83 Å. In the seventh Te site, Te is bonded in a 6-coordinate geometry to two equivalent Mo3+, one Te, and three Br1- atoms. The Te–Te bond length is 2.77 Å. There are a spread of Te–Br bond distances ranging from 3.73–3.92 Å. In the eighth Te site, Te is bonded in a 6-coordinate geometry to one Mo3+, two Te, and three Br1- atoms. There are a spread of Te–Br bond distances ranging from 3.50–3.99 Å. In the ninth Te site, Te is bonded in a 6-coordinate geometry to one Mo3+, two Te, and three Br1- atoms. The Te–Te bond length is 2.81 Å. There are a spread of Te–Br bond distances ranging from 3.24–3.59 Å. In the tenth Te site, Te is bonded in a 1-coordinate geometry to two equivalent Mo3+, one Te, and three Br1- atoms. There are a spread of Te–Br bond distances ranging from 3.11–3.84 Å. In the eleventh Te site, Te is bonded in a 6-coordinate geometry to one Mo3+, two Te, and three Br1- atoms. There are a spread of Te–Br bond distances ranging from 3.21–3.92 Å. In the twelfth Te site, Te is bonded in a 1-coordinate geometry to two equivalent Mo3+, one Te, and two Br1- atoms. There are one shorter (3.17 Å) and one longer (3.82 Å) Te–Br bond lengths. There are six inequivalent Br1- sites. In the first Br1- site, Br1- is bonded in a 5-coordinate geometry to five Te atoms. In the second Br1- site, Br1- is bonded in a 5-coordinate geometry to six Te atoms. In the third Br1- site, Br1- is bonded in a 6-coordinate geometry to six Te atoms. In the fourth Br1- site, Br1- is bonded in a 4-coordinate geometry to four Te atoms. In the fifth Br1- site, Br1- is bonded in a 1-coordinate geometry to five Te atoms. In the sixth Br1- site, Br1- is bonded in a distorted single-bond geometry to five Te atoms.},

  doi          = {10.17188/1278117},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {Thu Apr 30 00:00:00 EDT 2020},

  month        = {Thu Apr 30 00:00:00 EDT 2020}

}

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DOI: https://doi.org/10.17188/1278117

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