Materials Data on Tl2Hg2PdCl8 by Materials Project

doi:10.17188/1275206

Title: Materials Data on Tl2Hg2PdCl8 by Materials Project

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Abstract

PdHg2Tl2Cl8 crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. Pd2+ is bonded in a square co-planar geometry to four equivalent Cl1- atoms. All Pd–Cl bond lengths are 2.33 Å. Hg2+ is bonded in a distorted linear geometry to four Cl1- atoms. There are a spread of Hg–Cl bond distances ranging from 2.34–3.23 Å. Tl1+ is bonded in a 10-coordinate geometry to ten Cl1- atoms. There are a spread of Tl–Cl bond distances ranging from 3.34–3.77 Å. There are three inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a 1-coordinate geometry to one Pd2+, one Hg2+, and three equivalent Tl1+ atoms. In the second Cl1- site, Cl1- is bonded in a distorted single-bond geometry to one Hg2+ and two equivalent Tl1+ atoms. In the third Cl1- site, Cl1- is bonded in a distorted single-bond geometry to one Hg2+ and two equivalent Tl1+ atoms.

Authors:: The Materials Project

Publication Date:: Tue Jul 14 00:00:00 EDT 2020

Other Number(s):: mp-569675

DOE Contract Number:: AC02-05CH11231; EDCBEE

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). LBNL Materials Project

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Collaborations:: MIT; UC Berkeley; Duke; U Louvain

Subject:: 36 MATERIALS SCIENCE

Keywords:: crystal structure; Tl2Hg2PdCl8; Cl-Hg-Pd-Tl

OSTI Identifier:: 1275206

DOI:: https://doi.org/10.17188/1275206

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                    The Materials Project. Materials Data on Tl2Hg2PdCl8 by Materials Project.  United States: N. p., 2020. 
        Web.  doi:10.17188/1275206.

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                    The Materials Project. Materials Data on Tl2Hg2PdCl8 by Materials Project.  United States.  doi:https://doi.org/10.17188/1275206

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                    The Materials Project. 2020.  
"Materials Data on Tl2Hg2PdCl8 by Materials Project".  United States.  doi:https://doi.org/10.17188/1275206.  https://www.osti.gov/servlets/purl/1275206. Pub date:Tue Jul 14 00:00:00 EDT 2020

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@article{osti_1275206,

  title        = {Materials Data on Tl2Hg2PdCl8 by Materials Project},

  author       = {The Materials Project},

  abstractNote = {PdHg2Tl2Cl8 crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. Pd2+ is bonded in a square co-planar geometry to four equivalent Cl1- atoms. All Pd–Cl bond lengths are 2.33 Å. Hg2+ is bonded in a distorted linear geometry to four Cl1- atoms. There are a spread of Hg–Cl bond distances ranging from 2.34–3.23 Å. Tl1+ is bonded in a 10-coordinate geometry to ten Cl1- atoms. There are a spread of Tl–Cl bond distances ranging from 3.34–3.77 Å. There are three inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a 1-coordinate geometry to one Pd2+, one Hg2+, and three equivalent Tl1+ atoms. In the second Cl1- site, Cl1- is bonded in a distorted single-bond geometry to one Hg2+ and two equivalent Tl1+ atoms. In the third Cl1- site, Cl1- is bonded in a distorted single-bond geometry to one Hg2+ and two equivalent Tl1+ atoms.},

  doi          = {10.17188/1275206},

  journal      = {},

  number       = ,

  volume       = ,

  place        = {United States},

  year         = {Tue Jul 14 00:00:00 EDT 2020},

  month        = {Tue Jul 14 00:00:00 EDT 2020}

}

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DOI: https://doi.org/10.17188/1275206

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